A5074624879- Asymmetric Synthesis and Catalysis
- Advanced Photocatalysis Techniques
- Catalytic C–H Functionalization Methods
- Synthesis and Catalytic Reactions
- Oxidative Organic Chemistry Reactions
- Click Chemistry and Applications
- Chemical Synthesis and Analysis
- Chemical Synthesis and Reactions
- Advanced Nanomaterials in Catalysis
- Advanced oxidation water treatment
- Cyclopropane Reaction Mechanisms
- Asymmetric Hydrogenation and Catalysis
- Molecular Sensors and Ion Detection
- TiO2 Photocatalysis and Solar Cells
- Silk-based biomaterials and applications
- Covalent Organic Framework Applications
- Vanadium and Halogenation Chemistry
- Catalytic Processes in Materials Science
- Inorganic and Organometallic Chemistry
- Catalytic Alkyne Reactions
- Gas Sensing Nanomaterials and Sensors
- Innovative concrete reinforcement materials
- Catalytic Cross-Coupling Reactions
- Domain Adaptation and Few-Shot Learning
- Cancer-related molecular mechanisms research
Sichuan University of Science and Engineering
2025
The Affiliated Yongchuan Hospital of Chongqing Medical University
2024
Chongqing Medical University
2024
Wyższa Szkoła Technologii Informatycznych w Warszawie
2023
Hunan University
2014-2023
Zhengzhou University
2010-2023
Changzhou University
2022
Zhejiang Hospital
2022
Shaanxi Provincial Hospital of Traditional Chinese Medicine
2019
China XD Group (China)
2019
New 1,4-naphthalenedicarboxylic acid- and 3,5-bis(benzimidazol-2-yl)pyridine-appended Cd( ii ) Zn( coordination polymers were synthesized used as recoverable turn-off luminescent sensors for tetracycline.
A concise synthesis of spiro-cyclopropane compounds from indole derivatives and sulfur ylides has been developed via a dearomatization strategy. Moreover, the could be conveniently transformed to rearomatized in presence acids.
A divergent cascade annulation has been developed using readily available vinyl azides and carbazates with a wide range of substituents. Vinyl were successfully applied as bifunctional partners to prepare aza-pyrimidinones via 6-ring closure well construct polyfunctionalized imidazoles 5-ring N-substituted carbazates. The aza-heterocycles obtained high levels chemoselectivity excellent yields.
Understanding the general mechanism of metal-free and cofactor-free oxidases oxygenases catalyzed activation triplet O2 is one most challenging questions in field enzymatic catalysis. Herein, we have performed Quantum Mechanics/Molecular Mechanics (QM/MM) multiscale simulations to reveal detailed HOD (i.e., 1-H-3-hydroxy-4-oxoquinaldine 2,4-dioxygenase from Arthrobacter nitroguajacolicus Rü61a) decomposition N-heteroaromatic compounds. The complete catalytic includes four steps: (1) proton...
In this study, Co-modified alkalinized g-C3N4 (named Co-CNK-OH) was prepared for the Fenton-like photocatalytic degradation of tetracycline (TC) via a simple yet effective calcination–impregnation method. all samples CNK-OH with different Co2+ loadings, Co-CNK-OH catalyst optimal content (9%) exhibited highest catalytic activity, 87.1% removal and 50% efficiency total organic carbon (TOC). Mechanism studies revealed that 9%Co-CNK-OH had lower electrical resistance after alkalization...
Tandem Michael addition and Witting or Horner–Wadsworth–Emmons olefination initiated [3+3] annulation between vinyl azides allylic phosphorus ylides phosphoryl-stabilized carbanions has been developed.
An efficient annulation of vinyl azides with activated imines has been developed for the synthesis poly-functionalized imidazole derivatives.
A computational study was performed to explore the possible mechanisms of β-isocinchonine-catalyzed asymmetric C(sp2)-H allylation trisubstituted allenoates using Morita–Baylis–Hillman (MBH) carbonates for synthesis axially chiral tetrasubstituted allenoates. The calculated results indicate that most energetically favorable pathway includes (1) nucleophilic attack on MBH carbonate by β-isocinchonine, (2) BocO– dissociation, (3) stereoselective formation C–C bond, and (4) regeneration...
Abstract Immune thrombocytopenia (ITP), an acquired autoimmune disease, is characterized by immune-mediated platelet destruction. A biomarker a biological entity that contributes to disease pathogenesis and reflects activity. Metabolic alterations are reported be associated with the occurrence of various diseases. As metabolic biomarkers for ITP have not been identified. This study aimed identify metabolism-related differentially expressed genes as potential using bioinformatic analyses.The...
The possible mechanisms and the origin of regioselectivity N-heterocyclic carbene (NHC)-catalyzed double acylation reaction aromatic 1,2-diketones with α,β-unsaturated ketones have been theoretically studied using density functional theory.
Herein, novel luminol functional gold nanoparticles (lum-AuNPs) were quickly prepared in an alkaline solution with HAuCl4, which had the unique characteristics of uniform size and excellent luminescence properties. A self-made flow injection-chemiluminescence (FI-CL) system was established to study interaction between pepsin (Pep) five alkaloids (anisodamine, berberine, reserpine, jatrorrhizine matrine) using lum-AuNPs as CL probe. Based on abovementioned home-made system, possible...
Mannich-type addition of the titanium enolate derived from 2′-hydroxypropiophenone to N-tosylimines provided corresponding β-aminoketones in good excellent yields (60%–90%) and with >99 : <1 anti diastereoselectivity. A model for synthesis β-aminoketone as a predominant isomer based on has been developed. High selectivity is not independent electron-donating electron-withdrawing groups phenyl ring N-tosylimines. Noteworthy observation that influence second Lewis acid reaction opposite...
The DFT version of the Hückel-defined free valence (HFV) index has been suggested and successfully used for predicting origin chemoselectivity in selected organocatalytic reactions.
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