Sam John

ORCID: 0000-0002-6652-7468
Publications
Citations
Views
---
Saved
---
About
Contact & Profiles
Research Areas
  • Corrosion Behavior and Inhibition
  • Concrete Corrosion and Durability
  • Hydrogen embrittlement and corrosion behaviors in metals
  • Conducting polymers and applications
  • Synthesis and Characterization of Heterocyclic Compounds
  • Advanced Sensor and Energy Harvesting Materials
  • Supercapacitor Materials and Fabrication
  • Analytical Chemistry and Chromatography
  • Inorganic and Organometallic Chemistry
  • Electrochemical Analysis and Applications
  • Hydrogels: synthesis, properties, applications
  • ZnO doping and properties
  • Synthesis of Tetrazole Derivatives
  • Advanced Photocatalysis Techniques
  • Analytical chemistry methods development
  • Electrospun Nanofibers in Biomedical Applications
  • Tribology and Wear Analysis
  • Analytical Chemistry and Sensors
  • Mass Spectrometry Techniques and Applications
  • Electrodeposition and Electroless Coatings
  • Adsorption and biosorption for pollutant removal
  • Supramolecular Self-Assembly in Materials
  • Biocrusts and Microbial Ecology
  • Polymer Nanocomposite Synthesis and Irradiation
  • Advanced Cellulose Research Studies

St John Berchmans University College
2025

Mahatma Gandhi University
2016-2024

University of Calicut
2010-2019

Government Medical College
2015-2019

Mahatma Gandhi University
2019

Indian Institute of Technology Kharagpur
1998

Inhibition of mild steel corrosion in 1N hydrochloric acid with 4-amino-6-methyl-3-thioxo-3,4-dihydro-1,2,4-triazin-5(2H)-one (AMTDT) and (4-amino-4H-1,2,4-triazole-3,5-diyl) dimethanol (ATD) was investigated by polarization (Tafel), electrochemical impedance (EIS), adsorption computational calculations at 27 °C. The mixed type inhibitor property these molecules potentiodynamic studies. It revealed that the effectiveness inhibition is influenced several factors such as nature state metal...

10.1016/j.ejpe.2016.10.005 article EN cc-by-nc-nd Egyptian Journal of Petroleum 2016-11-11

Inhibition of mild steel corrosion in 1 M hydrochloric acid with three different 1,2,4-triazine precursors were investigated by polarization (Tafel), electrochemical impedance (EIS), adsorption and computational calculations at room temperature. Polarization studies showed that these molecules act as mixed-type inhibitors. As the electron density around inhibitor molecule increases inhibition efficiency also increases. Obvious correlation found between some quantum chemical parameters such...

10.1039/c2ra20663c article EN RSC Advances 2012-01-01

Two N(4)-substituted thiosemicarbazones, anisoin- and furoin N(4)-methyl(phenyl) thiosemicarbazone (AMPTSC FMPTSC, respectively) have been tested as inhibitors on the corrosion of mild steel in 1 M HCl solution using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP) methods, adsorption studies surface morphological studies. Polarization measurements revealed mixed type inhibitor character. The inhibiting action these molecules is discussed terms blocking...

10.1016/j.ejpe.2016.05.012 article EN cc-by-nc-nd Egyptian Journal of Petroleum 2016-06-18

Abstract The interaction of 4‐amino‐4H,3,5‐di(methoxy)‐1,2,4‐triazole (ATD), (4‐(benzylideneamino)‐4H‐1,2,4‐triazole‐3,5‐diyl) dimethanol (BATD), and (4‐(4‐(dimethylamino) benzylideneamino))‐4H‐1,2,4‐triazole‐3,5‐diyl) (DBATD) on copper in 1 N sulfuric acid was investigated by potentiodynamic polarization (Tafel), ac impedance (EIS), molecular dynamic (MD) studies, quantum chemical calculations at 300 K. Polarization studies clearly showed that ATD, BATD, DBATD act as mixed type inhibitors....

10.1002/maco.201005938 article EN Materials and Corrosion 2011-03-24

The interaction and corrosion inhibition properties of methyl carbamate on copper metal in 1 N HNO3 have been studied by polarization, electrochemical impedance spectroscopy (EIS), adsorption, surface studies computational calculations at 300 K. Polarization showed that act as a cathodic type inhibitor. inhibitive action this molecule is discussed terms blocking the electrode adsorption inhibitor molecules obeying Langmuir isotherm. In addition, local reactivity, analyzed through Fukui...

10.1039/c3ra40922h article EN RSC Advances 2013-01-01

Effective inhibition of metallic corrosion to prevent its consequent loss is one the serious apprehensions for industries in modern world. This paper analyses application poly(2-ethyl-2-oxazoline) (PEOX) as an effective inhibitor corrosion, when it made be contact with surfaces mild steel (MS). The sustainability MS against 0.1 M Hydrochloric acid solution presence known concentration PEOX assessed by potentiodynamic polarization (PDP) measurements, linear studies (LPR), and electrochemical...

10.1016/j.heliyon.2020.e05560 article EN cc-by-nc-nd Heliyon 2020-11-01

Abstract The present study describes the inhibition of aluminium in 1 N HNO 3 with different concentrations 1, 2, 4‐triazine precursors 4‐amino‐6‐methyl‐3‐thioxo‐3,4‐dihydro‐1,2,4‐triazin‐5(2H)‐one (AMTDT) and 4‐amino‐6‐benzyl‐3‐thioxo‐3,4‐dihydro‐1,2,4‐triazin‐5(2H)‐one (ABTDT) using electrochemical impedance spectroscopy adsorption studies quantum chemical calculations at 298 K. As electron density around inhibitor molecule increases due to substitution, efficiency also correspondingly....

10.1002/maco.201206782 article EN Materials and Corrosion 2012-11-05

The inhibition of mild steel corrosion in 0.1 N nitric acid by the bis-1,2,4-triazole precursors EBATT and BBATT was investigated potentiodynamic polarization (Tafel), electrochemical impedance spectroscopy (EIS), adsorption, quantum chemical calculations at 300 K. Polarization studies showed that these molecules act as mixed-type inhibitors. As electron density around inhibitor increases due to substitution, efficiency also increases. approach used calculate electronic properties ascertain...

10.1021/ie301963a article EN Industrial & Engineering Chemistry Research 2012-12-03

The corrosion protection efficiency of MBIMOT, 5-((2-methyl-1H-benzo[d]imidazol-1-yl) methyl)-1, 3, 4 oxadiazole-2-thiol towards mild steel (MS) in HCl and its variation with inhibitor concentration, acid concentration temperature were assessed by weight loss electrochemical methods. Corrosion rate found to decrease increasing the MBIMOT increase concentration. Electrochemical impedance spectroscopy studies revealed that adsorption on MS surface follow Langmuir isotherm. mixed type behavior...

10.1080/01694243.2019.1637169 article EN Journal of Adhesion Science and Technology 2019-07-16
Coming Soon ...