A5102977413- Crystallization and Solubility Studies
- Chemical and Physical Properties in Aqueous Solutions
- Catalysis for Biomass Conversion
- Advanced Battery Technologies Research
- Polyoxometalates: Synthesis and Applications
- Nanoparticles: synthesis and applications
- Atomic and Subatomic Physics Research
- Supercapacitor Materials and Fabrication
- Calcium Carbonate Crystallization and Inhibition
- Quantum, superfluid, helium dynamics
- Advanced Battery Materials and Technologies
- Cyclone Separators and Fluid Dynamics
- Methane Hydrates and Related Phenomena
- Natural product bioactivities and synthesis
- Advancements in Battery Materials
- Electrochemical sensors and biosensors
- Pharmacological Effects of Natural Compounds
- Thermochemical Biomass Conversion Processes
- Combustion and flame dynamics
- Chromatography in Natural Products
- Ionic liquids properties and applications
- Advanced Nanomaterials in Catalysis
- Granular flow and fluidized beds
- Phase Equilibria and Thermodynamics
- Electrocatalysts for Energy Conversion
Shenzhen Maternity and Child Healthcare Hospital
2024
Shantou University
2024
Zhejiang University
2018-2022
Quzhou University
2020-2022
Abstract Uncontrollable dendritic behavior and infinite volume expansion in alkali metal anode results the severe safety hazards short lifespan for high‐energy batteries. Constructing a stable host with superior Na/Li‐philic properties is prerequisite commercialization. Here, it demonstrated that small Gibbs free energy change reaction between oxide (Co 3 O 4 , SnO 2 CuO) key infusion. The as‐prepared hierarchical Co nanofiber–carbon sheet (CS) skeleton shows improved wettability toward...
2,5-Furandicarboxylic acid (FDCA), which is currently prepared by catalyzing the oxidation of 5-hydroxymethylfurfural (HMF), a biobased platform compound with broad market prospects. Herein, detailed free-radical chain reaction mechanism consisting both main and side pathways was proposed to describe liquid-phase air process 2,5-furandicarboxylic over Co/Mn/Br catalyst. The higher reactivity hydroxymethyl group than aldehyde for HMF first explained according retardation effect alcohols on...
In this contribution, readily available 5-methyl furfural (MF) derived from biomass was used as an excellent substitute of the chemically unstable 5-hydroxymethylfurfural (HMF) for preparing commercial precursor 2,5-furandicarboxylic acid (FDCA). MF catalytically oxidized by air into FDCA in acetic over homogeneous Co/Mn/Br catalysts at 130–170 °C. It found that both reactivity and ring chemical stability have a remarkable impact on yield aromatic dicarboxylic acids. The effects reaction...
The solubilities of 2,5-furandicarboxylic acid (FDCA) in binary acetic + water, methanol and ethanol water solvent mixtures were measured by a static analytical method with the mass fraction varying from 0 to 0.3 at atmospheric pressure. Furthermore, molar enthalpy fusion (ΔfusH = 55.131 kJ/mol) temperature (Tfus 614.45 K) FDCA determined differential scanning calorimetry. non-random two liquid (NRTL) model parameters used correlate these solubility data, relevant regressed least-squares...
Solubilities of isophthalic acid in ternary mixtures acetic + water benzoic were determined by the static analytical method. The temperature range was from 292.55 to 372.10 K, mass ratios 0, 1:9, and 1:4, fractions initial solvent ranged 0 20.1%. experimental results indicated that solubility increased with introduction binary solvents water, could be explained Hansen's three-dimensional parameters like-dissolves-like rule. Then solubilities correlated nonrandom two liquids (NRTL) model,...
Oxidative stress during sepsis could play a crucial role in the pathogenesis of several diseases, especially cardiovascular disorders. In fact, myocardial dysfunction is caused by number chemicals, one which hydrogen peroxide (H2O2). Therefore, sepsis‐induced cardiomyopathy can be controlled through modulation oxidative stress. Despite encouraging pharmacological activities demonstrated inorganic nanostructures, mechanisms behind their blood protein interaction and antioxidant activity...
Ammonium sulfate [(NH4)2SO4], an undesired byproduct in the caprolactam process, can be converted into recyclable NH3 by substitution reaction with lime milk to reduce ammonia consumption and produce high-quality gypsum. However, thermodynamic mechanism of this process has not been clarified, which results unpredictable crystal phase calcium products. In work, a model for CaSO4–(NH4)2SO4–NH3–H2O quaternary system asymmetric E-NRTL activity coefficient was developed understand behavior. The...