Hannah L. Smith

ORCID: 0000-0002-7290-8865
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About
Contact & Profiles
Research Areas
  • Organic Electronics and Photovoltaics
  • Conducting polymers and applications
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Organic Light-Emitting Diodes Research
  • Perovskite Materials and Applications
  • Luminescence and Fluorescent Materials
  • Silicon Nanostructures and Photoluminescence
  • Chalcogenide Semiconductor Thin Films
  • Covalent Organic Framework Applications
  • Molecular Junctions and Nanostructures
  • Nanowire Synthesis and Applications
  • Metal-Organic Frameworks: Synthesis and Applications
  • Peace and Human Rights Education
  • Semiconductor materials and devices
  • Quantum Dots Synthesis And Properties
  • Advancements in Semiconductor Devices and Circuit Design
  • Photochromic and Fluorescence Chemistry

Princeton University
2017-2022

Princeton Public Schools
2020

Wake Forest University
2017

Solution-processable electronic devices are highly desirable due to their low cost and compatibility with flexible substrates. However, they often challenging fabricate the hydrophobic nature of surfaces constituent layers. Here, we use a protein solution modify surface properties improve wettability fluoropolymer dielectric Cytop. The engineered hydrophilic is successfully incorporated in bottom-gate solution-deposited organic field-effect transistors (OFETs) hybrid organic-inorganic...

10.1021/acsami.7b03232 article EN ACS Applied Materials & Interfaces 2017-05-09

Abstract n‐Doping electron‐transport layers (ETLs) increases their conductivity and improves electron injection into organic light‐emitting diodes (OLEDs). Because of the low affinity large bandgaps ETLs used in green blue OLEDs, n‐doping has been notoriously more difficult for these materials. In this work, polymer poly[(9,9‐dioctylfluorene‐2,7‐diyl)‐ alt ‐(benzo[2,1,3]thiadiazol‐4,7‐diyl)] (F8BT) is demonstrated via solution processing, using air‐stable n‐dopant...

10.1002/adfm.202000328 article EN Advanced Functional Materials 2020-02-27

2D polymers (2DPs) are promising as structurally well-defined, permanently porous, organic semiconductors. However, 2DPs nearly always isolated closed shell species with limited charge carriers, which leads to low bulk conductivities. Here, the conductivity of two naphthalene diimide (NDI)-containing 2DP semiconductors is enhanced by controllably n-doping NDI units using cobaltocene (CoCp2 ). Optical and transient microwave spectroscopy reveal that both as-prepared NDI-containing...

10.1002/adma.202101932 article EN Advanced Materials 2021-12-01

Transparent photovoltaic cells are an emerging technology that can provide point-of-use electricity generation for building-integrated applications. While most transparent solar to date target absorption of the photon-rich near-infrared portion spectrum, these devices compromise color neutrality and transparency because parasitic long-wavelength visible light. One solution eliminate is employ materials absorb near-ultraviolet light with sharper cutoffs. Herein, we demonstrate organic donor...

10.1021/acsenergylett.1c02244 article EN ACS Energy Letters 2021-12-09

To accelerate materials discovery, computational methods such as inverse design, are used to design UV-absorbing coronene based derivatives that, following synthesis achieve high open-circuit voltages and visible transparencies.

10.1039/d0tc05092j article EN Journal of Materials Chemistry C 2020-12-11

Singlet fission can split a high energy singlet exciton and generate two lower triplet excitons. This process has shown near 200 percent yield. Sensitizing solar cells with material, it potentially increase the power conversion efficiency limit from 29 to 35 percent. in tetracene is known be efficient, of excitons are energetically matched silicon bandgap. In this work, we designed an optical measurement external magnetic field determine efficiencies transfer silicon. Using method, have...

10.1117/12.2567365 article EN 2020-08-20

In the standard configurations of metal halide perovskite solar cell, active layer, or absorber, follows a p-i-n n-i-p electronic structure that is designed to enhance separation and extraction photo-induced charge carriers. The control Fermi level position across film, between electron hole transport layers, therefore paramount importance. Direct localized doping in perovskites being still elusive, design structures has so far relied predominantly on surface interface as well work function...

10.1063/5.0060129 article EN publisher-specific-oa Applied Physics Reviews 2021-10-01

Doping has proven to be a critical tool for enhancing the performance of organic semiconductors in devices like light-emitting diodes. However, challenge working with high-ionization-energy (IE) is find p-dopants correspondingly high electron affinity (EA) that will improve conductivity and charge carrier transport film. Here, we use an oxidant been recently recognized very strong p-type dopant, hexacyano-1,2,3-trimethylene-cyclopropane (CN6-CP). The EA CN6-CP previously estimated via cyclic...

10.1021/acsami.1c21302 article EN ACS Applied Materials & Interfaces 2022-01-03
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