A5100679047- Silicone and Siloxane Chemistry
- Covalent Organic Framework Applications
- Metal-Organic Frameworks: Synthesis and Applications
- Luminescence and Fluorescent Materials
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Proteins in Food Systems
- Advanced Photocatalysis Techniques
- Synthesis and properties of polymers
- Peanut Plant Research Studies
- Advanced Chemical Sensor Technologies
- Membrane Separation and Gas Transport
- Spectroscopy and Chemometric Analyses
- Synthesis and characterization of novel inorganic/organometallic compounds
- Molecular Sensors and Ion Detection
- Chemical Synthesis and Characterization
- Advanced Sensor and Energy Harvesting Materials
- Advanced ceramic materials synthesis
- Spectroscopy Techniques in Biomedical and Chemical Research
- Food composition and properties
- Coconut Research and Applications
- Surface Modification and Superhydrophobicity
- Conducting polymers and applications
- Gas Sensing Nanomaterials and Sensors
- Catalytic Processes in Materials Science
Shandong University
2016-2025
Shandong Academy of Sciences
2025
Qilu University of Technology
2025
Binzhou Medical University
2025
Binzhou University
2025
Beijing Technology and Business University
2024-2025
China Southern Power Grid (China)
2024
Institute of Food Science and Technology
2016-2023
Chinese Academy of Agricultural Sciences
2012-2023
Ministry of Agriculture and Rural Affairs
2020-2023
Cage-like silsesquioxanes are considered to be ideal and versatile building blocks of hybrid materials due their unique structures excellent performance. This Perspective highlights recent advances in the field cage-like silsesquioxane-based materials, ranging from monomer functionalization preparation application. The existing issues reviewed challenges prospects this also discussed for further development exploitation.
To maintain sustainable development and improve resource utilization, there is an urgent need to recover gold using eco-friendly, efficient highly-selective method.
Epoxy was modified by an incompletely condensed polyhedral oligomeric silsesquioxane (POSS), and the phenyltrisilanol POSS [Ph7Si7O9(OH)3, POSS-triol] incorporated into epoxy networks with content of up to 30 wt %. The organic−inorganic hybrid composites were prepared via in situ polymerization monomers presence POSS-triol, which started from homogeneous solutions POSS-triol monomers. nanocomposites can be metal complex, aluminum triacetylacetonate ([Al]) being used as catalyst for reaction...
Abstract Summary: Octaaminophenyl polyhedral oligomeric silsesquioxane (OapPOSS) was used as a crosslinking agent together with 4,4 ′ ‐methylenebis‐(2‐chloroaniline) to prepare polyurethane networks containing POSS. Fourier transform infrared spectroscopy (FT‐IR), dynamic mechanical analysis (DMA) and thermogravimetric (TGA) were employed characterize the POSS‐reinforced polyurethane. The POSS‐containing PU displayed enhanced glass transition temperatures ( T g s) storage moduli of glassy...
A multifunctional hybrid porous material with a <italic>S</italic><sub>BET</sub> of 1910 cm<sup>2</sup> g<sup>−1</sup> was prepared by the Friedel–Crafts reaction octavinylsilsesquioxane (OVS) tetraphenylethene (TPE). It exhibits highly selective adsorption for dye molecules and fluorescence detection metal ions. moderate CO<sub>2</sub> capacity 1.42 mmol at 273.0 K/101 kPa is also found this material.
A novel nanoporous adsorbent THPP (a silsesquioxane-based, thiophene-containing hybrid porous polymer) shows highly efficient removal capability for wastewater treatment.
The study describes the synthesis of two porous hybrid polymers (abbreviated as DPPF-HPP and DPPOF-HPP) from Friedel-Crafts reaction octavinylsilsesquioxane with 1,1'-bis(diphenylphosphine)ferrocene (DPPF) 1,1'-bis(diphenylphosphine oxide)ferrocene (DPPOF), respectively. DPPOF-HPP possess surface areas about 890 780 m2 g-1, respectively, well similar pore structures coexisting micropores mesopores. They are excellent materials for high adsorption different dyes capacities 2280 mg g-1 Congo...
β-Alkoxyalcohols generated from epoxide ring-opening reactions are significant due to their enormous value as pharmaceutical intermediates and fine chemicals. Using a phenyl-substituted double-decker-type silsesquioxane the precursor, hybrid porous material (PCS-DDSQ) was synthesized through Scholl coupling reaction with an AlCl3 catalyst. Then, novel excellent Brønsted acid-derived solid catalysts (PCS-DDSQ-SO3H-x) were successfully obtained electrophilic aromatic substitution of...
Hydrogel electrolytes with antifreezing performance and excellent mechanical properties have become a research hotspot, but the general preparation process requires time energy consumption, limiting scope of applications. In this work, simple, universal, fast gelation based on sodium lignin sulfonate macromolecule–zinc ion (LS-Zn2+) self-catalytic system is developed. The catechol group LS can coordinate Zn2+ to form complexes accelerate establishment reversible oxidation–reduction, which...
A novel ferrocene-linked organic-inorganic hybrid porous polymer has been successfully prepared by Friedel-Crafts reaction of octavinylsilsesquioxane and ferrocene. The relationship structure/property was investigated FTIR, NMR, XRD, Brunauer-Emmett-Teller (BET) etc. obtained exhibited a high surface area 1015 m2 g-1 hierarchical pore structure. It could be applied to wastewater treatment with the absorption capacity up 1683 mg for Congo red (CR), 1083 crystal violet (CV), 1003 rhodamine B...
The purpose of the present study is to investigate changes in extraction yield, physicochemical properties, micronutrients content, oxidative stability and flavor quality cold pressed peanut oil extracted from microwave (MW) treated seeds (0, 1, 2, 3, 4, 5 min, 700 W). acid value peroxide MW-treated peanuts were slightly increased but far below limit Codex standard. Compared with untreated sample, a significant (p < 0.05) increase yield (by 33.75%), free phytosterols content 32.83%),...
Developing a material toward simultaneous detection and recovery of gold ions (Au(III)) is highly desirable for the economy environment. Herein, we report efficient dual-function Au(III) by simply introducing abundant imidazole thione thioether groups in one system. This material, that is, an thione-modified polyhedral oligomeric silsesquioxane (POSS-2), was prepared mild reaction imidazolium-containing POSS sulfur at ambient temperature. The POSS-2 suspension water can rapidly selectively...