Longlong Fan

ORCID: 0000-0002-1748-1192
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About
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Research Areas
  • Ferroelectric and Piezoelectric Materials
  • Multiferroics and related materials
  • Microwave Dielectric Ceramics Synthesis
  • Thermal Expansion and Ionic Conductivity
  • Advanced Battery Materials and Technologies
  • Acoustic Wave Resonator Technologies
  • Catalytic Processes in Materials Science
  • Advancements in Battery Materials
  • Metal-Organic Frameworks: Synthesis and Applications
  • Magnetic and transport properties of perovskites and related materials
  • Electrocatalysts for Energy Conversion
  • Thermodynamic and Structural Properties of Metals and Alloys
  • Covalent Organic Framework Applications
  • Electronic and Structural Properties of Oxides
  • Supercapacitor Materials and Fabrication
  • Dielectric properties of ceramics
  • Advanced Photocatalysis Techniques
  • Nanomaterials for catalytic reactions
  • Copper-based nanomaterials and applications
  • Magnesium Oxide Properties and Applications
  • Advanced battery technologies research
  • Gas Sensing Nanomaterials and Sensors
  • CO2 Reduction Techniques and Catalysts
  • Advanced Condensed Matter Physics
  • Transition Metal Oxide Nanomaterials

Chinese Academy of Sciences
2022-2025

Eighth Affiliated Hospital of Sun Yat-sen University
2024-2025

Sun Yat-sen University
2023-2025

Institute of High Energy Physics
2022-2025

Second Affiliated Hospital of Hunan University of Traditional Chinese Medicine
2025

Beijing Institute of Technology
2022-2024

Maternal and Child Health Hospital of Xinjiang Uygur Autonomous Region
2024

Tianjin University of Technology
2024

China Spallation Neutron Source
2024

Technical Institute of Physics and Chemistry
2024

An epitaxial route to strain Strain can have a dramatic effect on the properties of materials. Zhang et al. introduced large in material PbTiO 3 by growing it epitaxially composite with PbO. On boundaries between two materials, their normally different lattice constants were matched, giving rise strain. As consequence, films exhibited very electric polarization even absence an field. The method may be applicable generating other functional Scence , this issue p. 494

10.1126/science.aan2433 article EN Science 2018-08-03

Abstract Freestanding 2D nanosheets with many unprecedented properties have been used in a myriad of applications. In this work, copper‐bearing metal‐organic frameworks (MOFs; viz., Cu‐BDC) are successfully fabricated via facile and benign methodology through using Cu 2 O nanocubes (≈60 nm) as confined metal ion source 1,4‐benzenedicarboxylic acid (H BDC) an organic linker. The gradually release + ions which further oxidized by the dissolved oxygen serve nutrients for construction...

10.1002/adfm.201806720 article EN Advanced Functional Materials 2019-01-08

Atomic-scale ferroelectrics are of great interest for high-density electronics, particularly field-effect transistors, low-power logic, and nonvolatile memories. We devised a film with layered structure bismuth oxide that can stabilize the ferroelectric state down to 1 nanometer through samarium bondage. This be grown on variety substrates cost-effective chemical solution deposition. observed standard hysteresis loop thickness ~1 nanometer. The thin films thicknesses range from 4.56...

10.1126/science.abm5134 article EN Science 2023-03-23

The success of electrochemical CO2 reduction at high current densities hinges on precise interfacial transportation and the local concentration gaseous CO2. However, creation efficient channels remains an unexplored frontier. In this study, we design synthesize hydrophobic porous Cu2O spheres with varying pore sizes to unveil nanoporous channel's impact gas transfer triple-phase interfaces. not only facilitate rapid but also trap compressed bubbles form abundant stable interfaces, which are...

10.1021/jacs.4c00082 article EN Journal of the American Chemical Society 2024-04-03

Abstract Understanding the relationship between electrocatalytic performance and local structure at molecular level is of great significance. Herein, a bifunctional electrocatalyst CuCA (CA = chloranilate) constructed for both nitrogen reduction reaction (NRR) nitrate (NO 3 RR). Combined structural analyses using Rietveld refinement, extended X‐ray adsorption fine (EXAFS), pair distribution function (PDF) revealed significant distortion Cu‐O 4 structure. Benefitting from unique structure,...

10.1002/adfm.202409064 article EN Advanced Functional Materials 2024-07-09

The rare physical property of zero thermal expansion (ZTE) is intriguing because neither nor contraction occurs with temperature fluctuations. Most ZTE, however, below room temperature. It a great challenge to achieve isotropic ZTE at high temperatures. Here we report the unconventional in cubic (Sc1-xMx)F3 (M = Ga, Fe) over wide range (linear coefficient (CTE), αl 2.34 × 10(-7) K(-1), 300-900 K). Such broad considerably negligible CTE has rarely been documented. present designed using...

10.1021/ja5077487 article EN Journal of the American Chemical Society 2014-09-18

The understanding of the negative thermal expansion (NTE) mechanism remains challenging but critical for development NTE materials. This study sheds light on ScF3, one most outstanding materials with NTE. local dynamics ScF3 has been investigated by a combined analysis synchrotron-based X-ray total scattering, extended absorption fine structure, and neutron powder diffraction. Very interestingly, we observe that (i) Sc–F nearest-neighbor distance strongly expands increasing temperature,...

10.1021/jacs.6b02370 article EN Journal of the American Chemical Society 2016-06-23

High-performance piezoelectric materials constantly attract interest for both technological applications and fundamental research. The understanding of the origin high-performance property remains a challenge mainly due to lack direct experimental evidence. We perform in situ high-energy x-ray diffraction combined with 2D geometry scattering technology reveal underlying mechanism perovskite-type lead-based materials. structural evidence reveals that electric-field-driven continuous...

10.1103/physrevlett.119.017601 article EN publisher-specific-oa Physical Review Letters 2017-07-07

The origin of the excellent piezoelectric properties at morphotropic phase boundary is generally attributed to existence a monoclinic in various systems. However, there exist no experimental studies that reveal role behavior phase-pure ceramics. In this work, single has been identified Pb(Zr,Ti)O_{3} ceramics room temperature by situ high-energy synchrotron x-ray diffraction, and its response electric field characterized for first time. Unique terms large intrinsic lattice strain negligible...

10.1103/physrevlett.116.027601 article EN publisher-specific-oa Physical Review Letters 2016-01-15

Tetragonal PbTiO(3)-BiFeO(3) exhibits a strong negative thermal expansion in the PbTiO(3)-based ferroelectrics that consist of one branch family materials. Its is much weakened, and then unusually transforms into positive as particle size slightly reduced. This transformation new phenomenon termal The detailed structure, temperature dependence unit cell volume, lattice dynamics samples were studied by means high-energy synchrotron powder diffraction Raman spectroscopy. Such unusual from to...

10.1103/physrevlett.110.115901 article EN Physical Review Letters 2013-03-14

A functional material with coexisting energetically equivalent phases often exhibits extraordinary properties such as piezoelectricity, ferromagnetism, and ferroelasticity, which is simultaneously accompanied by field-driven reversible phase transformation. The study on the interplay between transformation performance of great importance. Here, we have experimentally revealed important role in achieving enhanced electromechanical using situ high-energy synchrotron x-ray diffraction combined...

10.1103/physrevlett.120.055501 article EN publisher-specific-oa Physical Review Letters 2018-01-29

P2-structured Na0.67Ni0.33Mn0.67O2 (PNNMO) is a promising Na-ion battery cathode material, but its rapid capacity decay during cycling remains hurdle. Li doping in layered transition-metal oxide (TMO) materials known to enhance their electrochemical properties. Nevertheless, the influence of at different locations structure has not been investigated. Here, crystallographic role and impact lithium on sites PNNMO investigated LixNa0.67–yNi0.33Mn0.67O2+δ (0.00 ≤ x 0.2, y = 0, 0.1). Lithium...

10.1021/acs.chemmater.1c00569 article EN cc-by-nc-nd Chemistry of Materials 2021-06-02

Metal-organic frameworks (MOFs) have attracted enormous research interest as precursors/templates to prepare catalytic materials. However, the effect of structural isomerism MOFs on performance has rarely been studied. In this contribution, two topologically different Ce-benzene tricarboxylate (Ce-BTC) based same ligands and metal centers (viz., "MOF isomers") are prepared used porous supports load Pt nanoparticles (NPs), which shows distinct differences in porosities loading behaviors Pt....

10.1002/smll.202003597 article EN Small 2020-09-15

The capacity degredation in layered Ni-rich LiNixCoyMnzO2 (x ≥ 0.8) cathode largely originated from drastic surface reactions and intergranular cracks polycrystalline particles. Herein, we report a highly stable single-crystal LiNi0.83Co0.12Mn0.05O2 material, which can deliver high specific (∼209 mAh g-1 at 0.1 C, 2.8-4.3 V) meanwhile display excellent cycling stability (>96% retention for 100 cycles >93% 200 cycles). By combination of situ X-ray diffraction pair distribution function...

10.1021/acs.nanolett.1c03613 article EN Nano Letters 2021-11-23

An effective yet simple approach was developed to synthesize mesoporous PdBi nanocages for electrochemical applications. This technique relies on the subtle utilization of hydrolysis a metal salt generate precipitate cores in situ as templates navigating growth shells with assistance polymeric micelles. The are then obtained by excavating vulnerable and regulating crystals metallic skeletons. resultant exhibited excellent electrocatalytic performance toward ethanol oxidation reaction mass...

10.1039/d1sc06314f article EN cc-by Chemical Science 2022-01-01

Imposing phase engineering to porous materials is promising realize outperforming electrocatalytic performances by taking advantages of the merits nanoarchitecture and heterophase structure. In this work, amorphous/crystalline ruthenium oxide (RuO<sub>2</sub>) particles with rationally regulated heterophases are successfully prepared integrating into material synthesis. The resultant defect-rich RuO<sub>2</sub> exhibit excellent performance toward oxygen evolution reaction, achieving a low...

10.26599/nre.2023.9120070 article EN cc-by Deleted Journal 2023-05-05

Three-dimensional ordered porous Cu 2 O cuboctahedra were designed and synthesized for an enhanced C 2+ production from electrochemical CO reduction by the steric confinement effect.

10.1039/d3sc04840c article EN cc-by-nc Chemical Science 2023-01-01

Despite widely used as a commercial cathode, the anisotropic 1D channel hopping of lithium ions along [010] direction in LiFePO

10.1002/adma.202405956 article EN Advanced Materials 2024-05-31
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