Jin Cao

ORCID: 0000-0003-0330-1231
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Research Areas
  • Advanced battery technologies research
  • Advanced Battery Materials and Technologies
  • Advancements in Battery Materials
  • Advanced Battery Technologies Research
  • Supercapacitor Materials and Fabrication
  • Advanced Thermoelectric Materials and Devices
  • Perovskite Materials and Applications
  • Thermochemical Biomass Conversion Processes
  • Thermal Radiation and Cooling Technologies
  • MXene and MAX Phase Materials
  • Combustion and flame dynamics
  • Advanced Thermodynamics and Statistical Mechanics
  • Supramolecular Chemistry and Complexes
  • Complex Network Analysis Techniques
  • Thermal properties of materials
  • Advanced materials and composites
  • Conducting polymers and applications
  • Advanced Sensor and Energy Harvesting Materials
  • Advanced ceramic materials synthesis
  • Advanced Photocatalysis Techniques
  • Extraction and Separation Processes
  • Heat Transfer and Optimization
  • Catalytic Processes in Materials Science
  • Coal Combustion and Slurry Processing
  • Opinion Dynamics and Social Influence

Second Affiliated Hospital of Xi'an Jiaotong University
2025

China Three Gorges University
2022-2024

China Energy Engineering Corporation (China)
2023-2024

Yanshan University
2024

City University of Hong Kong
2023-2024

Shanghai University
2023

Wuhan University
2012-2023

China General Nuclear Power Corporation (China)
2022-2023

Chulalongkorn University
2020-2022

Nanjing University of Science and Technology
2017-2022

This review gives a comprehensive introduction of the solvation structure regulation strategies for dendrite-free and side reaction-suppressed zinc-ion batteries, further proposes potential directions perspectives research.

10.1039/d1ee03377h article EN Energy & Environmental Science 2021-12-21

Abstract The dendrite issues associated with zinc anode lead to safety hazards and sluggish reaction kinetics, largely restrain widespread application of aqueous ion batteries (ZIBs). Herein, a functional separator composed cellulose nanofibers graphene oxide (CG) is developed for dendrite‐free exceptionally stable ZIBs, realized by uniform hexagonal deposits manipulated crystallographic orientation (002) plane. This CG negative surface charges abundant zincophilic‐O groups ensures the...

10.1002/aenm.202101299 article EN Advanced Energy Materials 2021-06-10

Abstract Manganese‐based materials are considered potential cathode for aqueous zinc ion batteries (ZIBs). However, the dissolution of manganese leading to an abrupt decline capacity and sluggish electrochemical reaction kinetics still main bottlenecks restricting their further development. Herein, a NiMn‐layered double hydroxide‐derived Ni‐doped Mn 2 O 3 (NM) is developed suppress manganese. The incorporation Ni 2+ can promote electronic rearrangement enhance conductivity, ultimately...

10.1002/adfm.202009412 article EN Advanced Functional Materials 2021-01-31

A universal and facile approach using a graphene oxide (GO) modified separator is used to suppress dendrite formation in Zn Li metal anodes, <italic>via</italic> the preferential growth of non-protruding crystal planes.

10.1039/d0ta02486d article EN Journal of Materials Chemistry A 2020-01-01

The poor conductivity, unsatisfactory stability, and severe aggregation of nanosheets have been recognized as the main reasons that limit electrochemical performance layered double hydroxide (LDH) materials. present work proposes a chemical structure consists in situ anchoring highly dispersed NiMn-LDH on Ti3C2 MXene sheets via bonds. Negatively charged will provide abundant heterogeneous nucleation sites for during crystallization process, surface functional groups can strengthen connection...

10.1021/acsaem.0c00863 article EN ACS Applied Energy Materials 2020-05-26

The uncontrollable dendrites growth and intricately water-induced side reactions occurred on zinc anode leads to safety issues poor electrochemical kinetics, which largely limit the widespread application of zinc-ion batteries (ZIBs). Herein, ethylenediaminetetraacetic acid disodium salt (EDTA-2Na) is utilized as an electrolyte additive strengthen reversibility cycling stability anode. Experimental results theoretical calculation demonstrate that EDTA-2Na presents a much stronger...

10.1016/j.apmate.2021.09.007 article EN cc-by-nc-nd Advanced Powder Materials 2021-11-22

Zinc-ion batteries have drawn tremendous attention in the electrochemical energy storage market because of their merits high safety and low cost, however, dendrites issue zinc anodes remains a challenge. Herein, we developed hybrid electrolyte with graphene oxide as an additive functions promoting uniform distribution electric field reducing nucleation overpotential Zn2+, displaying smooth electrodeposition layer reaction kinetics. The resultant symmetric battery affords stable anode which...

10.1021/acsaem.1c00224 article EN ACS Applied Energy Materials 2021-04-22

Abstract The long‐term reversible plating/stripping of Zn metal anode is a critical aspect within aqueous zinc‐ion batteries (ZIBs). However, it limited by uncontrolled electrodeposition and side reactions occurring at the anode/electrolyte interface. Guided metal‐coordination chemistry, novel additive, sodium diphenylamine sulfonate (DASS), added into ZnSO 4 electrolyte to guide stably invertible zinc deposition. Theoretical calculations experimental results reveal that DASS can adsorbed on...

10.1002/aenm.202302770 article EN Advanced Energy Materials 2023-11-30

Abstract The low cost and intrinsic safety of rechargeable aqueous zinc‐ion batteries (ZIBs) contribute to their significant potential in grid‐level energy storage systems. However, the limited cathode options still hinder development ZIBs, which always delivers poor rate capacities cycling stability. Herein, Monoclinic phase H 3.78 V 6 O 13 microspheres with a stable internal framework metallic properties as high‐performance for ZIBs are proposed utilized. reversible Zn 2+...

10.1002/adfm.202307270 article EN Advanced Functional Materials 2023-09-01

Abstract Constructing artificial solid electrolyte interface on the Zn anode surface is recognized as an appealing method to inhibit zinc dendrites and side reactions, whereas current techniques are complex time‐consuming. Here, a robust zincophilic tungstate (ZnWO 4 ) layer has been in situ constructed (denoted ZWO@Zn) by ultrafast chemical solution reaction. Comprehensive characterizations theoretical calculations demonstrate that ZWO can effectively modulate interfacial electric field...

10.1002/anie.202319661 article EN cc-by Angewandte Chemie International Edition 2024-05-04

Manipulating the crystallographic orientation of zinc deposition is recognized as an effective approach to address dendrites and side reactions for aqueous zinc-ion batteries (ZIBs). We introduce 2-methylimidazole (Mlz) additive in sulfate (ZSO) electrolyte achieve vertical electrodeposition with preferential (100) (110) crystal planes. Significantly, anode exhibited long lifespan 1500 h endurance at 1 mA cm–2 excellent 400 capability a depth discharge (DOD) 34% Zn||Zn battery...

10.1021/acsnano.4c00288 article EN ACS Nano 2024-06-18

Abstract The cost‐effectiveness and environmentally friendly nature of aqueous zinc‐ion batteries (ZIBs) have garnered significant attention. Nevertheless, obstacles such as dendrite growth side reactions hindered their practical application. Here, an alkaline earth metal ion, strontium ions (Sr 2+ ), is chosen a dual‐functional electrolyte additive to improve the reversibility ZIBs. Importantly, Sr adsorb on anode surface, creating dynamic electrostatic shield layer, thus regulating Zn...

10.1002/adfm.202401537 article EN Advanced Functional Materials 2024-04-03

Abstract Designing a cost‐effective and multifunctional separator that ensures dendrite‐free stable Zn metal anode remains significant challenge. Herein, cellulose‐based is presented consisting of industrial waste‐fly ash particles cellulose nanofiber using facile solution‐coating method. The resulting fly ash‐cellulose (FACNF) separators enable high ion conductivity (5.76 mS cm −1 ) low desolvation energy barrier hydrated 2+ . These features facilitate fast transfer kinetics inhibit...

10.1002/smll.202311203 article EN Small 2024-01-17

Abstract Despite the widespread adoption of Zn anodes for aqueous energy storage, presence an inherent passivation layer and polycrystalline interface commercial foil consistently lead to non‐uniform electrodeposition, undermining stability practicality. Herein, study introduces a chemically polished metal anode (CP‐Zn) fabricated via simple immersion method. This “chemically polishing” process can effectively remove interfacial (de‐passivation), providing ample active sites...

10.1002/adma.202410947 article EN Advanced Materials 2024-09-27

Abstract The cost‐effectiveness and environmental benefits of aqueous zinc‐ion batteries (ZIBs) have attracted considerable attention. However, practical applications are hindered by side processes including dendritic growth hydrogen evolution corrosion. Herein, gallium ions (Ga 3+ ) been chosen as a multifunctional electrolyte additive to improve the reversibility (ZIBs). Remarkably, Ga adhere anode surface, establishing dynamic electrostatic shielding layer that modulates Zn 2+ deposition...

10.1002/aenm.202403175 article EN Advanced Energy Materials 2024-09-16
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