- Advancements in Battery Materials
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- Advanced Battery Technologies Research
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Beijing Institute of Technology
2016-2025
Chongqing University of Technology
2019-2025
Zhuhai Institute of Advanced Technology
2024-2025
Lenovo (China)
2024
CITIC Group (China)
2022
Spice and Beverage Research Institute
2022
Chinese Academy of Tropical Agricultural Sciences
2022
Hainan University
2022
Hunan Agricultural University
2022
China National Center for Biotechnology Development
2008-2021
Ni-rich materials are appealing to replace LiCoO2 as cathodes in Li-ion batteries due their low cost and high capacity. However, there also some disadvantages for cathode such poor cycling rate performance, especially under voltage. Here, we demonstrate the effect of dual-conductive layers composed Li3PO4 PPy layered material. Fourier transform infrared spectroscopy X-ray photoelectron show that coating PPy. (NH4)2HPO4 transformed after reacting with surface lithium residuals formed an...
Li excess LiNi0.8Co0.1Mn0.1O2 was produced by sintering the Ni0.8Co0.1Mn0.1(OH)2 precursor with different amounts of a lithium source. X-ray photoelectron spectroscopy confirmed that greater Li+ leads to an increase in number Ni2+ ions. Interestingly, level Li+/Ni2+ disordering decreases content determined I003/I104 ratio diffraction patterns. The electrochemical measurement shows cycling stability and rate capability improve content. After cycling, impedance decreased charge transfer...
Best of both worlds: A heterostructured material is synthesized that comprises a core layered lithium-rich and an outer layer nanospinel material. This spinel/layered maximizes the inherent advantages 3D Li(+) insertion/extraction framework spinel structure high storage capacity structure. The exhibits super-high reversible capacities, outstanding rate capability excellent cycling ability.
Lack of high-performance cathode materials has become a technological bottleneck for the commercial development advanced Li-ion batteries. We have proposed biomimetic design and versatile synthesis ultrathin spinel membrane-encapsulated layered lithium-rich cathode, modification by nanocoating. The membrane is attributed to superior high reversible capacity (over 290 mAh g–1), outstanding rate capability, excellent cycling ability this even stubborn illnesses such as voltage decay thermal...
Hierarchical Li1.2Ni0.2Mn0.6O2 nanoplates with exposed {010} planes are designed and synthesized. In combination the advantages from hierarchical architecture electrochemically active of layered materials, this material satisfies both efficient ion electron transport thus shows superior rate capability excellent cycling stability. As a service to our authors readers, journal provides supporting information supplied by authors. Such materials peer reviewed may be re-organized for online...
High-capacity silicon has been regarded as one of the most promising anodes for high-energy lithium-ion batteries. However, it suffers from severe volume expansion, particle pulverization, and repeated solid electrolyte interphase (SEI) growth, which leads to rapid electrochemical failure, while size also plays key role here its effects remain elusive. In this paper, through multiple-physical, chemical, synchrotron-based characterizations, evolutions composition, structure, morphology,...
Tremendous studies have been engaged in exploring the application of solid-state electrolytes (SSEs) as it provides opportunities for next-generation batteries with excellent safety and high energy density. Among existing SSEs, newly developed halide SSEs become a hot spot owing to their ionic conductivity up 1 mS cm −1 stability against high-voltage cathode. As result, shown be promising candidates all-solid-state lithium (ASSLBs). Here, we review progress available modification strategies...
We doped Zr4+ ions in the outer layer of Ni0.8 Co0.1 Mn0.1 (OH)2 by coprecipitation. The distribution final cathode materials showed a gradient because ion migration during thermal treatment. was confirmed using various analysis methods (energy-dispersive X-ray spectroscopy, XRD, photoelectron and TEM), which implies that can not only occupy both transition metal slabs Li but also form Li2 ZrO3 on surface as highly ion-conductive layer. stabilize crystal structure strong Zr-O bond energy,...
The promising layered lithium-rich cathode materials, Li1.2Mn0.6−xNi0.2YxO2 (0 ≤ x 0.05), have been synthesized by substituting Mn4+ in Li1.2Mn0.6Ni0.2O2 with unusually large Y3+ ions, order to improve their cycling performance and rate capability. An oxalate co-precipitation method is adopted the synthetic process. X-ray diffraction (XRD) patterns show that, other than as a dopant, yttrium element found become Y2O3 or LiYO2 excess Y3+-doped samples. effects of content on electrochemical...
Abstract 3D coral-like, nitrogen and sulfur co-doped mesoporous carbon has been synthesized by a facile hydrothermal-nanocasting method to house for Li–S batteries. The primary doped species (pyridinic-N, pyrrolic-N, thiophenic-S sulfonic-S) enable this matrix suppress the diffusion of polysulfides, while interconnected network is favourable rapid transport both electrons lithium ions. Based on synergistic effect N, S co-doping conductive pathway, as-fabricated C/S cathodes yield excellent...
Nickel-rich cathode materials are among the most promising for high-energy lithium-ion batteries. However, their structural and thermodynamic stability, cycle rate performances still need to be further improved. In this study, rare earth element Ce is employed reinforce interface of Ni-rich both internally externally. High-valence Ce4+ can easily cause oxidization Ni2+ Ni3+ when doped into material owing its strong oxidation performance, thus reducing Li+ /Ni2+ mixing. addition, inert Ce3+...
The nickel-rich LiNi0.7Co0.15Mn0.15O2 material was sintered by Li source with the Ni0.7Co0.15Mn0.15(OH)2 precursor, which prepared via hydrothermal treatment after coprecipitation. intensity ratio of I(110)/I(108) obtained from X-ray diffraction patterns and high-resolution transmission electronmicroscopy confirm that particles have enhanced growth (110), (100), (010) surface planes, supply superior inherent Li+ deintercalation/intercalation. electrochemical measurement shows has high...
A modified Ni-rich Li[Ni0.8Co0.1Mn0.1]O2 cathode material with exposed {010} planes is successfully synthesized for lithium-ion batteries. The scanning electron microscopy images have demonstrated that by tuning the ammonia concentration during synthesis of precursors, primary nanosheets could be stacked along [001] crystal axis predominantly, self-assembling like multilayers. According to high-resolution transmission results, such a morphology benefits growth active final layered cathodes...