A5043980404- Metal-Organic Frameworks: Synthesis and Applications
- Sulfur Compounds in Biology
- Covalent Organic Framework Applications
- Industrial Gas Emission Control
- Nanoplatforms for cancer theranostics
- X-ray Diffraction in Crystallography
- Advanced Nanomaterials in Catalysis
- Advancements in Battery Materials
- Magnetism in coordination complexes
- Advanced Battery Technologies Research
- Boron and Carbon Nanomaterials Research
- Advanced Battery Materials and Technologies
- Carbon Dioxide Capture Technologies
Cornell University
2021-2024
Ithaca College
2021
Hydrogen sulfide (H
Hydrogen sulfide (H2S) is an endogenous gasotransmitter with potential therapeutic value for treating a range of disorders, such as ischemia-reperfusion injury resulting from myocardial infarction or stroke. However, the medicinal delivery H2S hindered by its corrosive and toxic nature. In addition, small molecule donors often generate other reactive sulfur-containing species upon release, leading to unwanted side effects. Here, we demonstrate that release biocompatible porous solids, namely...
ConspectusMetal–organic frameworks (MOFs) are porous, crystalline materials constructed from organic linkers and inorganic nodes that have attracted widespread interest due to their permanent porosity highly modular structures. However, the large volumes of solvents additives, long reaction times, specialized equipment typically required synthesize MOFs hinder adoption in both academia industry. Recently, our lab has developed several user-friendly methods for gram-scale (1–100 g)...
Mechanochemical and solvothermal routes to the metal–organic framework Mg 2 ( m -dobdc) bearing coordinatively unsaturated Mg( ii ) sites are presented. The mechanochemical synthesis produces porous material exhibiting higher carbon dioxide uptake.
Lithium–sulfur (Li–S) batteries hold promise for next-generation energy storage due to their high theoretical density (∼2600 Wh kg–1). However, practical use is hindered by capacity loss from the polysulfide shuttle effect and poor efficiency slow kinetics. To overcome these challenges, we developed a novel sulfur host material featuring highly porous concave nanocubes derived Prussian blue analogue. By controlling annealing conditions, achieved surface area (up 248 m2 g–1), which enhances...
Hydrogen sulfide (H2S) is an endogenously produced gasotransmitter involved in many physiological processes that are integral to proper cellular functioning, including chemical signaling, redox balancing, and modification of vital proteins. Due its profound anti-inflammatory antioxidant properties, H2S plays important roles preventing inflammatory skin disorders improving wound healing. Transdermal delivery a therapeutically viable option for the man-agement such disorders. However, current...
Chlorine (Cl2) is a toxic and corrosive gas that both an essential reagent in industry potent chemical warfare agent. Materials can strongly bind Cl2 at low pressures are for industrial civilian personal protective equipment (PPE). Herein, we report the first examples of irreversible capture via dichlorination alkene linkages Zr-based metal–organic frameworks. Frameworks constructed from fumarate (Zr-fum) stilbene (Zr-stilbene) linkers retain long-range order accessible porosity after...
Metal–organic frameworks bearing coordinatively unsaturated Mg(II) sites are promising materials for gas storage, chemical separations, and drug delivery due to their low molecular weights lack of toxicity. However, there remains a limited number such MOFs reported in the literature. Herein, we investigate sorption properties understudied framework Mg2(m-dobdc) (dobdc4− = 4,6-dioxido-1,3-benzenedicarboxylate) synthesized under both solvothermal mechanochemical conditions. Both found be...
Chlorine (Cl2) is a toxic and corrosive gas that both an essential reagent in industry potent chemical warfare agent. Materials can strongly bind Cl2 at low pressures are for industrial civilian personal protective equipment (PPE). Herein, we report the first examples of irreversible capture via dichlorination alkene linkages Zr-based metal–organic frameworks (MOFs). Frameworks constructed from fumarate (Zr-fum) stilbene (Zr-stilbene) linkers retain long-range order accessible porosity after...