A5100387297- Crystallography and molecular interactions
- Luminescence and Fluorescent Materials
- Analytical Chemistry and Chromatography
- Supramolecular Self-Assembly in Materials
- Crystallization and Solubility Studies
- Antimicrobial agents and applications
- Surface Chemistry and Catalysis
- Characterization and Applications of Magnetic Nanoparticles
- Computational Drug Discovery Methods
- Chemical Synthesis and Analysis
- Polydiacetylene-based materials and applications
- Supramolecular Chemistry and Complexes
- Iron oxide chemistry and applications
- Synthesis and Properties of Aromatic Compounds
- Geomagnetism and Paleomagnetism Studies
- Antimicrobial Peptides and Activities
Beijing National Laboratory for Molecular Sciences
2018-2023
Peking University
2018-2023
Ministry of Education
2018
Abstract Selective crystallization represents one of the most economical and convenient methods to provide large-scale optically pure chiral compounds. Although significant development has been achieved since Pasteur’s separation sodium ammonium tartrate in 1848, this method is still fundamentally low efficient (low transformation ratio or high labor). Herein, we describe an enantiomer-selective-magnetization strategy for quantitatively separating crystals conglomerates by using a kind...
Abstract Collection of two optically pure enantiomers in a single crystallization process can significantly increase the chiral separation efficiency but this is difficult to realize. Now self‐reporting strategy presented for visualizing by dyed self‐assembled inhibitor made from copolymers with tri(ethylene glycol)‐grafting polymethylsiloxane as main chain and poly(N 6 ‐methacryloyl‐ l ‐lysine) side chains. When applied seeds together fractional conglomerates, inhibitors label formation...
Abstract Hierarchically ordered chiral crystals have attracted intense research efforts for their huge potential in optical devices, asymmetric catalysis and pharmaceutical crystal engineering. Major barriers to the application been use of costly enantiomerically pure building blocks difficulty precise control chirality transfer from molecular macroscopic level. Herein, we describe a strategy that offers not only preferred formation one enantiomorph racemic solution but also subsequent...
Abstract Collecting both enantiomorphs with high optical purity and yield in a single crystallization process can be achieved by adding aggregated polymeric “tailor‐made” additives, known as nano‐splitters. Inefficient preparation large addition amount have hindered the practical application of such amazing nanoparticles. Herein, we report first nano‐splitters containing aggregation‐induced emission luminogens prepared via polymerization‐induced self‐assembly block copolymer, poly[( S...
Abstract Collection of two optically pure enantiomers in a single crystallization process can significantly increase the chiral separation efficiency but this is difficult to realize. Now self‐reporting strategy presented for visualizing by dyed self‐assembled inhibitor made from copolymers with tri(ethylene glycol)‐grafting polymethylsiloxane as main chain and poly(N 6 ‐methacryloyl‐ l ‐lysine) side chains. When applied seeds together fractional conglomerates, inhibitors label formation...
A series of novel gradient copolymers <italic>R</italic>-(−)-poly(StN-<italic>grad</italic>-C8) were synthesized through atom transfer radical copolymerization an achiral styrenic monomer, <italic>N</italic>,<italic>N</italic>-dimethyl-4-ethenylbenzamide (M-StN), and a chiral bulky vinylterphenyl (−)-2,5-bis{4′-[(<italic>R</italic>)-<italic>sec</italic>-octyloxycarbonyl]phenyl}styrene (<italic>R</italic>-(−)-M-C8).