A5054286416- Metal-Organic Frameworks: Synthesis and Applications
- Crystallography and molecular interactions
- Molecular Sensors and Ion Detection
- X-ray Diffraction in Crystallography
- Crystal structures of chemical compounds
- Zeolite Catalysis and Synthesis
- Radioactive element chemistry and processing
- Carbon Dioxide Capture Technologies
- Machine Learning in Materials Science
- Mass Spectrometry Techniques and Applications
- Analytical Chemistry and Chromatography
École Polytechnique Fédérale de Lausanne
2022-2025
Budapest University of Technology and Economics
2020
Homochiral metal-organic frameworks (MOFs) are exceptional media for heterogenous enantiodifferentation processes. Their rational design, however, is challenging. An available solution this moving from constitutive, structure-bearing, homochiral ligands to separating chiral selector and structural roles. This introduces combinatorial modulability, which the independent change of parts. Such modulability circumvents limitations designability. Further considerations narrow emphasis covalent...
Homochiral metal-organic frameworks (MOFs) are exceptional media for heterogenous enantiodifferentation processes. Modifying available achiral structure-bearing MOF scaffolds is a preferred method to extend this class of materials. However, reported post-synthetic covalent chiralizations generally lead uniform, site-specific modifications. The use chemically versatile modifying agents, like aldehydes, may instead result in the statistical formation non-uniform anchored products. Such...
The heat capacity of a material is fundamental property that significant practical importance. For example, in carbon capture process, the required to regenerate solid sorbent directly related material. However, for most materials suitable applications not known, and thus standard procedure assume same value all materials. In this work, we developed machine-learning approach accurately predict these materials, i.e., zeolites, metal-organic frameworks, covalent-organic frameworks. accuracy...
Homochiral metal-organic frameworks (MOFs) are exceptional media for heterogenous enantiodifferentation processes. Modifying available achiral structure-bearing MOF scaffolds is a preferred method to extend this class of materials. Reported postsynthetic covalent chiralizations generally lead uniform, site-specific modifications. The use chemically versatile modifying agents, like aldehydes, may instead result in the statistical formation non-uniform anchored products. In addition, such...
Homochiral metal-organic frameworks (MOFs) are exceptional media for heterogenous enantiodifferentation processes. Modifying available achiral structure-bearing MOF scaffolds is a preferred method to extend this class of materials. Reported postsynthetic covalent chiralizations generally lead uniform, site-specific modifications. The use chemically versatile modifying agents, like aldehydes, may instead result in the statistical formation non-uniform anchored products. In addition, such...
Seven dimethyl-substituted optically active pyridino-18-crown-6 ethers containing various substituents at position 4 of the pyridine ring were studied with regards to electron-donating and -withdrawing effects on enantiomeric recognition. In order compile this set compounds, we prepared four novel ethers, including an intermediate a new synthetic route for formerly reported crown ether. The discriminating ability these pyridino-crown C2-symmetry toward enantiomers protonated primary amines...