Abstract High-power Na-ion batteries have tremendous potential in various large-scale applications. However, conventional charge storage through ion intercalation or double-layer formation cannot satisfy the requirements of such applications owing to slow kinetics and small capacitance double layer. The present work demonstrates that pseudocapacitance nanosheet compound MXene Ti 2 C achieves a higher specific capacity relative capacitor electrodes rate capability electrodes. By utilizing as...

Recently, battery technology has come to require a higher rate capability. The main difficulty in high-rate charge−discharge experiments is kinetic problems due the slow diffusion of Li-ions electrodes. Nanosizing popular way achieve surface area and shorter Li-ion length for fast diffusion. However, while various nanoelectrodes that provide excellent capability have been synthesized, size-controlled synthesis systematic study nanocrystalline LiCoO2 not carried out because controlling size....

MXene, a family of layered compounds consisting nanosheets, is emerging as an electrode material for various electrochemical energy storage devices including supercapacitors, lithium-ion batteries, and sodium-ion batteries. However, the mechanism its reaction not yet fully understood. Herein, using solid-state 23Na magic angle spinning NMR density functional theory calculation, we reveal that MXene Ti3C2Tx in nonaqueous Na+ electrolyte exhibits reversible intercalation/deintercalation into...

The development of efficient electrochemical energy storage (EES) devices is an important sustainability issue to realize green electrical grids. Charge mechanisms in present EES devices, such as ion (de)intercalation lithium-ion batteries and electric double layer formation capacitors, provide insufficient efficiency performance for grid use. Intercalation pseudocapacitance (or redox capacitance) has emerged alternative chemistry advanced devices. occurs through bulk reactions with...

Extending the pyrophosphate chemistry for rechargeable Na-ion batteries, here we report synthesis and electrochemical characterization of Na2FeP2O7, a novel Fe-based cathode material sodium batteries. Prepared by conventional solid-state as well solution-combustion (at 600 °C), Na2FeP2O7 adopts triclinic structure (space group: P-1) with three-dimensional channels running along [100], [− 110] [01-1] directions. With no further optimization, as-synthesized was found to be electrochemically...

Abstract Sodium-ion batteries are attractive energy storage media owing to the abundance of sodium, but low capacities available cathode materials make them impractical. Sodium-excess metal oxides Na 2 MO 3 (M: transition metal) appealing that may realize large through additional oxygen redox reaction. However, general strategies for enhancing capacity poorly established. Here using two polymorphs RuO , we demonstrate critical role honeycomb-type cation ordering in . Ordered with...

Pseudocapacitance is a key charge storage mechanism to advanced electrochemical energy devices distinguished by the simultaneous achievement of high capacitance and charge/discharge rate using surface redox chemistries. MXene, family layered compounds, pseudocapacitor‐like electrode material which exhibits through exceptionally fast ion accessibility sites. Here, authors demonstrate steric chloride termination in MXene Ti 2 C T x ( : groups) open interlayer space between individual 2D units....

Prussian blue analogues (PBAs) have recently been proposed as electrode materials for low-cost, long-cycle-life, and high-power batteries. However, high-capacity bimetallic examples show poor cycle stability due to surface instabilities of the reduced states. The present work demonstrates that, relative single-component materials, higher capacity longer are achieved when using analogue core@shell particle heterostructures cathode material Li-ion storage. Particle with a size dispersion...

Abstract Increasing the energy density of rechargeable batteries is paramount importance toward achieving a sustainable society. The present limitation owing to small capacity cathode materials, in which (de)intercalation ions charge‐compensated by transition‐metal redox reactions. Although additional oxygen‐redox reactions oxide cathodes have been recognized as an effective way overcome this limit, irreversible structural changes that occur during charge/discharge cause voltage drops and...

Lithium-ion batteries are key energy-storage devices for a sustainable society. The most widely used positive electrode materials LiMO2 (M: transition metal), in which redox reaction of M occurs association with Li+ (de)intercalation. Recent developments Li-excess transition-metal oxides, deliver large capacity more than 200 mAh/g using an extra oxygen, introduce new possibilities designing higher energy density lithium-ion batteries. For better engineering this fascinating chemistry, it is...

Abstract Electric double-layer capacitors are efficient energy storage devices that have the potential to account for uneven power demand in sustainable systems. Earlier attempts improve an unsatisfactory capacitance of electric focused on meso- or nanostructuring increase accessible surface area and minimize distance between adsorbed ions electrode. However, dielectric constant electrolyte solvent embedded electrode surface, which also governs capacitance, has not been previously exploited...

The effect of crystallite size on Li-ion insertion in electrode materials is great interest recently because the need for nanoelectrodes higher-power rechargeable batteries. We present a systematic study electrochemical properties LiMn2O4. Accurate control nanocrystalline LiMn2O4, which realized by hydrothermal method, significantly alters phase diagram as well voltage. Nanocrystalline LiMn2O4 with extremely small 15 nm cannot accommodate domain boundaries between Li-rich and Li-poor phases...

The discovery of a new electrode material that provides reversible Li ion insertion/extraction reaction is primary importance for batteries. In this report, electrochemical in valence tautomeric Prussian blue analogues AxMny[Fe(CN)6] (A: K, Rb) was investigated. Ex situ X-ray diffraction experiments revealed the K salt without tautomerism exhibits with redox process an Fe ion, while Rb Mn ion. Regardless redox-active metal ions, highly storage achieved. electronic structure changes during...

The development of high-performance Na-ion intercalation electrodes has been required recently because batteries hold much promise for inexpensive and efficient energy storage, which can be deployed in a power grid. For both optimization better understanding the electrode materials, it is indispensable to clarify relationship between electronic state electrochemical properties systematically. In this work, we studied P2–Na2/3MnyCo1–yO2 detail. A series P2 phases was successfully synthesized...

Mg2+ intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situ X-ray diffraction evidenced the solid solution process of intercalation/deintercalation, while 57Fe Mössbauer spectroscopy absorption near edge structure revealed redox both Cu Fe.

Na-ion batteries have been the subjects of intensive studies for grid-scale energy storage recently. O3-type NaFeO2 is a promising candidate cathode materials, though irreversibility during extraction/insertion seriously hinders its practical application. The present work demonstrates that partial replacement Fe in O3-NaFeO2 with Ni leads to significant improvement electrochemical properties. 57Fe Mössbauer and X-ray absorption spectra show NaFeO2–NaNiO2 solid solution forms hybridized...

Interfacial charge transfer is one of the most important fundamental steps in and discharge processes intercalation compounds for rechargeable batteries. In this study, temperature-dependent electrochemical impedance spectroscopy was carried out to clarify origin high power output aqueous batteries with Prussian blue analog electrodes. The activation energy interfacial transfer, Ea, estimated from temperature dependence resistance. Ea values Li+ Na+ electrolytes were considerably smaller...

Host frameworks with the ability to store guest ions are very important in a wide range of applications including electrode materials for Li-ion batteries. In this report, we demonstrate that ion storage cyanide-bridged coordination polymer (Prussian blue analogue, PBA) can be enhanced by suppressing vacancy formation. K-ions vacancy-suppressed PBA framework K1.72Mn[Mn(CN)6]0.93·□0.07·0.65H2O (□: [Mn(CN)6]4– defect) were electrochemically extracted. The open circuit voltages (OCVs) during...

Abstract MXene electrodes in electrochemical capacitors have a distinctive behavior that is both capacitive and pseudocapacitive depending on the electrolyte. In this work, to better understand their mechanism, first‐principles calculations based density functional theory combined with implicit solvation model are used (termed as 3D reference‐interaction‐site model). From viewpoint of electronic states, hydration shell prevents orbital coupling between intercalated ions, which leads...

Abstract An alluaudite‐type sodium iron sulfate has recently been discovered as a 3.8 V cathode material for low‐cost, high‐power, and efficient sodium‐ion batteries. To optimize the composition of alluaudite phase to explore further compounds, we have carefully surveyed Na 2 SO 4 ‐FeSO binary system. Solid‐state reactions at moderate temperature 623 K produce two stable phases: 1) vanthoffite‐structured 6 Fe(SO ) 2) 2+2 x Fe 2− (SO 3 with certain non‐stoichiometry. The possible...

We demonstrate that core-shell nanoparticles consisting of two different Prussian blue analogues, one high capacity and the other robust, can provide enhanced rate capability as cathode materials in sodium-ion batteries.

Raising the operating potential of cathode materials in sodium-ion batteries is a crucial challenge if they are to outperform state-of-the-art lithium-ion batteries. Although layered transition metal oxides, NaMO2 (M: metal), most promising owing their high theoretical capacity with much more stable nature than Li1–xMO2 system, factors influencing redox have not yet been fully understood. Here, we identify paradox, E(Ni3+/Ni2+) > E(Ni4+/Ni3+), an identical structural framework, namely,...

Nonbonding oxygen 2p orbitals during oxygen-redox reaction are monitored using resonant inelastic X-ray scattering (RIXS).