A5087476156- Electrocatalysts for Energy Conversion
- Advanced battery technologies research
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Advanced Photocatalysis Techniques
- Metal-Organic Frameworks: Synthesis and Applications
- Fuel Cells and Related Materials
- Polyoxometalates: Synthesis and Applications
- Catalytic Processes in Materials Science
- Luminescence and Fluorescent Materials
- Electrochemical Analysis and Applications
- Advanced Nanomaterials in Catalysis
- Ammonia Synthesis and Nitrogen Reduction
- Advancements in Battery Materials
- Semiconductor materials and devices
- Nanoplatforms for cancer theranostics
- Advanced Memory and Neural Computing
- Crystallography and molecular interactions
- Covalent Organic Framework Applications
- Chemical Synthesis and Reactions
- Advanced ceramic materials synthesis
- Organometallic Complex Synthesis and Catalysis
- Supramolecular Chemistry and Complexes
- Nanomaterials for catalytic reactions
- Organic Light-Emitting Diodes Research
Jining University
2015-2024
Nankai University
2023-2024
State Key Laboratory of Medicinal Chemical Biology
2023
Guizhou University
2022
Linyi City Chinese Medicine Hospital
2022
Qufu Normal University
2014-2020
Shandong Normal University
2017-2018
Nanjing Normal University
2013-2016
Second Hospital of Shandong University
2012
Shanghai Institute of Organic Chemistry
1981-1986
Abstract Electrochemical water splitting is one of the most economical and sustainable methods for large-scale hydrogen production. However, development low-cost earth-abundant non-noble-metal catalysts evolution reaction remains a challenge. Here we report two-dimensional coupled hybrid molybdenum carbide reduced graphene oxide with ternary polyoxometalate-polypyrrole/reduced nanocomposite as precursor. The exhibits outstanding electrocatalytic activity excellent stability in acidic media,...
A novel nitrogen-doped Fe/Fe<sub>3</sub>C@graphitic layer/carbon nanotube hybrid derived from MOFs has been first fabricated by a facile approach. The exhibited outstanding bifunctional electrocatalytic activity for ORR and OER.
The nitrogen (N), phosphorus (P) and sulphur (S) ternary-doped metal-free porous carbon materials have been successfully synthesized using MOFs as templates (denoted NPS-C-MOF-5) for oxygen reduction reaction (ORR) the first time. influences of carbons from carbonizing different carbonization temperature on ORR systematically investigated. Due to synergistic effect N, P S ternary-doping, NPS-C-MOF-5 catalyst shows a higher onset potential electrocatalyst among currently reported...
Novel Fe<sub>3</sub>C/Mo<sub>2</sub>C-containing N, P co-doped graphitic carbon derived from POM@MOF-100 (Fe) has been synthesized for the first time. The nanomaterial shows an outstanding electrocatalytic performance hydrogen evolution reaction in acidic media.
Highly efficient electrocatalysts for hydrogen evolution reactions (HER) are crucial electrochemical water splitting, where high-cost and low-abundance Pt-based materials the benchmark catalysts HER. Herein, we report fabrication of MoP nanoparticles confined in P-doped porous carbon (MoP@PC) via a metal–organic framework-assisted route first time. Remarkably, due to synergistic effects nanocrystals, P dopant, carbon, resulting MoP@PC composite exhibits superior HER catalytic activity with...
A novel MOF-templated nitrogen and sulphur co-doped porous material has been first synthesized. The representative NS(3 : 1)–C-MOF-5 shows high ORR activity, even comparable to commercial Pt–C.
Exploiting high-performance, low-cost, and robust bifunctional catalysts toward electrochemical water splitting is of great importance, but remains challenging.
Benzene, toluene and pyridine are widely used as essential raw materials in industry laboratory research, with stringent purity requirements. Herein, we show that solid double-cavity host nor-seco-cucurbit[10]uril (ns-Q[10]) functions an efficient adsorption separator for pyridine; benzene can be obtained >99.9 % by this method. Thermal removal of from ns-Q[10]⋅Py2 allows 10 separation cycles without erosion performance. The geometry the ternary complex was established single-crystal X-ray...
Abstract Room‐temperature phosphorescent (RTP) materials have great potential for in vivo imaging because they can circumvent the autofluorescence of biological tissues. In this study, a class organic‐doped long‐wavelength (≈600 nm) RTP with benzo[c][1,2,5] thiadiazole as guest was constructed. Both host and molecules simple structures be directly purchased commercially at low cost. Owing to long phosphorescence wavelength doping system, it exhibited good tissue penetration (10 mm). Notably,...
A series of remarkable crystalline compounds containing metallapillararene/metallacalixarene metal-organic frameworks (MOFs), [Ag5(pyttz)3·Cl·(H2O)][H3SiMo12O40]·3H2O (1), [Ag5(trz)6][H5SiMo12O40] (2), [Ag5(trz)6][H5GeMo12O40] (3), and [Ag5(trz)6][H4PW12O40] (4) (pyttz = 3-(pyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl, trz 1,2,4-triazole), have been obtained by using a simple one-step hydrothermal reaction silver nitrate, pyttz for 1 2–4, Keggin type polyoxometalates (POMs). Crystal...
A coupled hybrid of molybdenum phosphide (MoP) and reduced graphene oxide has been prepared for the first time utilizing Mo-MOFs as precursors through a facile method. The nanocomposite exhibits superior electrocatalytic performance towards HER, is one best high-performance MoP-based electrocatalysts under acidic conditions reported so far.
RuP2 embedded in P-doped porous carbon hybrids as pH-universal catalysts for the HER show extraordinary catalytic activity and long-term stability.
Abstract Development of the powerful building block is great significance to construct materials with advanced properties. Herein, for first time, a triazole‐based luminescent core balanced twist and conjugation reported, which explored D‐A near‐infrared (NIR) aggregation‐induced emission luminogens (TPT‐DCM) high molar extinction coefficient, good brightness excellent reactive oxygen species generation rate. These features enable it function as nanoprobe ultralong NIR afterglow luminescence...
For exploring the multifold helical fabrication of polyoxometalate (POM)-based hybrid compounds, four POM-based crystalline compounds with different meso-helices, H3[Ag27(trz)16(H2O)6][SiW12O40]2·5H2O (1), H[Ag27(trz)16(H2O)4][PW12O40]2·2H2O (2), [Ag23(trz)14(H2O)2][HSiW12O40] (3), and [Ag23(trz)14(H2O)2][PW12O40] (4), were successfully isolated by using delicate 1,2,3-triazole ligand silver ions in this work. Crystal analysis reveals that 1 2 3 4 are isomorphous display 2-/4-fold mixed...
Hydrogen as a clean and environmentally friendly energy carrier has attracted extensive interest. Although Pt-based materials have been considered the state-of-the-art catalysts for hydrogen evolution reaction (HER), high-cost low-abundance hinder their practical application. Herein, we report development of reduced graphene oxide (rGO) supported molybdenum phosphide (MoP) encapsulated in P-doped porous carbon (PC) nano-octahedrons derived from polyoxometalate-based metal–organic frameworks...
We synthesized a novel mesoporous Mn2O3 nanostructure as an electrocatalyst support, then Pd–Mn2O3 with different Pd loading amounts were obtained by facile solvothermal method. The demonstrated good competitive ORR activity and high selectivity in alkaline medium, which can be comparable to commercial Pt/C catalysts.