- Crystallization and Solubility Studies
- Molecular Sensors and Ion Detection
- Photochromic and Fluorescence Chemistry
- X-ray Diffraction in Crystallography
- Supramolecular Chemistry and Complexes
- Bamboo properties and applications
- Dyeing and Modifying Textile Fibers
- Luminescence and Fluorescent Materials
Masaryk University
2018-2020
Driving forces of anion binding in water contrast to nonpolar environments are high interest because their relevance biology and medicine. Here we report a neutral bambusuril macrocycle (1), soluble both solvents due decoration with 12 polyethylene glycol-based substituents. The new has the highest affinity for I– pure ever reported synthetic relying on hydrogen bonding interactions rather than metal coordination or Coulombic forces. Isothermal titration calorimetry (ITC) experiments nine...
Bambusurils are a growing family of macrocyclic anion receptors. In this Letter, we present the first syntheses monofunctionalized bambusurils and their use for preparation heteroditopic bambusuril–crown ether conjugates suitable extraction ion pairs from water to chloroform.