A5085347129- Advanced Chemical Physics Studies
- Photochemistry and Electron Transfer Studies
- Spectroscopy and Quantum Chemical Studies
- Inorganic Fluorides and Related Compounds
- Molecular Spectroscopy and Structure
- Inorganic and Organometallic Chemistry
- Spectroscopy and Laser Applications
- Solid-state spectroscopy and crystallography
- Mass Spectrometry Techniques and Applications
- Atomic and Molecular Physics
- Molecular spectroscopy and chirality
- Atmospheric Ozone and Climate
- Molecular Junctions and Nanostructures
- Analytical Chemistry and Sensors
- Various Chemistry Research Topics
- Chemical Reactions and Mechanisms
- Fluorine in Organic Chemistry
- Radioactive element chemistry and processing
- Electrochemical Analysis and Applications
- Laser-Matter Interactions and Applications
- Advanced Chemical Sensor Technologies
- Luminescence Properties of Advanced Materials
- Chemical Thermodynamics and Molecular Structure
- Nonlinear Optical Materials Research
- Catalysis and Oxidation Reactions
Université Grenoble Alpes
2025
CEA LETI
2013-2025
CEA Grenoble
1978-2025
Commissariat à l'Énergie Atomique et aux Énergies Alternatives
2013-2025
IMT Atlantique
2022-2024
Centre National de la Recherche Scientifique
2022-2024
Institut National de Physique Nucléaire et de Physique des Particules
2022-2024
Bipar
2021
Centre National pour la Recherche Scientifique et Technique (CNRST)
2021
Université Le Havre Normandie
2021
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPerfluoro effect in photoelectron spectroscopy. II. Aromatic moleculesC. R. Brundle, M. B. Robin, and N. A. KueblerCite this: J. Am. Chem. Soc. 1972, 94, 5, 1466–1475Publication Date (Print):March 1, 1972Publication History Published online1 May 2002Published inissue 1 March 1972https://pubs.acs.org/doi/10.1021/ja00760a008https://doi.org/10.1021/ja00760a008research-articleACS PublicationsRequest reuse permissionsArticle...
The high-resolution He i and ii photoelectron spectra of all fluoromethanes in the series CH4 to CF4 their deuterated analogs have been recorded are compared with Koopmans' theorem results near-Hartree–Fock calculations performed a Gaussian basis. agreement is very good general offers an unambiguous assignment almost bands observed. In particular, repeated correlations demonstrated between compositions orbitals from which electrons ejected characters resulting bands. Identifiable trends...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPerfluoro effect in photoelectron spectroscopy. I. Nonaromatic moleculesC. R. Brundle, M. B. Robin, N. A. Kuebler, and Harold BaschCite this: J. Am. Chem. Soc. 1972, 94, 5, 1451–1465Publication Date (Print):March 1, 1972Publication History Published online1 May 2002Published inissue 1 March 1972https://pubs.acs.org/doi/10.1021/ja00760a007https://doi.org/10.1021/ja00760a007research-articleACS PublicationsRequest reuse permissionsArticle...
The electronic states of cyclopropane, ethylene oxide, ethylenimine, and diaziridine were investigated using gas-phase condensed-phase vacuum ultraviolet spectroscopy, photoelectron Gaussian orbital self-consistent field calculations. Correlation the optical spectra cyclopropane with first band in its spectrum confirms presence Rydberg transitions involving excitation an electron from 3e′ sigma level. valence shell is complex but dominated by two very strong A11′ → 1E′, σ σ*, excitations....
The presence of a moderately strong band falling between the n→π* and π→π* (N→V1) transitions amide group has been observed for first time. All-electron SCF calculations in Gaussian bases aimed at assigning bands formamide suggest that new is an n→σ* excitation which σ* orbital Rydberg-like. A second π→σ* big-orbit transition follows excitation. In basis containing expanded orbitals, usual virtual orbital—configuration interaction predict every upper state will be Rydberg-orbital dimensions....
The first four bands in the gas-phase spectra of amides, carboxylic acids, and acyl fluorides are thought to be n → π*, 3s Rydberg, π 3p Rydberg excitations. That second fourth whereas third valence shell is demonstrated a comparison condensed-phase absorption circular dichroism spectra. All-electron, SCF Gaussian orbital calculations also presented which qualitatively explain trends HCOX molecules, predict several quantities interest, such as upper-state dipole moments magnetic transition...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNonlinear photochemistry in organic, inorganic, and organometallic systemsA. Gedanken, M. B. Robin, N. A. KueblerCite this: J. Phys. Chem. 1982, 86, 21, 4096–4107Publication Date (Print):October 1, 1982Publication History Published online1 May 2002Published inissue 1 October 1982https://pubs.acs.org/doi/10.1021/j100218a004https://doi.org/10.1021/j100218a004research-articleACS PublicationsRequest reuse permissionsArticle...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAntibonding .sigma.* valence MOs in the inner-shell and outer-shell spectra of fluorobenzenesA. P. Hitchcock, Fischer, Aharon. Gedanken, M. B. RobinCite this: J. Phys. Chem. 1987, 91, 3, 531–540Publication Date (Print):January 1, 1987Publication History Published online1 May 2002Published inissue 1 January 1987https://pubs.acs.org/doi/10.1021/j100287a009https://doi.org/10.1021/j100287a009research-articleACS PublicationsRequest reuse...
The weak mystery band found in the mono-olefins at 5–6 eV is here reassigned as a symmetry-allowed π→CH*(1Ag→1B2u) transition which CH* sigma upper orbital has considerable ns Rydberg character. Evidence supporting this assignment and militating against recent CH→π*(1Ag→1B3g) of Berry [J. Chem. Phys. 38, 1934 (1963)], only other plausible assignment, drawn from (a) ab initio calculations electronic spectrum energies ethylene large Gaussian bases, (b) study intensities vibronic shapes bands...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Structure, Spectra, and Magnetic Properties of Certain Iron Halide ComplexesA. P. Ginsberg M. B. RobinCite this: Inorg. Chem. 1963, 2, 4, 817–822Publication Date (Print):August 1, 1963Publication History Published online1 May 2002Published inissue 1 August 1963https://pubs.acs.org/doi/10.1021/ic50008a038https://doi.org/10.1021/ic50008a038research-articleACS PublicationsRequest reuse permissionsArticle Views450Altmetric-Citations92LEARN ABOUT...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe structure of an iron core analog ferritinG. W. Brady, C. R. Kurkjian, E. F. X. Lyden, M. B. Robin, P. Saltman, T. Spiro, and A. TerzisCite this: Biochemistry 1968, 7, 6, 2185–2192Publication Date (Print):June 1, 1968Publication History Published online1 May 2002Published inissue 1 June 1968https://pubs.acs.org/doi/10.1021/bi00846a022https://doi.org/10.1021/bi00846a022research-articleACS PublicationsRequest reuse permissionsArticle...
Indirect SCF calculations in a Gaussian basis of the lower π→σ* and σ→π* states ethylene demonstrate that excitations are Rydberg involve 3s 3p orbitals on carbon, whereas strictly valence shell. Calculations an identical using virtual-orbital approximation instead lead to excited which mixtures valence-shell configurations. The also show oscillator strengths π↔σ transitions should not exceed 0.1, twisted olefins, rotational excitations, general, smaller than those for excitation. e.ectronic...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIonization potentials of the tetraphosphorus moleculeC. R. Brundle, N. A. Kuebler, M. B. Robin, and Harold BaschCite this: Inorg. Chem. 1972, 11, 1, 20–25Publication Date (Print):January 1972Publication History Published online1 May 2002Published inissue 1 January 1972https://doi.org/10.1021/ic50107a005Request reuse permissionsArticle Views94Altmetric-Citations77LEARN ABOUT THESE METRICSArticle Views are COUNTER-compliant sum full text article...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic States of the AzoalkanesM. B. Robin, Robert R. Hart, and N. A. KueblerCite this: J. Am. Chem. Soc. 1967, 89, 7, 1564–1572Publication Date (Print):March 1, 1967Publication History Published online1 May 2002Published inissue 1 March 1967https://pubs.acs.org/doi/10.1021/ja00983a005https://doi.org/10.1021/ja00983a005research-articleACS PublicationsRequest reuse permissionsArticle Views129Altmetric-Citations75LEARN ABOUT THESE METRICSArticle...
Details of the positive ion fragmentation patterns acetaldehyde produced by collisionless multiphoton ionization are presented. Fragments generated in collection region a quadrupole mass spectrometer and analyzed with unit resolution. Daughter ions found corresponding to absorption up five photons. All fragment show same excitation spectrum, which closely resembles that obtained total both conventional parallel plate cell. Individual production depends strongly on laser power, going...
The 5pπ→6p Rydberg excitations of methyl iodide-h3 and -d3 are observed using multiphoton ionization spectroscopy as two-photon resonances when excited in the 28 000–32 000 cm−1 region. iodide abruptly cease at 32 cm−1, higher frequencies replaced by originating 2P1/2 2P3/2 levels iodine atom. A tentative assignment is also made for a resonance radical this replacement with those fragments beginning correlates directly onset one-photon intermediate band iodide. When pumping light frequency...
The lattice of the HI3·2C6H5CONH2 inclusion complex is triclinic (a=20.828 Å, b=9.885 c=9.588 α=95°46′, β=101°54′, γ=94°44′) with four molecules per unit cell. host structure consists dimerized benzamide stakced in such a way as to form long channels which guest tri-iodide ions are aligned. Each channel filled two chains polymerized end end, being separated by van der Waals distance, 4.6 Å. Within chains, bent about 3° from linear and asymmetric one bond 0.02 Å longer than other. distance...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPlatinblau [blue platinum amide complex]David Basset Brown, R. D. Burbank, and M. B. RobinCite this: J. Am. Chem. Soc. 1969, 91, 11, 2895–2902Publication Date (Print):May 1, 1969Publication History Published online1 May 2002Published inissue 1 1969https://pubs.acs.org/doi/10.1021/ja01039a012https://doi.org/10.1021/ja01039a012research-articleACS PublicationsRequest reuse permissionsArticle Views267Altmetric-Citations57LEARN ABOUT THESE...