A5059881619- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Boron and Carbon Nanomaterials Research
- MXene and MAX Phase Materials
- Magnetism in coordination complexes
- Carbon dioxide utilization in catalysis
- Crystallization and Solubility Studies
- Advanced Condensed Matter Physics
- Polyoxometalates: Synthesis and Applications
- Catalysis for Biomass Conversion
- Nanoplatforms for cancer theranostics
- biodegradable polymer synthesis and properties
- Crystallography and molecular interactions
- X-ray Diffraction in Crystallography
Ludwig-Maximilians-Universität München
2019-2024
Center for NanoScience
2019-2024
Nanosystems Initiative Munich
2019
University of Florida
2018
Recently, a small group of metal-organic frameworks (MOFs) has been discovered featuring substantial charge transport properties and electrical conductivity, hence promising to broaden the scope potential MOF applications in fields such as batteries, fuel cells supercapacitors. In combination with light emission, electroactive MOFs are intriguing candidates for chemical sensing optoelectronic applications. Here, we incorporated anthracene-based building blocks into MOF-74 topology five...
Abstract We report the synthesis of a unique cubic metal–organic framework (MOF), Fe‐HHTP‐MOF, comprising hexahydroxytriphenylene (HHTP) supertetrahedral units and Fe III ions, arranged in diamond topology. The MOF is synthesized under solvothermal conditions, yielding highly crystalline, deep black powder, with crystallites 300–500 nm size tetrahedral morphology. Nitrogen sorption analysis indicates porous material surface area exceeding 1400 m 2 g −1 . Furthermore, Fe‐HHTP‐MOF shows...
Biosuccinic acid, obtained<italic>via</italic>sugar fermentation, is cyclodimerized and oxidized to yield building blocks for aromatic polyesters with high glass transition temperatures.
In recent years, metal–organic frameworks (MOFs) with the structure MOF-74 have attracted much interest owing to their tunable pore aperture, high surface area, and electrical conductivity. The synthesis of well-defined, highly crystalline thin films is paramount importance for implementation into device-based applications such as in chemical sensing, optoelectronics, gas storage, separations. Here, we present (M = Zn2+, Mg2+, Ni2+, Co2+) by vapor-assisted conversion. MOF-74(M) were grown on...
Metal‐organic frameworks (MOFs) featuring significant electrical conductivity constitute a growing class of materials, with intriguing possible applications as porous semiconductors or supercapacitors. If such features are combined photoluminescence (PL), additional functionalities selective chemical sensing become accessible. Here, perylene diimide (PDI)‐based linear building blocks incorporated into the MOF‐74 topology three metal ions Zn 2+ , Mg and Ni resulting in new series MOFs, namely...
A flexible, electron-rich building block was integrated into the backbone of a metal–organic framework with MOF-74 topology. The comprises central anthracene core connected to acetylene groups. Solvothermal synthesis Mn2+ yields highly crystalline anthracene–ethyne-based structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photoluminescence.
Abstract We report the synthesis of a unique cubic metal–organic framework (MOF), Fe‐HHTP‐MOF, comprising hexahydroxytriphenylene (HHTP) supertetrahedral units and Fe III ions, arranged in diamond topology. The MOF is synthesized under solvothermal conditions, yielding highly crystalline, deep black powder, with crystallites 300–500 nm size tetrahedral morphology. Nitrogen sorption analysis indicates porous material surface area exceeding 1400 m 2 g −1 . Furthermore, Fe‐HHTP‐MOF shows...
A novel electrically conducting cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy- cata -hexabenzocoronene ( c -HBC) and Fe III ions is presented.
Fe-HHTP-MOF , ein einzigartiges kubisches metallorganisches Gerüst (MOF), das aus supertetraedrischen Hexahydroxytriphenylen(HHTP)-Einheiten und in Rautentopologie angeordneten FeIII-Ionen aufgebaut ist, wird im Forschungsartikel auf S. 18213 von Thomas Bein, Dana D. Medina et al. vorgestellt. ist hochkristallines, poröses tiefschwarzes Material, eine hohe elektrische Leitfähigkeit aufweist.