A5078387899- Catalytic Processes in Materials Science
- Advanced oxidation water treatment
- Catalysis and Oxidation Reactions
- Electrochemical Analysis and Applications
- Environmental remediation with nanomaterials
- Water Quality Monitoring and Analysis
- Nanomaterials for catalytic reactions
- Carbon dioxide utilization in catalysis
- Catalysis and Hydrodesulfurization Studies
- Advanced Photocatalysis Techniques
- Ionic liquids properties and applications
- Electrocatalysts for Energy Conversion
- TiO2 Photocatalysis and Solar Cells
- Gold and Silver Nanoparticles Synthesis and Applications
- Industrial Gas Emission Control
- Metal-Organic Frameworks: Synthesis and Applications
- Analytical Chemistry and Sensors
- Hydrogen Storage and Materials
- Radioactive element chemistry and processing
- Iron oxide chemistry and applications
- Nanoporous metals and alloys
- Covalent Organic Framework Applications
- Higher Education Teaching and Evaluation
- Additive Manufacturing and 3D Printing Technologies
- Innovative Microfluidic and Catalytic Techniques Innovation
Universidad Autónoma de Madrid
2015-2024
Delft University of Technology
2008
Universidad Complutense de Madrid
2002-2005
A kinetic model for formic acid (FA) decomposition over a commercial 10 wt% Pd/AC catalyst has been developed to describe the hydrogen production and understand deactivation mechanism. The data were obtained in batch slurry reactor absence of mass transfer limitation at: CFA,0 = 0.25–2 M, CCAT 1 g L−1, T 25–85 ºC P atm. stability was studied successive cycles at different temperatures. Fresh, used regenerated catalysts deeply characterized gain insight into activity, selectivity stability....
This work reports on the evolution of toxicity phenol-containing simulated wastewater upon catalytic wet oxidation with a commercial copper-based catalyst (Engelhard Cu-0203T). The results study show that this enhances detoxification, in addition to its effect rate. EC50 values intermediates identified throughout route phenol have been determined and used predict oxidation. predicted compared ones measured directly from aqueous solution during process. To learn about routes oxidation,...
This work deals with the evolution of intermediates and ecotoxicity upon Fenton's oxidation phenol in aqueous solution. The EC50 values identified pathway have been measured. Some these compounds, mainly hydroquinone p-benzoquinone, showed toxicity levels much higher than itself. Depending on operating conditions, could be completely transformed into organic acids, oxalic formic. Ecotoxicity substantially lower those expected from chemical composition were measured reaction samples. is...
Abstract BACKGROUND The breakdown of imidazolium ionic liquids ( ILs ) by Fenton oxidation has been demonstrated, but using unaffordable doses hydrogen peroxide H 2 O ). literature studies so far do not report on the evolution total organic carbon TOC and ecotoxicity. Therefore, potential application process for degradation still remains an open question. This work investigates feasibility treatment aqueous effluents containing imidazolium‐based different structures, represented length alkyl...
A semi-crystalline iron-based metal-organic framework (MOF), in particular Fe-BTC, that contained 20 wt.% Fe, was sustainably synthesized at room temperature and extensively characterized. Fe-BTC nanopowders could be used as an efficient heterogeneous catalyst for the synthesis of dihydroxybenzenes (DHBZ), from phenol with hydrogen peroxide (H2O2), oxidant under organic solvent-free conditions. The influence reaction temperature, H2O2 concentration dose were studied hydroxylation performance...