A5083265760- Surface Chemistry and Catalysis
- Surface and Thin Film Phenomena
- Molecular Junctions and Nanostructures
- Spectroscopy and Quantum Chemical Studies
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Advanced Battery Technologies Research
- Advancements in Battery Materials
- Advanced Battery Materials and Technologies
- Crystallography and molecular interactions
- Photonic Crystals and Applications
- Force Microscopy Techniques and Applications
- Advanced Chemical Physics Studies
- Pickering emulsions and particle stabilization
- Advanced Glycation End Products research
- Porphyrin and Phthalocyanine Chemistry
- Quantum Dots Synthesis And Properties
- Ionic liquids properties and applications
- Phytochemicals and Antioxidant Activities
- Microgrid Control and Optimization
- Cancer-related molecular mechanisms research
- Tea Polyphenols and Effects
- Block Copolymer Self-Assembly
- Supramolecular Self-Assembly in Materials
- Extracellular vesicles in disease
Shenzhen University
2020-2024
KU Leuven
2018-2024
South China University of Technology
2014-2023
University of South China
2021-2023
Nanjing Tech University
2022
Tsinghua University
2011-2020
Key Laboratory of Guangdong Province
2020
Tsinghua–Berkeley Shenzhen Institute
2020
Nanjing University
2016-2019
Second Hospital of Yichang
2012
Abstract The garnet electrolyte presents poor wettability with Li metal, resulting in an extremely large interfacial impedance and drastic growth of dendrites. Herein, a novel ultra‐stable conductive composite interface (CCI) consisting y Sn alloy 3 N is constructed situ between 6.4 La Zr 1.4 Ta 0.6 O 12 (LLZTO) pellet metal by conversion reaction SnN x at 300 °C. as continuous robust bridge LLZTO can effectively reduce the LLZTO/Li resistance from 4468.0 Ω to 164.8 Ω. Meanwhile, fast Li‐ion...
The Li–EG composite anode was prepared by embedding the EG in Li metal, which induces uniform deposition of and inhibits dendrites.
Exosomes can encapsulate lncRNA to mediate intercellular communication in cancer progression. Our study devoted research the effect that long noncoding RNA Metastasis-associated lung adenocarcinoma transcript 1 (lncRNA MALAT1) influence on cervical (CC).MALAT1 and miR-370-3p levels CC was assessed using qRT-PCR. CCK-8 assay flow cytometry were confirm MALAT1 influencing proliferation cisplatin-resistant cells. Futher more, MALAT1, combined with confirmed by dual-luciferase reporter...
Lithiated transition metal phosphates with large theoretical capacities have emerged as promising cathode materials for rechargeable lithium-ion batteries. However, the poor kinetic properties caused by their low intrinsic electronic and ionic conductivity greatly hinder practical applications. In this work, we demonstrate a novel strategy to prepare monoclinic lithium vanadium phosphate nanoparticles implanted in carbon nanofibers cathodes of Li-ion cells high capacity, flexibility, long...
Halogen bonding with high specificity and directionality in the geometry has proven to be an important type of noncovalent interaction fabricate control 2D molecular architectures on surfaces. Herein, we first report how orientation ester substituent for thienophenanthrene derivatives (5,10-DBTD 5,10-DITD) affects positive charge distribution halogens by density functional theory, thus determining formation intermolecular halogen bond different self-assembled patterns scanning tunneling...
The self-assembled behaviors of two fluorenone derivatives, 2,7-bis((11-hydroxyundecyl)oxy)-9-fluorenone (BHUF) and 2,7-bis((10-carboxydecyl)oxy)-9-fluorenone (BCDF), were investigated at the liquid–solid interface by scanning tunneling microscopy. Two solvents, 1-octanoic acid 1-phenyloctane, employed in consideration their distinct polarity solubility. It is observed that BHUF molecules self-assemble into seven different polymorphs upon adsorption, while only are BCDF monolayer....
Amid escalating energy crises and environmental pressures, electric vehicles (EVs) have emerged as an effective measure to reduce reliance on fossil fuels, combat climate change, uphold sustainable development, strive towards carbon peaking neutrality goals. This study introduces a nonlinear integer programming model for the deployment of dynamic wireless charging lanes (DWCLs) EV strategy joint optimization in highway networks. Taking into account established resources service areas (HSAs),...
Investigating and regulating the self-assembly structure is of great importance in 2D crystal engineering it also gaining significant interest surface studies. In this work, we systematically explored variation self-assembled patterns induced by changeable side chain position. Moreover, molecules with different alkyl lengths (n = 15, 16) were synthesized probed for purpose understanding how an odd/even number carbon atoms peripheral chains can affect molecular adlayers. Structural isomers...
Herein, the photophysical properties of two π-conjugated thienophenanthrene derivatives (6,9- and 5,10-DBTD) are reported. Their self-assembled monolayers in aliphatic hydrocarbon solvents under different concentrations were investigated by scanning tunneling microscopy on a graphite surface. The STM results revealed that structures geometrical isomers exhibited absolutely behaviors. At solvent/graphite interface, 6,9-DBTD produced almost single stable coassembled linear structure, except...
Tin (Sn) based anode materials have been regarded as promising alternatives for graphite in lithium ion batteries (LIBs) due to their high theoretical specific capacity and conductivity. However, practical application is severely restrained by the drastic volume variation during cycling processes. Here we report preparation of intermetallic SnSb nanodots embedded carbon nanotube reinforced N-doped nanofibers (SnSb-CNTs@NCNFs) a free-standing flexible LIBs. In this unique structure, are well...
Abstract The garnet electrolyte presents poor wettability with Li metal, resulting in an extremely large interfacial impedance and drastic growth of dendrites. Herein, a novel ultra‐stable conductive composite interface (CCI) consisting y Sn alloy 3 N is constructed situ between 6.4 La Zr 1.4 Ta 0.6 O 12 (LLZTO) pellet metal by conversion reaction SnN x at 300 °C. as continuous robust bridge LLZTO can effectively reduce the LLZTO/Li resistance from 4468.0 Ω to 164.8 Ω. Meanwhile, fast Li‐ion...
Two-dimensional supramolecular assemblies of a series 2,7-bis(10-n-alkoxycarbonyl-decyloxy)-9-fluorenone derivatives (BAF-Cn, n = 1, 3-6) consisting polar fluorenone moieties and ester alkoxy chains were investigated by scanning tunneling microscopy on highly oriented pyrolytic graphite surfaces. The chain-length effect was observed in the self-assembly BAF-Cn. Self-assembly BAF-C1 composed linear I pattern, where side adopted fully interdigitated arrangement. As length increased,...
We design a bifunctional molecule (5-bromo-2-hexadecyloxy-benzoic acid, 5-BHBA) with bromine atom and carboxyl group its two-dimensional self-assembly is experimentally theoretically investigated by using scanning tunneling microscopy (STM) density functional theory (DFT) calculations. The supramolecular self-organization of 5-BHBA in two different solvents (1-octanoic acid n-hexadecane) at the liquid-solid interface solution concentrations obviously due to cooperative competitive...
This study presents efficient strategies on manipulation of hydrogen bonds and dipole–dipole induced chiral achiral self-assembly nanostructures.
We report a scanning tunneling microscopy (STM) study of the molecular self-assembly biphenyl-3,3',5,5'-tetracarboxylic acid (BPTC) at octanoic acid/graphite interface. STM revealed that BPTC molecules generated stable bilayers and monolayers under high low sample concentrations, respectively. Besides hydrogen bonds, were stabilized by π-stacking, whereas maintained solvent co-adsorption. A thermodynamically Kagomé structure was obtained upon mixing with coronene (COR), while kinetic...
Dietary advanced glycation end products (AGEs) are formed via the Maillard reaction in foods, especially reheated and can cause chronic diseases. In this study, a series of reaction-based time-temperature indicators (TTIs: TTI-1, TTI-2, TTI-3) were developed with lysine xylose for monitoring dynamic formation fluorescent AGEs foods. The discoloration kinetics TTIs dynamics AGE explored. Formulas derived to illustrate relationship color change time temperature. activation energies (E values)...
Understanding the molecular self-assembly behavior, especially at microscopic level, sheds light on rational design of artificial supramolecular systems surfaces. In this work, scanning tunneling microscopy (STM) and force field simulations were utilized to explore two where four carboxyl groups are symmetrically modified onto a skeleton. The target molecules 4,4'-(ethyne-1,2-diyl) dibenzoic acid (EBA) 1,1'-ethynebenzene-3,3',5,5,'-tetracarboxylic (TCA). former assembly led robust close...
In this present work, a scanning tunneling microscope (STM) operated under ambient conditions was utilized to probe the self-assembly behavior of 2,7-bis-nonyloxy-9-fluorenone (F-OC9) at liquid-solid (l/s) interface. On highly oriented pyrolytic graphite (HOPG) surface, two-dimensional (2D) polymorphism with diversity intermolecular dipole interactions induced by solvent found. Solvents ranged from hydrophilic solvating properties high polarity, such as viscous alkylated acids, nonpolar...
The self-assembly of 2,7-bis(decyloxy)-9-fluorenone on highly oriented pyrolytic graphite is investigated at the solid/gas interface by scanning tunneling microscopy, which allows us to determine effect its molecular structure formation monolayer morphology. By varying solution concentration in dichloromethane, seven types supramolecular assemblies can be obtained. concentration-dependent structural polymorphism discussed terms thermodynamics. In particular, these different patterns are...
Lithium metal is considered as one of the most promising anode materials for high-energy-density rechargeable batteries. However, uncontrolled dendrite growth, unstable interface between lithium and electrolyte, infinite volume change are major obstacles in their practical applications. Constructing a solid electrolyte interphase (SEI) with high strength, good stability desirable flexibility approaches to mitigate expansion induce uniform deposition dendrite-free anode. Herein, we summarize...
Alkyl chain number and position effects are explored <italic>via</italic> the fabrication regulation of 2D self-assemblies at liquid/HOPG interfaces.