A5102784043- Metal-Organic Frameworks: Synthesis and Applications
- X-ray Diffraction in Crystallography
- Magnetism in coordination complexes
- Crystallization and Solubility Studies
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Covalent Organic Framework Applications
- Polyoxometalates: Synthesis and Applications
- Crystal structures of chemical compounds
- Energetic Materials and Combustion
- Supramolecular Chemistry and Complexes
- Thermal and Kinetic Analysis
- Dendrimers and Hyperbranched Polymers
- Crystal Structures and Properties
- Lanthanide and Transition Metal Complexes
- Surface Chemistry and Catalysis
- Nanocluster Synthesis and Applications
- Rocket and propulsion systems research
- Chalcogenide Semiconductor Thin Films
- Machine Learning in Materials Science
- Chemical Thermodynamics and Molecular Structure
- Gas Sensing Nanomaterials and Sensors
- Magnetic properties of thin films
- Advanced Polymer Synthesis and Characterization
- Characterization and Applications of Magnetic Nanoparticles
University of Houston - Clear Lake
2013-2023
Northwest University
2018-2020
China XD Group (China)
2018-2020
Ministry of Education of the People's Republic of China
2018-2020
China Three Gorges University
2014
Rutgers, The State University of New Jersey
1998-2001
A new family of two-dimensional metal coordination polymers with the general formula [M(ox)(bpy)] (M = Fe(II), Co(II), Ni(II), Zn(II); ox C2O42-; bpy 4,4'-bipyridine) have been designed and synthesized via hydrothermal routes. Quantitative yields were obtained in all cases. The title compounds [Fe(ox)(bpy)] (I), [Co(ox)(bpy)] (II), [Ni(ox)(bpy)] (III), [Zn(ox)(bpy)] (IV) represent first network structure constructed by bridging oxalate 4,4'-bpy mixed ligands. I−IV are isostructural belong to...
By controlling stoichiometry, three Copper(I) containing coordination polymers [Cu2Cl2(bpy)] (I), [Cu2Br2(bpy)] (II), and [CuBr(bpy)] (III) (bpy = 4,4'-bipyridine) have been synthesized in superheated water at 170 °C. The crystal structures of I II are two-dimensional networks composed Cu2X2 double chains bridged by 4,4'-bpy molecules through the nitrogen sites. structure III is a three-dimensional interpenetrating network constructed concatenated 2D sheets. TGA studies indicate that these...
Two-dimensional transition-metal coordination polymers [MCl2(bpy)] (M = Fe, Co, Ni; Co/Ni, bpy 4, 4'-bipyridine) have been synthesized in superheated water solutions. The hydrothermal routes resulted four compounds [FeCl2(bpy)](I), [CoCl2(bpy)](II), [NiCl2(bpy)](III), and [(Co/Ni)Cl2(bpy)](IV). Compounds I−IV are isostructural belong to orthorhombic crystal system, space group Cmmm (No. 65). Crystal data for I: a 11.929(2) Å, b 11.447(2) c 3.638(1) V 496.77(18) Å3, Z 2. II: 11.993(2)...
A novel porous framework polymer with expandable structure, over 8% volume expansion upon inclusion, has been characterized.
Reactions of CuX2 (X = Cl, Br) and 2,2‘-dipyridylamine (dpa) in superheated water (170 °C) led to a chemical rearrangement dpa dpiz (dpiz dipyrido[1,2-a:2‘,3‘-d]imidazole C10H7N3) new Cu(I)-based coordination polymers (CuX)2(dpiz) (CuX)3(dpiz). The crystal structures [(CuCl)2(C10H7N3)] (I) [(CuBr)3(C10H7N3)] (II) were reported. two are built upon common structural motif Cu2X4(C10H7N3).
A simultaneous reduction of copper(II) to copper(I) by pyridinecarboxylate and the substitution carboxylato groups iodo nucleophiles in a self-assembly process under hydrothermal conditions afforded new iodine-inclusion coordination polymer [CuI(C5H3NI2)*1/2I2] 1. The synthetic studies produced supramolecular compound [IC5H3NCOOH] 2 revealed that catalytic properties copper ions redox reactions are attractive. Crystal data for [CuI(C5H3NI2)*1/2I2]: triclinic, space group P1; cell dimensions...
A chemical rearrangement under hydrothermal conditions resulted in an unprecedented interpenetrating structure with two covalently bonded open frameworks of different dimensionality: {[Cu2(IN)4·3H2O]·[Cu 2(IN)4·2H2O]}·3H2 O (IN = isonicotinate).
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTThe First Triple-Layer 2-D Coordination Polymer: [Cu3(bpen)(IN)6(H2O)2]Jack Y. Lu and Amy M. BabbView Author Information Department of Chemistry, University Houston-Clear Lake, Houston, Texas 77058 Cite this: Inorg. Chem. 2001, 40, 14, 3261–3262Publication Date (Web):June 6, 2001Publication History Received3 April 2001Published online6 June inissue 1 July...
A new green energetic metal–organic framework has potential application prospects in the fields of greener propellants and multi-dimensional magnetic materials.
Two flexible V-shape ligands, namely, 1,3-bis(pyridine-4-ylmethoxy)benzene (4-bpmb) and 1,3-bis(pyridine-2-ylmethoxy)benzene (2-bpmb), have been synthesized employed for constructing eight novel coordination polymers, {[Zn(4-bpmb)(H2O)(NO3)2]·(4-bpmb)}n (1), {[Cd(4-bpmb)(H2O)(NO3)2]·(4-bpmb)}n (2), {[Hg(4-bpmb)(H2O)(NO3)2]·(4-bpmb)}n (3), {[Zn4(2-bpmb)4Cl8]·C5H5N}n (4), {[Hg(2-bpmb)Cl2]·2H2O}n (5), [Cu4(μ-CH3COO)8(2-bpmb)2]n (6), [Ag(2-bpmb)(NO3)]n (7), {[Cu(2-bpmb)(H2O)2]·(NO3)2}n (8)....
In this work, a new energetic coordination polymer (ECP), [Cu(HBTI)(H2O)]n (1) (H3BTI = 4,5-bistetrazole-imidazole), was synthesized by hydrothermal method. Due to the existence of water molecules in 1, however, its energy density limited, which led insufficient detonation performance. To further improve performance, [Cu(H2BTI)(NO3)]n (2) then obtained substituting coordinated molecule 1 with nitrate through substitution reaction under acidic conditions. The structures two ECPs were...
The first removable solid-state iodine inclusion eclipsed two-dimensional coordination polymer with an unusually stable open-channel structure has been synthesized and characterized by X-ray diffraction technique.
A new acentric, open-framework metal−polymer created by unbalanced inclusion guest species has been synthesized. The coordination polymer fabricated into metal−organic nanofibers using electrospinning techniques.
Two novel two-dimensional (layered) intermetallic copper selenoantimonates Cu2SbSe3·0.5en (I) and Cu2SbSe3·en (II), have been prepared by soft solvothermal reactions of CuCl, SbCl3, Se with A2Se (A = Na, K) in the presence ethylenediamine. Single-crystal X-ray diffraction analyses show that both structures crystallize monoclinic crystal system. Compound I belongs to P21/n (no. 14) space group a 6.399(1) Å, b 18.858(4) c 6.786(1) β 113.23(3)°, Z 4, V 752.5(2) Å3, II Pn 7) 6.321(2) 11.841(2)...
The first oxalato and isonicotinato mixed-ligand guest-inclusion open-framework coordination polymer {[(H2O)2(oxa)Zn2(IN)2]·2(H2O)} was synthesized from a chemical rearrangement of isonicotinate to oxalate under hydrothermal conditions: space group, P21/c; = 8.302(1), b 15.557(2), c 7.344 (1) Å, β 94.351(1)°, U 945.8(1) Å3, Z 2.
The novel two-dimensional iron(II) compound of formula {[Fe2(bpym)(ox)2]·5H2O}n (1) [bpym = 2,2′-bipyrimidine and ox oxalate dianion] is obtained by reaction oxalic acid, chloride in aqueous solution. structure 1 made up oxalato-bridged chains cross-linked bischelating bpym affording a honeycomb lattice. Variable-temperature magnetic susceptibility data show the occurrence relatively large antiferromagnetic interactions between high spin ions separated more than 5.5 Å through bridging [Jbpym...