A5100407254- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Polyoxometalates: Synthesis and Applications
- Lanthanide and Transition Metal Complexes
- Metal complexes synthesis and properties
- Luminescence and Fluorescent Materials
- Nanocluster Synthesis and Applications
- Advanced Nanomaterials in Catalysis
- Supramolecular Chemistry and Complexes
- Molecular Sensors and Ion Detection
- Covalent Organic Framework Applications
- Crystal structures of chemical compounds
- Vanadium and Halogenation Chemistry
- Heavy metals in environment
- Aquaculture disease management and microbiota
- Supercapacitor Materials and Fabrication
- Chemical Synthesis and Reactions
- Analytical chemistry methods development
- Gas Sensing Nanomaterials and Sensors
- Supramolecular Self-Assembly in Materials
- Advanced biosensing and bioanalysis techniques
- Hydrogen Storage and Materials
Fujian Institute of Research on the Structure of Matter
2016-2025
Chinese Academy of Sciences
2016-2025
Peking University
2014-2025
Chengdu University
2024-2025
State Administration of Traditional Chinese Medicine of the People's Republic of China
2025
Zhangzhou Normal University
2020-2025
Guangdong Pharmaceutical University
2025
Fujian University of Technology
2024
Xinjiang Institute of Ecology and Geography
2024
University of Chinese Academy of Sciences
2014-2024
CONSPECTUS: Nanosized supramolecular metallocages have a unique self-assembly process that allows chemists to both understand and control it. In addition, well-defined cavities of such aggregates various attractive applications including storage, separation, catalysis, recognition, drug delivery, many others. Coordination-driven nanosized is powerful methodology construct with considerable size desirable shapes. this Account, we summarize our recent research on controllable...
Two classical metal clusters, CuI4I4 and CuI6S6, are introduced as functional connecting nodes to construct a novel multi-metal-cluster MOF [(CuI4I4)3(CuI6)2(3-ptt)12]n·24nDEF·12nH2O (1) that incorporate their inherent luminescent properties, induced by respective metal–metal interactions. These two distinct clusters combined together for the first time perform luminophores display unusual dual emission with both thermochromic luminescence near-infrared (NIR) character.
The simple design of a high-energy-density device with high-mass-loading electrode has attracted much attention but is challenging. Manganese oxide (MnO2 ) its low cost and excellent electrochemical performance shows high potential for practical application in this regard. Hence, the MnO2 wood-derived carbon (WC) as current collector reported through convenient hydrothermal reaction devices. Benefiting from (WC@MnO2 -20, ≈14.1 mg cm-2 abundant active sites on surface WC hierarchically porous...
The self-assembly of cationic tetranuclear-metal building blocks generated in situ based on p-tert-butylthiacalix[4]arene and linear anionic ligands (1,4-benzenedicarboxylic acid) gave rise to an truncated octahedral coordination cage through a [6 + 12] condensation. This research provides new block with unique geometry construct cages multifunctional properties.
A series of binary and ternary mixed LnMOFs with high stability showing potential applications in wide-range thermosensors white LEDs are reported.
A novel microporous polyhedral framework [Zn6(btb)4(4,4′-bipy)3(dmf)55(H2O)32] with high surface area has been designed and synthesized, which shows multigas-uptake capacity via supercritical carbon dioxide (SCD) activation.
Two metal-organic frameworks (MOFs), namely, [Ni(DTP)(H2O)]n (I) and [Cd2(DTP)2(bibp)1.5]n (II) (H2DPT = 4'-(4-(3,5-dicarboxylphenoxy) phenyl)-4,2':6',4″-terpyridine; bibp 1,3-di(1H-imidazol-1-yl)propane), that present structural diversity were solvothermally prepared. Single-crystal X-ray diffraction analysis indicates they consist of {NiN2O4} building units (for I) {CdO4N2} {CdO3N3} II), which are further linked by multicarboxylate H2DPT to construct microporous three-dimensional...
A bifunctional terbium metal–organic framework synthesized by a solvothermal method exhibits excellent sensitivity of Ba<sup>2+</sup> ions and unusual selectivities CO<sub>2</sub>–N<sub>2</sub> CO<sub>2</sub>–CH<sub>4</sub>.
By employing a tricarboxylate ligand 1-(4-carboxybenzyl)-1H-pyrazole-3,5-dicarboxylic acid (H3L), four lanthanide metal–organic frameworks (Ln-MOFs) formulated as {[LnL(H2O)2]·H2O}n (Ln = Eu, 1; Gd, 2; Tb, 3; Dy, 4) have been prepared under hydrothermal conditions. Single-crystal X-ray analyses reveal that compounds 1–4 are isomorphous and exhibit three-dimensional network structure featuring one-dimensional rectangular channel with size of ca. 7.8 Å × 12.1 along the b axis. The framework...
Materials exhibiting aggregation-induced emission (AIE) behaviour enable strong in solid state and can respond to various external stimuli, which may facilitate the development of materials for optical sensing, bioimaging or optoelectronic devices. Herein, we use an AIE luminogen 2',5'-diphenyl-[1,1':4',1"-terphenyl]-4,4"-dicarboxylic acid as ligand prepare AIEgen-based MOF (metal-organic framework) named FJI-H31. FJI-H31 exhibits bright luminescence under ambient conditions (under air at...
We systemically control the specific surface area and pore structure of flax-based carbon fibers by impregnating with zinc chloride (ZnCl 2 ) solution. The results show that ZnCl affects microstructure capacitance.
Achieving white-light emission, especially white circularly polarized luminescence (CPL) from a single-phase material is challenging. Herein, pair of chiral CuI coordination polymers (1-M and 1-P) have been prepared by the asymmetrical assembly achiral ligands Cu2 I2 clusters. The compounds display dual emission bands can be used as phosphors, achieving "warm"-white-light-emitting diode with an ultra-high color rendering index (CRI) 93.4 appropriate correlated temperature (CCT) 3632 K....