A5012263133- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Crystallography and molecular interactions
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Supramolecular Chemistry and Complexes
- Lanthanide and Transition Metal Complexes
- Metal complexes synthesis and properties
- Crystal structures of chemical compounds
- Molecular Sensors and Ion Detection
- Covalent Organic Framework Applications
- Electric Motor Design and Analysis
- Organometallic Compounds Synthesis and Characterization
- Organometallic Complex Synthesis and Catalysis
- Polyoxometalates: Synthesis and Applications
- Metal-Catalyzed Oxygenation Mechanisms
- Electrocatalysts for Energy Conversion
- Vacuum and Plasma Arcs
- Organoselenium and organotellurium chemistry
- Magnetic Properties and Applications
- Analytical Chemistry and Chromatography
- Catalysis and Hydrodesulfurization Studies
- Porphyrin and Phthalocyanine Chemistry
- Power System Optimization and Stability
- Inorganic Fluorides and Related Compounds
Monash University
2016-2025
Australian Regenerative Medicine Institute
2015-2025
IITB-Monash Research Academy
2019-2023
Clayton Foundation
2015-2020
University of Mumbai
2019
Indian Institute of Technology Bombay
2019
St. Mary's University, Texas
2016-2018
CSIRO Manufacturing
2014
Southwest Research Institute
2012
University of Huddersfield
2009
A lumped-parameter thermal model is described which provides both a steady-state and transient solution to the temperatures within an electrical machine of TEFC design. The sufficiently complex identify at most locations in machine, including peak endwinding surface rotor. It formulated out purely dimensional information constant coefficients therefore easily adapted range frame sizes. behaviour accurately by just eight linear differential equations. suitable for application online...
Herein, we report a series of CuPd catalysts for electrochemical hydrogenation (ECH) furfural to 2-methylfuran (MF or FurCH3 where Fur=furyl) in aqueous 0.1 M acetic acid (pH 2.9). The highest faradaic efficiency (FE) MF reached 75 % at -0.58 V vs. reversible hydrogen electrode with an average partial current density 4.5 mA cm-2 . In situ surface-enhanced Raman spectroscopic and kinetic isotopic experiments suggested that electrogenerated adsorbed (Hads ) was involved the reaction...
The synthesis, anion binding, and conformational properties of a series 3-aminopyridinium-based, tripodal, tricationic hosts for anions are described. Slow exchange on the (1)H NMR time scale at low temperature, coupled with titration, results in high level understanding anion-binding compounds, particularly respect to significant change resulting from induced fit complexation. Peak selectivity halides, Cl(-), is observed. approach has been extended dipodal tripodal podands based...
Furfural is regarded as one of the most promising bio-based feedstocks in bio-refinery industry. Selective hydrogenation carbonyl bond furfural plays a vital role its conversion to downstream products. Electrochemical (ECH) method provides green and sustainable way for this reaction. Yet, it still suffers from harsh pH conditions low selectivity highly reduced products, such 2-methylfuran. In study, high faradaic efficiencies over 90% furfuryl alcohol 60% 2-methylfuran were obtained...
Tripodal tris(urea) cationic receptors 1 and 2 containing p-tolyl or octyl substituents, respectively, have been synthesized, their association behavior with anionic guests has studied via a variety of methods. The are based around hexasubstituted aryl core contain both urea pyridinium functionalities. For 1:1 complexes, anions reside within the central cavity host species, held by hydrogen bonds from NH CH donors. following host-anion complexes characterized X-ray crystallography: 1-(Br)3,...
An optimal coordinated voltage controller (OCVC) is developed based on the spirit of model predictive control (MPC) method. The OCVC consists three components, namely a predictor, candidate pool, and selector. It has been used in secondary (SVC) to coordinate dissimilar actions at different geographical locations order maintain desired profiles global sense emergencies. A single-stage Euler state predictor (SESP) utilized, system model, predict performance under selected actions; selection...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface areas and porosities of iron(III)- iron(II)-derived oxyhydroxidesStuart A. Crosby, Douglas R. Glasson, Alan H. Cuttler, Ian. Butler, David Turner, Michael. Whitfield, Geoffrey E. MillwardCite this: Environ. Sci. Technol. 1983, 17, 12, 709–713Publication Date (Print):December 1, 1983Publication History Published online1 May 2002Published inissue 1 December...
A series of lanthanum benzoate complexes have been prepared and structurally characterised as DMF or DMSO solvates. The structures these vary considerably a function the steric bulk ligands degree solvation. With one exception, all form coordination polymers. These experimental results are compared to reported data from Cambridge Structural Database (CSD) in order study role sterically bulky substituents complexes. Binding modes η1 carboxylic acid co-ligand carboxylate adopting bridging μ-η2...
Abstract The monoclonal antibody C14/1/46/10 which defines the Y hapten carbohydrate antigen (Brown et a., 1983) was shown, by indirect immunoperoxidase technique, to stain tissue sections of 96% colo‐rectal adenocar‐cinomas and 100% adenomas. In contrast, a defining related H type‐2 blood‐group found 86% adenocarcinomas 32% percentage cells stained for both antigens was, on average, greater in group O than A patients. adenomas focal pattern expression observed, antigen, that characteristic...
The chemistry of the anions dicyanamide and tricyanomethanide (dca tcm, respectively) has produced a plethora discoveries over past few decades, particularly in relation to transition-metal coordination polymers with magnetic coupling. Over recent years there have been an increasing number reports heterofunctionalised cyano-containing anions, typically derivatives dicyanomethanide. Our own group concerned amide- nitroso-functionalised carbamoyldicyanomethanide (cdm) dicyanonitrosomethanide...
A series of iron(III) 1-D polymeric materials the general formula [Fe(III)(Schiff-base)(L)](BPh(4)).n(CH(3)OH) (Schiff base = N,N'-ethylenebis(salicylaldimine) (H(2)salen), N,N'-o-phenylenebis(salicylaldimine) (H(2)salophen) and N,N'-ethylenebis(acety1acetone)-2,2'-imine (H(2) acen); L bridging di-pyridyl or di-imidazole ligand, n 0-4) analogues therein, have been synthesised structurally magnetically characterised. In this series, a range structural motifs are observed including linear...
Self-assembling systems in nature display remarkable complexity with assemblies of different sub-units to generate functional species. Synthetic analogues such are a challenge, often requiring the ability bias distributions that under thermodynamic assembly control. Using lantern-type MOCs (metal-organic cages) as prototypical self-assembling system, herein we explore role steric bulk plays controlling exchange rate ligands paddlewheel-based assemblies, and thus stability cages, competitive...
Abstract The ability of an octanuclear cubic coordination cage to catalyse a nucleophilic aromatic substitution reaction on cavity‐bound guest was studied with 2,4‐dinitrofluorobenzene (DNFB) as the guest/substrate. It found that DNFB undergoes catalysed hydroxide ions within cavity (in aqueous buffer solution, pH 8.6). rate enhancement k cat /k uncat determined be 22, binding being required for catalysis occur. product, 2,4‐dinitrophenolate (DNP), remained bound due electrostatic...
Assembly of a silver(I) complex simple pyridyl ligand containing urea derivative is templated by nitrate; analogous complexes Ag(2)SO(4) and AgCF(3)SO(3) exhibit radically different geometries.
We report the synthesis and X-ray crystal structures of a series pyridyl ureas type currently topical in anion binding supramolecular gelation applications, along with their anion-binding ability solution. The simple are dominated by urea···N(pyridyl) hydrogen bonding, because steric congestion urea carbonyl intramolecular CH···O interations. However, introducing further competing synthon form alkenic or π-stacking interactions causes gradual changeover, through number interesting...