A5087697531- Catalytic C–H Functionalization Methods
- Synthetic Organic Chemistry Methods
- Catalytic Cross-Coupling Reactions
- Asymmetric Hydrogenation and Catalysis
- Organoboron and organosilicon chemistry
- Industrial Gas Emission Control
- Ammonia Synthesis and Nitrogen Reduction
- Heat Transfer and Boiling Studies
- Catalytic Processes in Materials Science
- Synthesis and Catalytic Reactions
- Radical Photochemical Reactions
- Various Chemistry Research Topics
- Carbon dioxide utilization in catalysis
- Sulfur-Based Synthesis Techniques
Universitat Jaume I
2022-2023
An effective visible-light-promoted iridium(III)-catalyzed hydrogen production from N-heterocycles is described. A single iridium complex constitutes the photocatalytic system playing a dual task, harvesting visible-light and facilitating C-H cleavage H2 formation at room temperature without additives. The presence of chelating C-N ligand combining mesoionic carbene along with an amido functionality in IrIII essential to attain transformation. Furthermore, also efficient catalyst for thermal...
The transition metal catalyzed dehydrogenation of alcohols to carboxylate salts and H2 is an attractive tool due their potential use as LOHCs (Liquid Organic Hydrogen Carriers). Still, most current methods encompass harsh conditions two steps synthesis. Herein, we describe efficient ruthenium(II) hydrogen production from benzylic the corresponding benzyl carboxylates assisted by visible light. Our photocatalytic system comprises a standalone N-heterocyclic carbene based piano stool ruthenium...
The activation of C–H bonds in a selective manner still constitutes major challenge from synthetic point view; thus, it remains an active area fundamental and applied research. Herein, we introduce ion mobility spectrometry mass spectrometry-based (IM-MS) approaches to uncover site-selective bond series metal complexes general formula [(NHC)LMCl]+ (NHC = N-heterocyclic carbene; L pentamethylcyclopentadiene (Cp*) or p-cymene; M Pd, Ru, Ir). at the N-bound groups NHC ligand is promoted upon...
Carboxylate-assisted Pd-catalyzed C-H bond activation constitutes a mild and versatile synthetic tool to efficiently selectively cleave inert bonds. Herein, we demonstrate simple method experimentally evaluate both reactivity selectivity in such systems using mass spectrometry (MS) methods. The N-heterocyclic carbene (NHC) cations [(NHC)PdX]
AN INSIDE VIEW OF INFRARED THERMOMETERS: APPROACH TO THE CHEMISTRY MATERIALS FOR HIGH LEVEL EDUCATION STUDENTS