A5073792514- Ionic liquids properties and applications
- Conducting polymers and applications
- Zeolite Catalysis and Synthesis
- Pharmacological Effects of Natural Compounds
- Electrocatalysts for Energy Conversion
- Oxidative Organic Chemistry Reactions
- Synthesis and biological activity
- Mesoporous Materials and Catalysis
- Computational Drug Discovery Methods
- Advanced battery technologies research
- Inorganic Fluorides and Related Compounds
- Polyoxometalates: Synthesis and Applications
- Electrochemical sensors and biosensors
- Catalytic Processes in Materials Science
University of Illinois Urbana-Champaign
2022-2024
Indian Institute of Technology Madras
2020
Central Leather Research Institute
2015
Homogeneous catalysts have rapid kinetics and keen reaction selectivity. However, their widespread use for industrial catalysis has remained limited because of challenges in reusability. Here, we propose a redox-mediated electrochemical approach catalyst recycling using metallopolymer-functionalized electrodes binding release. The redox platform was investigated the separation key platinum palladium homogeneous used organic synthesis chemical manufacturing. Noble metal hydrosilylation,...
Leveraging specific noncovalent interactions can broaden the mechanims for selective electrochemical separations beyond solely electrostatic interactions. Here, we explore redox-responsive halogen bonding (XB) electrosorption in nonaqueous media, by taking advantage of directional XB alongisde a cooperative and synergistic ferrocene redox-center. We designed evaluated new redox-active donor polymer, poly(5-iodo-4-ferrocenyl-1-(4-vinylbenzyl)-1
Solvent molecules within zeolite pores provide interactions that influence the stability of reactive intermediates and impact rates selectivities for catalytic reactions. We show kinetic thermodynamic consequences these reveal their origins using alkene epoxidations in titanium-substituted *BEA (Ti-BEA) zeolites. Epoxidation turnover vary widely among primary n-alkenes (C6–C18) hydrophilic (Ti-BEA-OH) hydrophobic (Ti-BEA-F) catalysts aqueous acetonitrile (CH3CN). Apparent activation...
In this study, an attempt has been made to investigate the mechanistic pathway for aerobic oxidation of alcohols over nitrogen-doped graphene using density functional theory methods employing a suitable model graphene. The formation activated oxygen species (AOS), upon oxidation, by dioxygen investigated with aid various possible models. detailed reaction mechanism benzyl alcohol and ethanol three AOS obtained in present study unraveled. Results indicate that ketonic oxidizes aromatic...
Triterpenoids possess valuable medicinal properties ranging from anti-microbial to anti-cancer. Some of them were known for their activity against HIV, Ebola and Influenza viruses. In this study, 108 triterpenoids screened its potential usage as anti-viral drug SARS-CoV-2, MERS SARS coronaviruses, using molecular docking calculation main proteases (M pro ) ADME based drug-likeliness parameters.