Irina L. Simakova

ORCID: 0000-0002-5138-4847
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About
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Research Areas
  • Catalysis for Biomass Conversion
  • Catalysis and Hydrodesulfurization Studies
  • Catalytic Processes in Materials Science
  • Catalysts for Methane Reforming
  • Mesoporous Materials and Catalysis
  • Nanomaterials for catalytic reactions
  • Asymmetric Hydrogenation and Catalysis
  • Catalysis and Oxidation Reactions
  • Biodiesel Production and Applications
  • Biofuel production and bioconversion
  • Zeolite Catalysis and Synthesis
  • Electrocatalysts for Energy Conversion
  • Carbon dioxide utilization in catalysis
  • Innovative Microfluidic and Catalytic Techniques Innovation
  • Glaucoma and retinal disorders
  • Enzyme Catalysis and Immobilization
  • Supercapacitor Materials and Fabrication
  • Chemical Synthesis and Reactions
  • Copper-based nanomaterials and applications
  • Oxidative Organic Chemistry Reactions
  • Gold and Silver Nanoparticles Synthesis and Applications
  • Advanced Chemical Physics Studies
  • nanoparticles nucleation surface interactions
  • Lignin and Wood Chemistry
  • Microbial Metabolic Engineering and Bioproduction

Åbo Akademi University
2008-2025

Boreskov Institute of Catalysis
2015-2024

Petro Mohyla Black Sea National University
2019-2020

Novosibirsk State University
2015-2020

Novosibirsk Tuberculosis Research Institute
2016-2020

National Chemical Laboratory
2019

Novosibirsk Institute of Organic Chemistry
2018

Siberian Branch of the Russian Academy of Sciences
2007-2016

Russian Academy of Sciences
2000-2014

Catalytic deoxygenation of neat stearic acid was studied at 360 °C under 10 bar argon or 5 vol % hydrogen in a fixed-bed reactor (down flow) using mesoporous-supported Pd/C (Sibunit) beads as catalyst. The results showed stable catalyst performance, giving about 15% conversion level acid. main liquid-phase product heptadecane, while the gaseous products were CO and CO2.

10.1021/ef900110t article EN Energy & Fuels 2009-08-20

Dry reforming of methane (DRM) is a promising method to utilize two greenhouse gases, such as CH4 and CO2, produce synthesis gas. In the current work, both monometallic Ni bimetallic Ni–Fe catalysts with different Fe/Ni molar ratios, synthesized by solution combustion (SCS) in DRM, were investigated using feed ratio CH4/CO2/Ar 1:1:1 at 600–900 °C. The characterized several physicochemical techniques X-ray diffraction (XRD), scanning electron microscopy energy-dispersive (SEM-EDX)...

10.1021/acs.iecr.3c00272 article EN cc-by Industrial & Engineering Chemistry Research 2023-07-18

The catalytic oxidation of arabinose to arabinonic acid was investigated in a recycled packed bed reactor address pH control issues continuous processes. Packed reactors are pivotal the valorization biomass, making shift from batch systems critical for industrial applications. setup used 2.1% Au/γ-alumina catalyst extrudates and incorporated tandem system with liquid recycling loop maintain controlled 8, ensuring optimal reaction conditions. Experiments were conducted at temperature 70 °C,...

10.24425/cpe.2025.153670 article EN Chemical and Process Engineering New Frontiers 2025-03-24

10.1134/s207005041103007x article EN Catalysis in Industry 2011-09-01

Carbon-supported mono- and bimetallic catalysts prepared via incipient wetness impregnation were systematically studied in aqueous-phase reforming (APR) of xylitol aiming at hydrogen production from biomass. The catalytic performance several VIII group metals their combinations, such as Pt, Ni, Pt-Ni, Re, Pt-Re, Ru, Pt-Ru, Pt-Co, was compared for APR a fixed-bed reactor 225 °C 29.7 bar (N2). Ni/C, Ru/C, Re/C displayed significantly lower activity to others. Activity selectivity H2 Pt-Ni/C,...

10.1021/acs.iecr.7b04937 article EN cc-by Industrial & Engineering Chemistry Research 2018-01-25

Isomerization of glucose, galactose and arabinose to corresponding keto-sugars was studied in the present work over a range heterogeneous catalysts.

10.1039/c7cy00281e article EN cc-by-nc Catalysis Science & Technology 2017-01-01

Hydrodeoxygenation (HDO) of isoeugenol was investigated over several Ni (Ni/SiO2, Ni/graphite) and Co (Co/SBA-15, Co/SiO2, Co/TiO2, Co/Al2O3) catalysts at 200 300 °C under 30 bar hydrogen pressure in a batch reactor. The were prepared by an impregnation method systematically characterized X-ray diffraction, transmission electron microscopy, scanning microscopy energy dispersive analysis, organic elemental, thermogravimetrical analysis before after the reaction. Analysis liquid, solid,...

10.1021/acssuschemeng.9b02108 article EN cc-by ACS Sustainable Chemistry & Engineering 2019-08-05

A set of low-cost monometallic Fe, Ni, and bimetallic Fe–Ni bifunctional H–Y-5.1 catalysts with different metal ratios were synthesized by sequential incipient wetness impregnation. The characterized in detail N2 physisorption, Fourier transform infrared spectroscopy pyridine, inductively coupled plasma optical emission spectroscopy, X-ray diffraction (XRD), transmission scanning electron microscopy (TEM–SEM), magic angle spinning nuclear magnetic resonance, photoelectron (XPS), Mössbauer...

10.1021/acsanm.3c00620 article EN cc-by ACS Applied Nano Materials 2023-06-05

Catalytic hydrogenation of vegetable oils was studied over Pd nanocomposite carbon catalysts. The mesoporous structure the support beneficial to achieve fast rates and desired cis/trans ratio monoenic products edible oil hydrogenation. preparation procedure developed for a slurry catalyst successfully utilized fixed bed applications. Industrial experience Pd/nanocomposite utilization in selective total nonedible is described.

10.1021/ie800663j article EN Industrial & Engineering Chemistry Research 2008-08-23

Deoxygenation of dilute and concentrated stearic acid over 2% Pd/C beads was performed in a continuous reactor at 300 °C 20 bar pressure Ar or 5% H2/Ar. Stable operation obtained H2 atmosphere, with 95% conversion 10 mol % dodecane 12% pure acid. Deactivation took place H2-deficient gas probably as result the formation unsaturated products coking pore system. Transient experiments step changes were performed: 1 h required for change to be visible liquid sampling, whereas steady states...

10.1021/ie201273n article EN Industrial & Engineering Chemistry Research 2011-09-02
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