A5093712748- Inorganic Chemistry and Materials
- MXene and MAX Phase Materials
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Ferrocene Chemistry and Applications
- 2D Materials and Applications
- Synthesis and characterization of novel inorganic/organometallic compounds
- Iron-based superconductors research
- Ferroelectric and Piezoelectric Materials
- Magnetism in coordination complexes
University of Geneva
2024-2025
University of Tübingen
2024
Isotypic compounds [Mg3(H2O)14][M(CN)6]2·4HMT·xH2O (HMT = hexamethylentetramine or urotropine) with M Fe, Cr and Co have been crystallized from aqueous solutions. The iron compound (M Fe) is most remarkable because it crystallizes distinctive thin, deep‐yellow crystal plates. structure of [Mg3(H2O)14][Fe(CN)6]2(C6H12N4)4(H2O)4.18 was solved refined by X‐ray single‐crystal diffraction, revealing the tetragonal space group P‾4c2, a 14.8156(5) Å, c 32.890(3) Å (Z 4). contains finite...
We herein report on a fast and convenient soft-chemical synthesis approach towards large 1T-CrTe
Abstract The tetracyanamidometallates Li 4 [ T (CN 2 ) ] with =Si, Ge were prepared by solid‐state metathesis (SSM) reactions between I and ). new compounds are obtained as crystalline phases in high yields represent the most basic examples of family tetracyanamidometallates. formation these compounds, via SiI ), is analyzed means differential scanning calorimetry (DSC). [Si(CN 4− ion structure can be considered an analogue to [SiO SiO . crystal structures solved refined isotypically on...
The Cover Feature shows a small section of layer in the structure new Li4[Si(NCN)4]. solid-state metathesis reaction (SSM) mixtures SiI4 and Li2(CN2) are controlled situ by differential scanning calorimetry (DSC), revealing polymeric stage subsequent product formation under successive elimination LiI. Tetracyanamidosilicates closely related to orthosilicates can exist with several cations PSE. As demonstrated our previous research, metal tetracyanamidosilicates act as robust host structures...