Patrizio Raffa

ORCID: 0000-0003-0738-3393
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About
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Research Areas
  • Advanced Polymer Synthesis and Characterization
  • Enhanced Oil Recovery Techniques
  • Surfactants and Colloidal Systems
  • Polymer composites and self-healing
  • Advanced Sensor and Energy Harvesting Materials
  • Conducting polymers and applications
  • biodegradable polymer synthesis and properties
  • Polymer Nanocomposites and Properties
  • Petroleum Processing and Analysis
  • Synthesis and properties of polymers
  • Polymer Surface Interaction Studies
  • Dielectric materials and actuators
  • Reservoir Engineering and Simulation Methods
  • Analytical Chemistry and Sensors
  • Fluorine in Organic Chemistry
  • Organoboron and organosilicon chemistry
  • Innovative Microfluidic and Catalytic Techniques Innovation
  • Carbon Nanotubes in Composites
  • Catalytic Cross-Coupling Reactions
  • Polymer crystallization and properties
  • Synthetic Organic Chemistry Methods
  • Catalytic Alkyne Reactions
  • Chemical Synthesis and Analysis
  • Asymmetric Synthesis and Catalysis
  • Electrocatalysts for Energy Conversion

University of Groningen
2016-2025

University Medical Center Groningen
2020

Practical Action
2014-2019

Yanshan University
2018

University of Milan
2018

Institut National des Sciences Appliquées de Lyon
2018

Université Claude Bernard Lyon 1
2018

Centre National de la Recherche Scientifique
2018

Kurdistan Regional Government
2018

Dutch Polymer Institute
2012-2015

Abstract Conductive hydrogels have emerged as fascinating materials for flexible electronics because of their integrated conductivity, mechanical flexibility, and the possibility to introduce several smart functions. However, swelling in aqueous environments significantly reduces applicability where contact with water is unavoidable. In this study, a physically cross‐linked composite hydrogel proposed, that transparent, highly stretchable, anti‐swelling, capable autonomous self‐healing,...

10.1002/adfm.202407529 article EN cc-by-nc-nd Advanced Functional Materials 2024-07-31

Zwitterionic conductive hydrogels have shown potential application in wearable strain and pressure sensors. However, there are still fundamental challenges to achieve zwitterionic with excellent mechanical properties, able keep flexibility at sub-zero temperatures. To overcome these limitations, a hydrogel was fabricated this work by in-situ polymerization of aniline (ANI) monomer copolymer sulfobetaine methacrylate (SBMA) acrylic acid (AA) matrix. The obtained possesses outstanding...

10.1016/j.eurpolymj.2023.112484 article EN cc-by-nc-nd European Polymer Journal 2023-10-10

Atomic transfer radical polymerization (ATRP) of acrylamide has been accomplished in aqueous media at room temperature. By using methyl 2-chloropropionate (MeClPr) as the initiator and tris[2-(dimethylamino)ethyl]amine (Me6TREN)/copper halogenide (CuX) catalyst system, different linear polyacrylamides with apparent molecular weights up to >150 000 g/mol were synthesized dispersities low 1.39. The agreed well theoretical ones relatively low-medium monomer/initiator ratios (<700:1). Initial...

10.1021/ma3006125 article EN Macromolecules 2012-05-10

ABSTRACT With the purpose of investigating new potential candidates for enhanced oil recovery (EOR), amphiphilic copolymers based on Poly(ethylene glycol) methyl ether acrylate (PEGA) have been prepared by Atom Transfer Radical Polymerization (ATRP). A P(PEGA) homopolymer, a block copolymer with styrene PS‐ b ‐P(PEGA), and an analogous terpolymer including also sodium methacrylate (MANa) in poly(PEGA) (PPEGA) block, ‐P(PEGA‐ co ‐MANa) characterized. Viscosity surface activity solutions...

10.1002/app.44100 article EN Journal of Applied Polymer Science 2016-07-08

During the past half-century, prefix “nano” attached to several words, such as “technology”, “motors”, “device”, and so on has denoted cutting-edge research fields topics at forefront of classical scientific disciplines. Possible application have been frequently evoked, even if real-life examples are still difficult find. The present review analyzes how nanotechnology is utilized in enhanced oil recovery (EOR) processes increase efficiency mature oilfields. Nanotechnology EOR classified into...

10.3390/app8122596 article EN cc-by Applied Sciences 2018-12-12

Polymers crosslinked via furan/maleimide thermo-reversible chemistry have been extensively explored as reprocessable and self-healing thermosets elastomers. For such applications, it is important that the features are reproducible after many reprocessing healing cycles. Therefore, side reactions undesirable. However, we noticed irreversible changes in mechanical properties of materials when exposing them to temperatures around 150 °C. In this work, study whether these due self-reaction...

10.3390/molecules26082230 article EN cc-by Molecules 2021-04-13

Abstract Micro‐nano‐fabrication on objects with complex surfaces is essential for the development of technologies in growing fields flexible electronics and photonics. Various strategies are devised to extend fabrication from conventional planar substrates curved ones, however, significant challenges still exist, especially framework 3D printing additive manufacturing. In this study, a novel technique presented realize micro‐structures arbitrary providing an extreme level conformability....

10.1002/adfm.202214409 article EN cc-by Advanced Functional Materials 2023-03-22

Starch is one of the best candidates to replace non-renewable plastics thanks its plentiful availability in nature, and low cost. Food industry produces large amount starch-containing waste, which are not utilizable as nutrients, therefore have potential for non-food applications. However, some physicochemical characteristics starch, such thermal stability high hydrophilicity undesirable many Supercritical CO2 an attractive alternative media chemical modification starch due unique tuneable...

10.1016/j.carpta.2024.100483 article EN cc-by-nc Carbohydrate Polymer Technologies and Applications 2024-03-12

A kinetic study of the esterification reaction citric (CA) acid and butyl glycol (BG) with without catalyst was performed to elucidate mechanism. Interestingly, different preferences sites on CA molecules (at α or β position) can be found in either bulk conditions organic solvents. The density functional theory (DFT) model used support this experimental study. Additionally, optimal for regioselectivity toward primary secondary alcohols, presence scandium triflate as catalyst, were studied....

10.1021/acssuschemeng.4c07569 article EN cc-by ACS Sustainable Chemistry & Engineering 2025-01-02

Three well-defined polystyrene–poly(sodium methacrylate) amphiphilic block copolymers characterized by different molecular architecture (diblock, triblock, and four-arm star) have been synthesized ATRP. The rheology of their water solutions has evaluated measuring dynamic moduli shear viscosity at concentrations. All polymers show remarkable thickening properties a sol–gel transition low concentration (0.1 wt %). Above the gel are thinning without an apparent Newtonian plateau. observed...

10.1021/ma401453j article EN Macromolecules 2013-08-22

Diels-Alder chemistry has been used for the thermoreversible cross-linking of furan-functionalized ethylene/propylene (EPM) and ethylene/vinyl acetate (EVM) rubbers. Both elastomers were successfully cross-linked with bismaleimide to yield products a similar cross-link density. NMR relaxometry SAXS measurements both show that apolar EPM-g-furan precursor contains phase-separated polar clusters occurs in these clusters. The heterogeneously network contrasts homogeneous EVM-g-furan....

10.1021/acs.macromol.7b01541 article EN cc-by-nc-nd Macromolecules 2017-11-07

ABSTRACT With the aim of up‐grading material properties post‐consumer PET, making them suitable for extrusion thermoformable thick sheets, a series polyepoxy chain extenders have been comparatively evaluated as melt viscosity modifiers toughened compatibilized blend containing up to 80 wt % bottle‐grade recycled poly(ethylene terephtalate) (r‐PET). Combinations commercial modifier with pentaerythritol were also successfully employed cause simultaneous hyperbranching and controlled scission,...

10.1002/app.40881 article EN Journal of Applied Polymer Science 2014-05-13

In the present study performance of a series star-like branched polyacrylamides (SB-PAMs) has been investigated in oil recovery experiments to ultimately determine their suitability as novel thickening agent for enhanced (EOR) applications. Hereby, SB-PAMs were compared with conventional linear PAM. The effect molecular architecture on rheology, and consequently was discussed. Rheological measurements identified unique properties SB-PAMs, those showed higher robustness under shear salt...

10.1021/acs.iecr.7b03368 article EN cc-by-nc-nd Industrial & Engineering Chemistry Research 2018-06-08
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