A5024148492- Strong Light-Matter Interactions
- Spectroscopy and Quantum Chemical Studies
- Thermal Radiation and Cooling Technologies
- Mechanical and Optical Resonators
- Perovskite Materials and Applications
- Quantum Electrodynamics and Casimir Effect
- Quantum, superfluid, helium dynamics
- Blood properties and coagulation
- Astrophysics and Star Formation Studies
- Platelet Disorders and Treatments
- CO2 Reduction Techniques and Catalysts
- Molecular Junctions and Nanostructures
- Blood groups and transfusion
- Photoreceptor and optogenetics research
- Chemistry and Chemical Engineering
- Advanced Fluorescence Microscopy Techniques
- Plasmonic and Surface Plasmon Research
- Lipid Membrane Structure and Behavior
- Impact of Technology on Adolescents
- Complement system in diseases
- Systemic Lupus Erythematosus Research
- Carbon dioxide utilization in catalysis
- Venous Thromboembolism Diagnosis and Management
- Social Media and Politics
- Gold and Silver Nanoparticles Synthesis and Applications
University of Jyväskylä
2021-2024
Robert Bosch (Germany)
2021
Université de Strasbourg
2016-2021
Centre National de la Recherche Scientifique
2016-2021
Fondation Jean-Marie Lehn
2019
Institut de Science et d'Ingénierie Supramoléculaires
2019
KU Leuven
2014
Many chemical methods have been developed to favor a particular product in transformations of compounds that two or more reactive sites. We explored different approach site selectivity using vibrational strong coupling (VSC) between reactant and the vacuum field microfluidic optical cavity. Specifically, we studied reactivity compound bearing possible silyl bond cleavage sites-Si-C Si-O, respectively-as function VSC three distinct modes dark. The results show can indeed tilt landscape one...
Vibrational strong coupling (VSC) has recently emerged as a completely new tool for influencing chemical reactivity. It harnesses electromagnetic vacuum fluctuations through the creation of hybrid states light and matter, called polaritonic states, in an optical cavity resonant to molecular absorption band. Here, we investigate effect vibrational water on enzymatic activity pepsin, where molecule is directly involved enzyme's mechanism. We observe approximately 4.5-fold decrease apparent...
Abstract Vibrational strong coupling (VSC) is currently emerging as a tool to control chemical dynamics. Here we study the impact of strength, given by Rabi splitting energy ( ħ Ω R ), on thermodynamic parameters associated with transition state desilylation reaction model molecule 1-phenyl-2-trimethylsilylacetylene. Under VSC, enthalpy and entropy activation determined from temperature-dependent kinetic studies varied nonlinearly strength. The noncavity did not show noticeable variation,...
It is well known that symmetry plays a key role in chemical reactivity. Here we explore its vibrational strong coupling (VSC) for charge-transfer (CT) complexation reaction. By studying the trimethylated-benzene-I
Abstract Vibrational strong coupling (VSC) has recently been shown to change the rate and chemoselectivity of ground‐state chemical reactions via formation light–matter hybrid polaritonic states. However, observation that vibrational‐mode symmetry a large influence on charge‐transfer under VSC suggests considerations could be used control other types selectivity through VSC. Here, we show influences stereoselectivity thermal electrocyclic ring opening cyclobutene derivative, reaction which...
In quantum electrodynamics, matter can be hybridized to confined optical fields by a process known as light–matter strong coupling. This gives rise new hybrid states and energy levels in the coupled material, leading modified physical chemical properties. Here, we report for first time coupling of vibrational modes proteins with vacuum field Fabry–Perot mid-infrared cavity. For two model systems, poly(l-glutamic acid) bovine serum albumin, is confirmed anticrossing dispersion curve, square...
Enhancing the electrical conductance through amorphous nondoped polymers is challenging. Here, we show that vibrational strong coupling (VSC) of intrinsically nonconducting and such as polystyrene, deuterated poly(benzyl methacrylate) to vacuum electromagnetic field cavity enhances conductivity by at least 6 orders magnitude compared uncoupled polymers. Remarkably, observed extraordinary mode selective occurs only under VSC aromatic C–H(D) out-of-plane bending modes The thermally activated...
Site-selectivity is fundamental for steering chemical reactivity towards a given product and various efficient methods have been developed this purpose. Here we explore very different approach by using vibrational strong coupling (VSC) between reactant the vacuum field of microfluidic optical cavity. For purpose, compound bearing two possible silyl bond cleavage sites, at Si-C Si-O, was studied as function VSC its modes in dark. The results show that can indeed tilt landscape to favor one...
Abstract Strong coupling plays a significant role in influencing chemical reactions and tuning material properties by modifying the energy landscapes of systems. Here we study effect vibrational strong (VSC) on supramolecular organization. For this purpose, rigid‐rod conjugated polymer known to form gels was strongly coupled together with its solvent microfluidic IR Fabry–Perot cavity. Absorption fluorescence studies indicate large modification self‐assembly under such cooperative VSC....
Abstract Vibrational strong coupling (VSC) has recently emerged as a completely new tool for influencing chemical reactivity. It harnesses electromagnetic vacuum fluctuations through the creation of hybrid states light and matter, called polaritonic states, in an optical cavity resonant to molecular absorption band. Here, we investigate effect vibrational water on enzymatic activity pepsin, where molecule is directly involved enzyme's mechanism. We observe approximately 4.5‐fold decrease...
The strong coupling regime of light–matter interaction has recently been extended to IR active molecular vibrations coupled microcavities, resulting in the formation so-called vibro-polaritonic states. Here we demonstrate emissivity such hybrid Using thermal excitation, achieve polaritonic emission from a strongly polymer. Thermal excitation vibro-polaritons, thus, constitutes an original way establishing sizable excited-states populations systems and opens new routes study interacting...
The von Willebrand factor (VWF) is a human plasma protein that plays key role in the initiation of formation thrombi under high shear stress both normal and pathological situations. It believed VWF undergoes conformational transition from compacted, globular to an extended form at stress. In this paper, we develop employ approach visualize large-scale conformation (pressure-driven) Poiseuille flow water-glycerol buffers with wide-field single molecule fluorescence microscopy as function...
Abstract Vibrational strong coupling (VSC) has recently been shown to change the rate and chemoselectivity of ground‐state chemical reactions via formation light–matter hybrid polaritonic states. However, observation that vibrational‐mode symmetry a large influence on charge‐transfer under VSC suggests considerations could be used control other types selectivity through VSC. Here, we show influences stereoselectivity thermal electrocyclic ring opening cyclobutene derivative, reaction which...
Abstract It is well known that symmetry plays a key role in chemical reactivity. Here we explore its vibrational strong coupling (VSC) for charge‐transfer (CT) complexation reaction. By studying the trimethylated‐benzene–I 2 CT complex, find VSC induces large changes equilibrium constant K DA of reflecting modifications Δ G ° value Furthermore, by tuning microfluidic cavity modes to different IR vibrations trimethylated benzene, either increases or decreases depending only on normal mode...
Site-selectivity is fundamental for steering chemical reactivity towards a given product and various efficient methods have been developed this purpose. Here we explore very different approach by using vibrational strong coupling (VSC) between reactant the vacuum field of microfluidic optical cavity. For purpose, compound bearing two possible silyl bond cleavage sites, at Si-C Si-O, was studied as function VSC its modes in dark. The results show that can indeed tilt landscape to favor one...
Achieving electrical conductance in amorphous non-doped polymers is a challenging task. Here, we show that vibrational strong coupling of the aromatic C-H(D) out-of-plane bending modes polystyrene, deuterated and poly (benzyl methacrylate) to vacuum electromagnetic field cavity enhance conductivity by at least six orders magnitude compared uncoupled polymers. The thermally activated onset coupling. It becomes temperature path length independent highest strengths, giving rise extraordinary...
ADVERTISEMENT RETURN TO ISSUEPREVAdditions and Correc...Additions CorrectionsNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to Vibro-Polaritonic IR Emission in the Strong Coupling RegimeMarcus SeidelMarcus SeidelMore by Marcus Seidelhttp://orcid.org/0000-0002-6246-1772, Thibault ChervyThibault ChervyMore Chervy, Anoop ThomasAnoop ThomasMore Thomas, Elias AkikiElias AkikiMore Akiki, Robrecht M. A. VergauweRobrecht VergauweMore Vergauwe, Atef ShalabneyAtef ShalabneyMore Shalabney,...
Abstract Strong coupling plays a significant role in influencing chemical reactions and tuning material properties by modifying the energy landscapes of systems. Here we study effect vibrational strong (VSC) on supramolecular organization. For this purpose, rigid‐rod conjugated polymer known to form gels was strongly coupled together with its solvent microfluidic IR Fabry–Perot cavity. Absorption fluorescence studies indicate large modification self‐assembly under such cooperative VSC....
Surface enhanced infrared absorption spectroscopic studies (SEIRAS) as a technique to study biological molecules in extremely low concentrations is greatly evolving. In order use the for identification of structure and interactions such molecules, it necessary identify effects plasmonic electric-field enhancement on spectral signature. this properties 1,2-Dipalmitoyl-sn-glycero-3 phosphothioethanol (DPPTE) phospholipid immobilized gold nanoantennas, specifically designed enhance vibrational...
This Minireview outlines the state of play in research area cellular bionics, where biological and synthetic cells are hybridised, thus bridging living/nonliving divide.Thanks to their predesigned structure, intrinsic porosity decent conductivity, 2D c-MOFs have attracted considerable attention especially electrochemical energy storage.In this Minireview, progress is surveyed with a focus on structural design principles, electrical properties potential applications supercapacitors batteries.