A5081889383- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Catalytic Cross-Coupling Reactions
- Organic Light-Emitting Diodes Research
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Click Chemistry and Applications
- Advanced Nanomaterials in Catalysis
- Metal-Organic Frameworks: Synthesis and Applications
- Synthetic Organic Chemistry Methods
- Catalytic C–H Functionalization Methods
- CO2 Reduction Techniques and Catalysts
- Radical Photochemical Reactions
- bioluminescence and chemiluminescence research
- Lanthanide and Transition Metal Complexes
- Advanced biosensing and bioanalysis techniques
- Crystallography and molecular interactions
- Nanoplatforms for cancer theranostics
- Photodynamic Therapy Research Studies
- Metal complexes synthesis and properties
- Luminescence and Fluorescent Materials
École Nationale Supérieure d'Ingénieurs de Caen
2017
Université de Caen Normandie
2014-2017
Laboratoire de Chimie Moléculaire et Thioorganique
2014-2016
Centre National de la Recherche Scientifique
2014-2016
Normandie Université
2014-2016
We describe the synthesis of new cationic tricoordinated copper complexes bearing bidentate pyridine-type ligands and N-heterocyclic carbene as ancillary ligands. These were fully characterized by NMR, electrochemistry, X-ray analysis, photophysical studies in different environments. Density functional theory calculations also undertaken to rationalize assignment electronic structure properties. possess a stabilizing CH−π interaction leading high stability both solid liquid states. In...
In this work, 29 iridium(III) heteroleptic organometallic complexes based on four cyclometalating and eight ancillary ligands were incorporated in a cross-linked copolymer. The photophysical properties of the chloroform solution polymer matrix studied. Preliminary scintillation behaviours samples, such as influence iridium complex concentration within or relative radioluminescence intensity each sample are given. scintillators showed promising yields (up to 1500 ph MeV−1) without use primary...
Two new series of cyclometalated iridium(III) complexes bearing a dipyridylamine as the N^N ligand have been prepared and fully characterized. After investigation their photophysical properties, catalytic activities evaluated in model photoredox reaction compared with commercially available [Ir(ppy)2(dtbbpy)][PF6] complex.
Cyclometallated iridium(iii) dipyridylamine complexes present antibacterial activity against P. aeruginosa, a highly resistant pathogenic bacterium. This is increased when the complex conjugated to biotin, bacterial nutrient, and MIC of 4 μM (4 μg mL-1) has been observed. The irradiation aeruginosa cultures with blue LED light potentiates anti-bacterial activities these they are glycoside.