A5053255592- Synthesis and characterization of novel inorganic/organometallic compounds
- Organometallic Complex Synthesis and Catalysis
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Organophosphorus compounds synthesis
- Asymmetric Hydrogenation and Catalysis
- Synthetic Organic Chemistry Methods
- Crystallography and molecular interactions
- Ferrocene Chemistry and Applications
- Asymmetric Synthesis and Catalysis
- Coordination Chemistry and Organometallics
- Phosphorus compounds and reactions
- Chemical Synthesis and Characterization
- Metal complexes synthesis and properties
- Inorganic Chemistry and Materials
- Organoboron and organosilicon chemistry
- Cyclopropane Reaction Mechanisms
- Catalytic Alkyne Reactions
- Inorganic and Organometallic Chemistry
- Organometallic Compounds Synthesis and Characterization
- Molecular Junctions and Nanostructures
- Chemical Synthesis and Analysis
- Metalloenzymes and iron-sulfur proteins
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Synthesis and Reactivity of Sulfur-Containing Compounds
Zhengzhou University
2011-2021
Nanyang Technological University
2009-2016
Centre National de la Recherche Scientifique
2001-2014
Université de Rennes
2011-2014
Institut des Sciences Chimiques de Rennes
2011-2014
École Polytechnique
1999-2013
CEA Paris-Saclay
1991-2013
Commissariat à l'Énergie Atomique et aux Énergies Alternatives
2013
Ministère de l'Agriculture et de la Souveraineté alimentaire
2010
University of California, Riverside
2004-2008
Since the beginning of seventies, organophosphorus chemistry has been completely rejuvenated by discovery stable derivatives in which phosphorus coordination numbers one or two. The these compounds mimics their all-carbon analogues. In this Review article analogy is discussed for counterparts alkenes, alkynes, and carbenes. each case, synthesis, reactivity, modes are briefly examined. Some special electronic configurations also discussed, include one-electron Pbond;P bonds, strained aromatic...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT1,1'-Diphosphaferrocenes. Synthesis, basic chemistry, and structureGuillaume De Lauzon, Bernard Deschamps, Jean Fischer, Francois Mathey, Andre MitschlerCite this: J. Am. Chem. Soc. 1980, 102, 3, 994–1000Publication Date (Print):January 1, 1980Publication History Published online1 May 2002Published inissue 1 January 1980https://pubs.acs.org/doi/10.1021/ja00523a015https://doi.org/10.1021/ja00523a015research-articleACS PublicationsRequest reuse...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProton [1,5] shifts in P-unsubstituted 1H-phospholes. Synthesis and chemistry of 2H-phosphole dimersClaude Charrier, Hubert Bonnard, Guillaume De Lauzon, Francois MatheyCite this: J. Am. Chem. Soc. 1983, 105, 23, 6871–6877Publication Date (Print):November 1, 1983Publication History Published online1 May 2002Published inissue 1 November 1983https://pubs.acs.org/doi/10.1021/ja00361a022https://doi.org/10.1021/ja00361a022research-articleACS...
A synthetic route to novel benzofuran-fused phosphole derivatives 3–5 is described. These compounds showed optical and electrochemical properties that differ from their benzothiophene analog. Preliminary results show 4 can be used as an emitter in OLEDs, illustrating the potential of these new for opto-electronic applications.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhosphaferroceneFrancois Mathey, Andre Mitschler, and Raymond WeissCite this: J. Am. Chem. Soc. 1977, 99, 10, 3537–3538Publication Date (Print):May 1, 1977Publication History Published online1 May 2002Published inissue 1 1977https://doi.org/10.1021/ja00452a076Request reuse permissionsArticle Views289Altmetric-Citations85LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF...
A new pair of P-stereogenic ligands with multiple chiral centers were synthesized and used in the copper(I)-catalyzed enatioselective [3 + 2] cycloaddition iminoesters alkenes. variety highly functionalized pyrrolidines obtained excellent yield enatioselectivity. This is first example a working as pseudoenantiomers to tune enantio- diastereoselective 1,3-dipolar cycloaddition, providing enantiomerically pure pyrrolidines, respectively.
Abstract Optically active phosphorus ligands are widely used in homogeneous asymmetric catalysis. However, among the numerous available structures of this type, subclass optically bisphosphines with at least one chiral atom is rather underdeveloped. A bisphosphine two chiral, nonracemizable bridgehead centers, ( meso,d/l )‐2,2′,3,3′‐tetraphenyl‐4,4′,5,5′‐tetramethyl‐6,6′‐ bi s‐1‐ p hospha nor borna‐2,5‐dienyl (BIPNOR), can be obtained by thermolysis 1,1′‐bisphospholyl diphenylacetylene....
Transient 2H-phospholes are easily obtained from 1-R-1H-phospholes by a [1,5]-shift of the R-substituent phosphorus to α-carbons ring. They display cyclopentadiene-like chemistry: [4+2]-cycloaddition reactions with alkenes, alkynes, conjugated dienes and aldehydes, deprotonation give aromatic phospholide ions, reaction transition metal derivatives η5-phospholyl complexes. The resulting products have found some use in homogeneous asymmetric catalysis show promise field electroconducting polymers.
Two routes are described for the synthesis of (η4-1,5-cyclooctadiene)(η6-phosphinine)iron(0) complexes. A three-component reaction iron vapor with COD and 2-(trimethylsilyl)-4,5-dimethylphosphinine at low temperature yields 20% (COD)(2-(trimethylsilyl)-4,5-dimethylphosphinine)Fe(0) (3), whereas ligand exchange one in situ prepared metal product (COD)2Fe by or (η1-2-chloro-4,5-dimethylphosphinine)Cr(CO)5 gives corresponding (COD)(phosphinine)Fe(0) complexes more than 80% isolated yield. As...
Im Vergleich zur Chemie anderer wohlbekannter Elektronenmangelverbindungen wie der Carbene, Silylene und Nitrene ist die Phosphinidene RP: äußerst wenig erforscht. Ein kritisches Studium Literatur zeigt, daß als wahrscheinliche Ursachen sowohl eine schlechte Zugänglichkeit dieser Spezies auch ein ihnen eigener Mangel an Reaktivität anzunehmen sind. Die Ergebnisse von Rechnungen deuten darauf hin, es möglich ist, durch Komplexierung mit Übergangsmetall-Komplexfragmenten M(CO)5 (M Cr, Mo, W)...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStabilization of R-P(H)A species (A = OH, OR, S, NH2, NHR, NR2, Cl, Br, I) by complexation with chromium and tungsten pentacarbonylsAngela Marinetti Francois MatheyCite this: Organometallics 1982, 1, 11, 1488–1492Publication Date (Print):November 1982Publication History Published online1 May 2002Published inissue 1 November 1982https://pubs.acs.org/doi/10.1021/om00071a017https://doi.org/10.1021/om00071a017research-articleACS PublicationsRequest...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory and application of photoelectron spectroscopy. 60. Phospholes. Electronic structureWerner Schaefer, Armin Schweig, Francois MatheyCite this: J. Am. Chem. Soc. 1976, 98, 2, 407–414Publication Date (Print):January 1, 1976Publication History Published online1 May 2002Published inissue 1 January 1976https://pubs.acs.org/doi/10.1021/ja00418a015https://doi.org/10.1021/ja00418a015research-articleACS PublicationsRequest reuse permissionsArticle...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhosphole [2 + 2] and [4 dimerizations around metal carbonyl moieties. Structure chemistry of a new type exo dimersCatherine C. Santini, Jean Fischer, Francois Mathey, Andre MitschlerCite this: J. Am. Chem. Soc. 1980, 102, 18, 5809–5815Publication Date (Print):August 1, 1980Publication History Published online1 May 2002Published inissue 1 August 1980https://doi.org/10.1021/ja00538a018RIGHTS & PERMISSIONSArticle Views258Altmetric-Citations63LEARN...
Under Pd(II)/CuI cocatalysis, o-diarylphosphinophenylalkynes cyclize in boiling toluene via C–P bond cleavage and arylphosphination of the C≡C bond. This protocol provides an unprecedented atom- step-efficient access to optoelectronically biologically interesting benzophospholes.
A Ag/P-stereogenic phosphine-complex-catalyzed 1,3-dipolar cycloaddition of azomethine ylides with electron-deficient olefins is reported. In this reaction, highly functionalized pyrrolines a spiro-quaternary stereogenic center were obtained in good yields (up to 99%) excellent levels diastereo- >20:1 dr) and enantioselectivities >99% ee). The chirality adducts was controlled predominantly by the P-stereogenic phosphines.
The synthesis of polyphosphinine macrocycles, which consist a 16-membered ring with four phosphorus atoms (P4) and 12-membered three (P3), is described. Their high coordination ability demonstrated by the quantitative rhodium iridium cation complexes P4 macrocycle W(CO)3 complex P3 compound. Unlike other available macrocyclic ligands bearing oxygen, sulfur, di- or tricoordinate nitrogen, even as ligating atoms, are all essentially final sigma donors, these dicoordinate phosphorus-based...
Syntheses of octaethyldiphosphaferrocene 4 and tetraethylphosphaferrocene 5 are presented. Tetraethylzirconacyclopentadiene 1 reacts with PCl3 in dichloromethane to yield the 1-chlorotetraethylphosphole 2, which upon reduction by lithium excess, yields teraethylphospholide anion 3. Anion 3 was subsequently converted into or treatment FeCl2 [Fe(η6-C9H12)(η5-C5H5)][PF6] respectively. The structure diphosphaferrocene determined. Two conformations present cell: a C2 conformation (α = 51.1°) P...
Reaction of 2,5-diphenylphospholide anion with 2-chloromethylpyridine affords the 1-(2-methylpyridine)phosphole ligand. The corresponding cationic Ru(cymene)Cl chelate complex catalyzes hydrogen transfer process ketones very high TON and TOF numbers.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, structure, and reactivity of (phosphoranylidenephosphine)pentacarbonyltungsten complexes. Another access to the phosphorus-carbon double bondPascal Le Floch, Angela Marinetti, Louis Ricard, Francois MatheyCite this: J. Am. Chem. Soc. 1990, 112, 6, 2407–2410Publication Date (Print):March 1, 1990Publication History Published online1 May 2002Published inissue 1 March...