A5051784205- Polyoxometalates: Synthesis and Applications
- Metal-Organic Frameworks: Synthesis and Applications
- Chemical Synthesis and Reactions
- Catalytic Processes in Materials Science
- Zeolite Catalysis and Synthesis
- Chemical Synthesis and Characterization
- Covalent Organic Framework Applications
- Nanomaterials for catalytic reactions
- Oxidative Organic Chemistry Reactions
- Catalysis for Biomass Conversion
- Physics of Superconductivity and Magnetism
- Rare-earth and actinide compounds
- Crystallization and Solubility Studies
- Advanced battery technologies research
- Metal-Catalyzed Oxygenation Mechanisms
- Advanced Sensor and Energy Harvesting Materials
- Carbon dioxide utilization in catalysis
- X-ray Diffraction in Crystallography
- Nuclear materials and radiation effects
- Asymmetric Hydrogenation and Catalysis
- Superconducting Materials and Applications
- Cancer therapeutics and mechanisms
- Catalysis and Oxidation Reactions
- Catalysis and Hydrodesulfurization Studies
- Chemotherapy-induced cardiotoxicity and mitigation
Dalian University of Technology
2023
Dalian University
2023
Jilin University
2017-2022
Jilin Medical University
2017-2019
Liaoning Shihua University
2016
Institute for Physics of Microstructures
1996
Three-dimensional porous scaffolds doped with the heteroatoms show excellent performances in energy conversion and storage. Herein, we report a green synthesis approach to construct oxygen-doped carbon electrodes by carbonizing oxygen-rich biomass material, sodium alginate. By precisely controlling carbonization temperature increasing mole ratio of α-L-guluronic acid units/β-D-mannuronic units alginate, morphology, oxygen content electrical conductivity as-obtained carbonaceous electrode are...
The encapsulation of polyoxomolybdic cobalt (CoPMA) and acid (PMA) within the Zr-based metal–organic frameworks (Zr-MOFs) UiO-bpy (connected by 2,2′-bipyridine-5,5′-dicarboxylic linkers) UiO-67 4,4′-biphenyldicarboxylic has been achieved direct solvothermal synthesis. Relatively high content polyoxometalate (POM) clusters (ranging from 12 to 15 wt % loading) could be introduced cages Zr-MOFs form uniform hybrid composites POM@Zr-MOFs. catalytic properties these were investigated for olefins...
Highly active catalysts for the dehydrogenation of formic acid were screened by using different amine-modified ZrSBA-15 as supports.
Developing an effective strategy to synthesize perfect titanosilicate TS-1 zeolite crystals with desirable morphologies, enriched isolated framework Ti species, and thus enhanced catalytic oxidation properties is a pervasive challenge in crystal engineering. We here used amino acid l-carnitine as growth modifier ethanol cosolvent regulate the morphologies coordination states of zeolites. During hydrothermal crystallization process, introduced can not only tailor anisotropic rates but also...
Two hybrid compounds, namely [Cu(3atrz)4][PMoMoVO40] (1) and [Cu(3atrz)6][PMo12O40]2 (2), were synthesized through hydrothermal reactions of 3-amino-1,2,4-triazole (3atrz), phosphomolybdic acid (PMA) appropriate copper salts. Crystal structure analysis reveals that compound 1 contains one-dimensional Cu-3atrz chains. The unit 2 a double calyx[3]arene-shaped hexamer, which is composed six two-coordinated CuI atoms 3atrz ligands. Both compounds present three-dimensional structure, built by the...
Pirarubicin (THP) is an anthracycline antibiotic, frequently used for the treatment of various human cancers. Unfortunately, clinical effectiveness THP limited by its dose-related cardiotoxicity. Apocynum leaf extract dried leaves venetum L. (a member Apocynaceae family, AVLE) that has many positive effects on cardiovascular system and widely consumed as tea in China. In this study we established a cardiactoxicity rat model, which showed pretreatment with AVLE attenuated THP-induced...
Designing highly efficient heterogeneous catalysts for the Friedel–Crafts acylation (FCA) reaction is a very significant subject development of green chemical industry. Herein, series nanosized iron carbide-encapsulated N-doped porous carbons (FexC/NC-n) have been prepared through high-temperature pyrolysis Fe-Zn bimetallic organic framework catalytic application in FCA aromatic compounds with acyl chlorides. A variety characterization results demonstrated that carbides (FexC), which are...
Carbon supported iron nanoparticles were prepared by pyrolyzing Fe-MOF material of Fe-diamine-dicarboxylic acid, and showed excellent catalytic activity stability for the Friedel–Crafts acylation aromatic compounds with acyl chloride.
Fe x Ni 1− @NC efficiently catalyzed Friedel–Crafts acylation for green synthesis of aromatic ketones and exploration the essence catalytically active sites.
The hybrid composite of cesium phosphomolybdate (CsPM) encapsulated in hierarchical porous UiO-66 (HP-UiO-66) was synthesized using a modulated solvothermal method. A variety characterization results demonstrated that the pore size distribution CsPM@HP-UiO-66 is broader than traditional microporous CsPM@UiO-66 and clusters are uniformly distributed octahedral cages HP-UiO-66. catalytic properties were investigated alkene epoxidation reaction with tert-butyl hydroperoxide (t-BuOOH) as an...
The chemical microenvironment of polyoxometalates (POMs) encapsulated in metal-organic frameworks (MOFs) presents a significant influence on their catalytic performance, which can be easily regulated by the linker functional group alteration or metal substitution MOFs. Herein, series cesium phosphomolybdate (CsPM) hierarchical porous UiO-66-X composites (CsPM@HP-UiO-66-X, X = H, 2CH3, 2OH, where represents alterable grafted onto benzene ring) were successfully synthesized through one pot...