Cesar Villa

ORCID: 0000-0003-0419-4925
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About
Contact & Profiles
Research Areas
  • Advancements in Battery Materials
  • Advanced Battery Materials and Technologies
  • Inorganic Fluorides and Related Compounds
  • Extraction and Separation Processes
  • Supercapacitor Materials and Fabrication
  • Semiconductor materials and devices
  • Chalcogenide Semiconductor Thin Films
  • Fiber-reinforced polymer composites
  • Molecular Junctions and Nanostructures
  • Electrocatalysts for Energy Conversion
  • Advanced Battery Technologies Research
  • 2D Materials and Applications
  • Quantum Dots Synthesis And Properties
  • Block Copolymer Self-Assembly
  • ZnO doping and properties
  • Advanced Data Storage Technologies
  • Catalysts for Methane Reforming
  • Electronic and Structural Properties of Oxides
  • nanoparticles nucleation surface interactions
  • Conducting polymers and applications
  • Recycling and Waste Management Techniques
  • Advanced battery technologies research

Northwestern University
2018-2022

Abstract Carbon dots have been recognized as one of the most promising candidates for oxygen reduction reaction (ORR) in alkaline media. However, desired ORR performance metal–air batteries is often limited by moderate electrocatalytic activity and lack a method to realize good dispersion. To address these issues, herein biomass‐deriving reported achieve situ phosphorus doping (P‐doping) carbon their simultaneous decoration onto graphene matrix. The resultant product, namely P‐doped...

10.1002/aenm.201902736 article EN Advanced Energy Materials 2019-12-05

Metal fluorides usually have a large electronegativity and are promising electrode materials for high-power lithium-ion batteries. However, like other conversion-reaction-based materials, volumetric expansions capacity losses in cycling the major issues metal fluorides. Here, we explore substitution of Ni with Cu binary NiF2 its effects on electrochemical properties. By situ transmission electron microscopy, structural evolutions several ternary different Cu/Ni ratios observed correlated...

10.1021/acsami.8b15791 article EN ACS Applied Materials & Interfaces 2018-12-06

The energy density of lithium-ion batteries can be increased by replacing the traditional graphite anode with a high capacity silicon anode. However, volume changes and interfacial instabilities cause large irreversible continual loss lithium during cycling, which lead to rapid loss. In this work, we add Li 5 FeO 4 (LFO) LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC) cathode as pre-lithiation additive, increases inventory extends cycle life Si-graphite/NMC full cells, decreases NMC particle degradation....

10.1149/1945-7111/abd1ef article EN cc-by Journal of The Electrochemical Society 2020-12-01

Copper (Cu) is a catalyst broadly used in industry for hydrogenation of carbon dioxide, which has broad implications environmental sustainability. An accurate understanding the degeneration behavior Cu catalysts under operando conditions critical uncovering failure mechanism and designing novel ones with optimized performance. Despite widespread use these materials, their mechanisms are not well understood because conventional characterization techniques lack necessary time spatial...

10.1021/acs.nanolett.1c01592 article EN Nano Letters 2021-08-11

Heterostructuring of different transition metal dichalcogenides (TMDs) leads to interesting band alignment and performance improvement, thus enables new routes for the development materials next-generation semiconductor electronics.

10.1039/c8mh00809d article EN Materials Horizons 2019-01-01

Abstract This paper describes a new, high‐performance, Pb‐based nanocomposite anode material for lithium‐ion batteries. A unique structure of Pb@PbO core‐shell nanoparticles in carbon matrix is obtained by using simple high‐energy ball milling method the low‐cost starting materials PbO and black. Electrochemical performance tests show its excellent reversible capacity (≈600 mAh g −1 ) cycle stability (92% retention at 100th cycle), which are one best values reported anodes literature....

10.1002/adfm.202005362 article EN Advanced Functional Materials 2020-09-13

The tremendous growth in Li-ion batteries puts pressure on supply chains leading to the need invest recyclable processes. In article number 2005362, Eungje Lee, Seong-Min Bak, and co-workers synthesize a potentially lead-based anode (Pb anode) via high-energy ball-milling production of self-limiting oxide coated lead core embedded within carbon matrix. Electrochemical cycling performance is good, demonstrating 500 mAhg−1 with over 92% retention at 100 cycles.

10.1002/adfm.202170008 article EN Advanced Functional Materials 2021-01-01

Journal Article Investigating Surface Structure, Chemistry, and Thickness of NMC Cathodes Blended with LFO using EELS Get access Cesar J Villa, Villa Department Materials Science Engineering, Northwestern University, Evanston, IL, USA Search for other works by this author on: Oxford Academic Google Scholar Xiaobing Hu, Hu USANUANCE Center, Wesley M Dose, Dose Division Chemical Sciences Argonne National Laboratory, Argonne, Christopher S Johnson, Johnson Vinayak P Dravid Microscopy...

10.1017/s1431927619011632 article EN Microscopy and Microanalysis 2019-08-01

This talk will describe a new, high-performance Pb-based nanocomposite anode material for lithium-ion batteries. A unique structure of core-shell Pb@PbO nanoparticles and carbon matrix was able to be obtained by simple high energy ball milling method using the low-cost PbO black starting materilas. The electrochemical performance tests showed excellent reversible capacity (ca. 600 mAh/g) cycle stability (92% retention at 100th cycle), which are best performances ever reported anodes in...

10.1149/ma2020-02131mtgabs article EN Meeting abstracts/Meeting abstracts (Electrochemical Society. CD-ROM) 2020-11-23

Journal Article In-situ Observation of the Degeneration Dynamics Cu Nanowires under Carbon Dioxide Environment Get access Xiaobing Hu, Hu Department Materials Science and Engineering, Northwestern University, Evanston, IL, USAThe NUANCE Center, USA Corresponding author: xbhu@northwestern.edu Search for other works by this author on: Oxford Academic Google Scholar Kun He, He Cesar Jared Villa, Villa Stephanie M Ribet, Ribet Paul J Smeets, Smeets Roberto dos Reis, Reis Vinayak P Dravid...

10.1017/s1431927622001611 article EN Microscopy and Microanalysis 2022-07-22
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