2D Zn(<sc>ii</sc>)/Cd(<sc>ii</sc>) based MOF involving mixed ligands have been synthesized. Zn(<sc>ii</sc>) has utilized as a bifunctional material towards reversible dye adsorption and an efficient heterogeneous catalyst in Biginelli reaction.

Developing a heterogeneous catalyst for alcoholysis/hydrolysis of spiro-epoxyoxindoles to form β-alkoxy/β-hydroxy alcohols is an emerging and promising research area in the academia industry due its importance pharmaceutical industry. In this work, chiral-phase pure Zn-based metal–organic framework (MOF), {[Zn2(D-CAM)2(L)]·MeOH·2H2O}n (ADES-6), has been constructed from mixed organic ligands involving D(+)-camphoric acid (D-H2CAM) amide-functionalized N-donor ligand...

Functional neutral metal–organic frameworks (MOFs) {[M(5OH-IP)(L)]}n [M = Zn(II) for ADES-4; Cd(II) ADES-5; 5OH-IP 5-hydroxyisophthalate; L (E)-N′-(pyridin-3-ylmethylene)nicotinohydrazide) have been synthesized by a diffusion/conventional reflux/mechanochemical method and characterized various analytical techniques. Crystals were harvested diffusion method, single-crystal X-ray diffraction (SXRD) analysis revealed that an adjacent [M2(COO)2]n ladder chain generates isostructural...

Coordination polymers (CPs)/metal–organic frameworks (MOFs) are promising catalytic materials for selective carbon capture and utilization (CCU) as a C1 feedstock the synthesis of value-added chemicals to mitigate growing CO2 concentration in atmosphere. Herein, we report Zn(II)-based coordination network with ladder motif (ADES-3) constructed on an acylamide functionalized bipyridyl-based Schiff base (E)-N′-(pyridin-4-ylmethylene)isonicotinohydrazide (L) 5-nitroisophthalic acid (5NO2-IP)...

In the emerging era of artificial intelligence, Generative AI models such as Transformer-based models, Adversarial Networks, Diffusion and Variational Autoencoders offer a powerful paradigm for data augmentation by enabling generation that be like to original distribution. This study discusses use generative in place traditional techniques reviewing their history drawbacks. It explains workings GANs VAEs, strategies effectively integrating them into pipeline boost model performance. Both...

Developing synthetic strategies for smart materials the adsorption and separation of toxic chemicals is great importance. Metal-organic frameworks (MOFs) have been proven to be outstanding adsorbent that possess excellent pollutant removal performances in wastewater treatment, including dye recycling. In this work, a neutral Cd(II) based 2D framework with dual ligand strategy involving -OH functionalized 5-hydroxyisophthalic acid (5-OH-H

This research study presents a comprehensive critical review and performance fine-tuning exploration of Flutter applications, cross-platform framework gaining prominence in mobile app development. The begins by elucidating the fundamental principles architecture Flutter, shedding light on its advantages challenges. A systematic analysis existing applications is conducted to identify common bottlenecks usability issues. encompasses an in-depth examination Flutter's underlying mechanisms, such...

Climate change is a long-term in weather patterns from the tropics to poles. It global threat that has begun put strain on various industries. The goal of this study conceptually engineer how climate variability affecting sustainability sectors. This research investigated implications and associated with Land Surface Temperature (LST), Normalized Difference Built-up Index (NDBI), Water (NDWI), Vegetation (NDVI) as markers Kheda (Kaira) District Gujarat, India. took place between 2015 2020....

Cardiovascular disorders are one of the most common and complex across world. According to sector fitness association, top 10 important reasons for death is heart ailment. Accurate timely identity a critical stage in rehabilitation remedy. A device that capable predicting prevalence, essential detection cardiovascular illness. To help health practitioner decide whether or not patient has coronary condition no longer they may be at higher danger developing In this research, clever clinical...

Attendance is for keeping records of number students present in schools, colleges or any organization. It very important constituent maintaining discipline among acollege and imparting quality education colleges. Complexity this process increases even more with increase innumber students. Biometric student attendance system the efficiency taking attendance.Automatic wireless identification has been facilitated by IoT technology using electronic passive active tags suitable readers. In paper...