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A5116875451Middle East Technical University
2025
The main obstacle in replacing well-established precious ruthenium photosensitizers with earth-abundant iron analogs is the short excited state lifetimes of metal-to-ligand charge transfer (MLCT) states due to relatively weak octahedral field splitting and relaxation via metal-centered (MC) states. In this study, we address issue lifetime by using pentacyanoferrate(II) complexes combat facile photodissociation utilizing positively charged pyrazinium or bipyridinium ligands. We utilize...
10.1021/acs.inorgchem.5c00412
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Inorganic Chemistry
2025-04-01
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