A5016533944- Inorganic Fluorides and Related Compounds
- Crystal Structures and Properties
- Inorganic Chemistry and Materials
- Fiber-reinforced polymer composites
- Solid-state spectroscopy and crystallography
- Magnetism in coordination complexes
- Advanced Condensed Matter Physics
- Physics of Superconductivity and Magnetism
- Graphene research and applications
- Advancements in Battery Materials
- Luminescence Properties of Advanced Materials
- Silicone and Siloxane Chemistry
- X-ray Diffraction in Crystallography
- Magnetic and transport properties of perovskites and related materials
- Surface Modification and Superhydrophobicity
- Superconductivity in MgB2 and Alloys
- Fluorine in Organic Chemistry
- Material Science and Thermodynamics
- Crystallization and Solubility Studies
- History and advancements in chemistry
- Advanced Battery Materials and Technologies
- Superconducting Materials and Applications
- Advanced ceramic materials synthesis
- Multiferroics and related materials
- Magnetic Properties of Alloys
Institut de Chimie de la Matière Condensée de Bordeaux
2013-2024
Laboratoire de Chimie
1982-2022
Centre National de la Recherche Scientifique
2010-2021
Université de Bordeaux
2007-2020
Institut Polytechnique de Bordeaux
1996-2017
Institute of Chemistry and Chemical Technology
2013
Le Mans Université
2006-2009
Institut de Chimie
2009
Conditions Extrêmes et Matériaux Haute Température et Irradiation
2008
Laboratoire Catalyse et Spectrochimie
2008
Abstract X‐ray photoelectron spectra of several Palladium fluorine compounds have been investigated. In all these phases atoms a more or less distorted octahedral coordination. Satellite Structures generally occur in Pd 3d 3/2 and 5/2 levels broad F 1s peaks are observed. Shifts binding energies can be correlated with oxidation State covalency. XPS results clearly confirm the unusual +III NaPdF 4 , Na 3 PdF 6 K 2 .
Supercritical fluids exhibit a range of unusual properties that can be exploited for new reactions which are qualitatively different from those involving classical solid state chemistry. After giving brief introduction to these we describe their use in inorganic chemistry and related fields. We then present two examples concerning areas chemistry: (i) the formation novel nanoparticles; (ii) preparation open-structure oxy(hydroxy)fluorides, thus showing advantages this supercritical fluid...
Microwave-assisted synthesis has been applied for the preparation of aluminum hydroxyfluorides derived from β-AlF3. In course obtaining high-surface-area and homogeneous nanocrystallites, several key parameters have adjusted. A relationship between OH/F molar ratio stabilized allotropic forms pointed out. The surface area monitored depending on water/isopropanol volume ratio. microstructural properties as-prepared material thoroughly investigated highlighting X-ray line broadening arising...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal structure of rhodium pentafluorideBarbara K. Morrell, Allan Zalkin, Alain Tressaud, and Neil BartlettCite this: Inorg. Chem. 1973, 12, 11, 2640–2644Publication Date (Print):November 1, 1973Publication History Published online1 May 2002Published inissue 1 November 1973https://pubs.acs.org/doi/10.1021/ic50129a029https://doi.org/10.1021/ic50129a029research-articleACS PublicationsRequest reuse permissionsArticle...
New exotic phenomena have recently been discovered in oxides of paramagnetic Ir(4+) ions, widely known as 'iridates'. Their remarkable properties originate from concerted effects the crystal field, magnetic interactions and strong spin-orbit coupling, characteristic 5d metal ions. Despite numerous experimental reports, electronic structure these materials is still challenging to elucidate, not attainable isolated, but chemically inaccessible, [IrO6](8-) species (the simplest molecular...
High surface area aluminium hydroxyfluoride exhibiting the pyrochlore-type structure has been synthesized using microwave hydrothermal process. The optimization of crystallite size and material performed by varying some synthesis parameters, i.e. nature precursor, choice solvents addition a small amount ether. as-prepared solid contains nanosized particles as calculated XRD (average particle size: 12 nm) leading to around 140 m2 g−1. These results have confirmed TEM observations. framework...