A5044416370- Catalysis and Hydrodesulfurization Studies
- Zeolite Catalysis and Synthesis
- Thermochemical Biomass Conversion Processes
- Catalysis for Biomass Conversion
- Catalytic Processes in Materials Science
- Catalysis and Oxidation Reactions
- Catalysts for Methane Reforming
- Polymer crystallization and properties
- Biodiesel Production and Applications
- Petroleum Processing and Analysis
- Recycling and Waste Management Techniques
- Granular flow and fluidized beds
- Biofuel production and bioconversion
- Process Optimization and Integration
- Thermal and Kinetic Analysis
- Microplastics and Plastic Pollution
- Fiber-reinforced polymer composites
- biodegradable polymer synthesis and properties
- Heat transfer and supercritical fluids
- Mesoporous Materials and Catalysis
- Mineral Processing and Grinding
- Groundwater and Isotope Geochemistry
- Cyclone Separators and Fluid Dynamics
- Particle Dynamics in Fluid Flows
- Membrane Separation and Gas Transport
University of the Basque Country
2014-2024
Instituto de Catálisis y Petroleoquímica
2007-2008
Consejo Nacional de Investigaciones Científicas y Técnicas
1997-2002
Universitat de Barcelona
1995
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStable operation conditions for gas-solid contact regimes in conical spouted bedsMartin Olazar, Maria J. San Jose, Andres T. Aguayo, Jose M. Arandes, and Javier BilbaoCite this: Ind. Eng. Chem. Res. 1992, 31, 7, 1784–1792Publication Date (Print):July 1, 1992Publication History Published online1 May 2002Published inissue 1 July 1992https://pubs.acs.org/doi/10.1021/ie00007a025https://doi.org/10.1021/ie00007a025research-articleACS PublicationsRequest...
A kinetic model has been proposed for the synthesis of dimethyl ether in a single reaction step from (H2 + CO) and CO2), parameters have calculated CuO−ZnO−Al2O3/γ-Al2O3 bifunctional catalyst. The suitably fits experimental results obtained an isothermal fixed bed reactor within wide range operating conditions: 225−325 °C; 10−40 bar; space time, 1.6−57.0 (g catalyst) h (mol H2)-1. crucial steps modeling are methanol CO)synthesis CO2) is not importantmethanol dehydration (very fast),...
The catalytic cracking of a blend raw bio-oil (20 wt %) from black poplar sawdust fast pyrolysis and vacuum gasoil (VGO, 80 has been studied. runs have performed in riser simulator reactor (RSR) under fluid (FCC) conditions; that is, 500–560 °C, catalyst to feed mass ratio 6 gcat (gfeed)–1 on dry basis, reaction times 3–10 s equilibrated commercial FCC catalyst. cofeeding effect quantified by comparing the yields product lumps individual components gaseous fraction gasoline lump VGO,...
The kinetics of the catalytic cracking plastic pyrolysis oil (PPO) over three FCC (fluid cracking) equilibrium commercial catalysts has been modeled. PPO comes from fast high-density polyethylene (HDPE). runs have carried out in a laboratory-scale reactor under conditions: 500–560 °C; catalyst/oil weight ratio 5 gcat gPPO-1; and contact time 1.5–6 s. Four different reaction schemes composed six lumps compared it obtained by statistical means that simplest one is most appropriate for...
The aim of this paper is for the production oils processed in refineries to come from pyrolysis real waste high plastic content rejected by recycling industry Basque Country (Spain). Concretely, streams were collected (1) a light packaging sorting plant, (2) industry, and (3) treatment plant electrical electronic equipment (WEEE). influence pre-treatments (mechanical separation operations) temperature on yield quality liquid fraction evaluated. In order study pre-treatment effect, samples...
The thermal and catalytic cracking of several plastic wastes (polypropylene, polystyrene, polystyrene−polybutadiene) dissolved in refinery LCO has been studied a riser simulator, under operating conditions (catalyst, temperature, contact time, C/O ratio) that are similar to commercial FCC units. results the product distribution show interest this strategy, which may be integrated into operation for large-scale tertiary exploitation wastes.
The nature and composition of the coke deposited on Pt–Pd catalysts supported acid carriers during hydroprocessing (hydrocracking hydrotreating) light-cycle oil (LCO) has been studied. Five types supports have used: a commercial cracking catalyst, alumina, Hβ zeolite, two HY zeolites (with different acidities). hydrocracking runs performed at 350 °C 50 bar for up to 24 h. characterization deactivating species catalyst used using temperature-programmed oxidation (TPO) coupled with mass...
ADVERTISEMENT RETURN TO ISSUEPREVArticleDesign factors of conical spouted beds and jet bedsMartin Olazar, Maria J. San Jose, Andres T. Aguayo, Jose M. Arandes, Javier BilbaoCite this: Ind. Eng. Chem. Res. 1993, 32, 6, 1245–1250Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Published inissue 1 June 1993https://pubs.acs.org/doi/10.1021/ie00018a034https://doi.org/10.1021/ie00018a034research-articleACS PublicationsRequest reuse permissionsArticle...
The deactivation of noble metal catalysts has been studied in the hydrocracking Light Cycle Oil (LCO) obtained as a byproduct FCC units. catalyst metallic functions are Pd, Pt, and Pt–Pd, which supported on acid materials different porous structure acidity (HY zeolite, Hβ amorphous alumina, an catalyst). reaction conditions 350 °C; 50 bar; H2/LCO molar ratio (nH2), 8.9 molH2 (molLCO)−1; space velocity (WHSV), 4 h–1; time stream, 300 min. roles function, support, and, particularly, by coke...
The hydrocracking of hydrotreated scrap tires pyrolysis oil (HT-STPO) has been studied aiming at high-quality refinery blends for alternative automotive fuels. runs have carried out with a PtPd/SiO2-Al2O3 catalyst in fixed-bed reactor 440–500 °C, 65 bar and space time 0.16 h. characterized by inductively coupled plasma optical emission spectroscopy, N2 adsorption–desorption isotherms, tert-butylamine (TPD), while coke both quantitatively qualitatively thermogravimetric-temperature-programmed...