A5067024672- Radical Photochemical Reactions
- Free Radicals and Antioxidants
- DNA and Nucleic Acid Chemistry
- Photochemistry and Electron Transfer Studies
- Sulfur-Based Synthesis Techniques
- Fatty Acid Research and Health
- DNA Repair Mechanisms
- Metabolomics and Mass Spectrometry Studies
- Chemical Synthesis and Reactions
- Synthesis and characterization of novel inorganic/organometallic compounds
- Organoboron and organosilicon chemistry
- Lipid metabolism and biosynthesis
- Oxidative Organic Chemistry Reactions
- Catalytic C–H Functionalization Methods
- Electron Spin Resonance Studies
- Advanced biosensing and bioanalysis techniques
- Lipid Membrane Structure and Behavior
- Organic Chemistry Cycloaddition Reactions
- Redox biology and oxidative stress
- Antioxidant Activity and Oxidative Stress
- Porphyrin and Phthalocyanine Chemistry
- Inorganic and Organometallic Chemistry
- Cancer, Lipids, and Metabolism
- Molecular Junctions and Nanostructures
- Chemical Synthesis and Analysis
Institute of Organic Synthesis and Photoreactivity
2015-2024
Adam Mickiewicz University in Poznań
2007-2024
National Research Council
1997-2024
Bologna Research Area
1999-2022
National Centre of Scientific Research "Demokritos"
2007-2019
Consorzio Roma Ricerche
2008-2018
Institute of Nanoscience and Nanotechnology
2018
New York University
2014
Institute of Organic Synthesis
2012
University of Bologna
1998-2010
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOrganosilanes as radical-based reducing agents in synthesisChryssostomos ChatgilialogluCite this: Acc. Chem. Res. 1992, 25, 4, 188–194Publication Date (Print):April 1, 1992Publication History Published online1 May 2002Published inissue 1 April 1992https://pubs.acs.org/doi/10.1021/ar00016a003https://doi.org/10.1021/ar00016a003research-articleACS PublicationsRequest reuse permissionsArticle Views3982Altmetric-Citations555LEARN ABOUT THESE...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRate constants and Arrhenius parameters for the reactions of primary, secondary, tertiary alkyl radicals with tri-n-butyltin hydrideC. Chatgilialoglu, K. U. Ingold, J. C. ScaianoCite this: Am. Chem. Soc. 1981, 103, 26, 7739–7742Publication Date (Print):December 1, 1981Publication History Published online1 May 2002Published inissue 1 December 1981https://pubs.acs.org/doi/10.1021/ja00416a008https://doi.org/10.1021/ja00416a008research-articleACS...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTris(trimethylsilyl)silane as a radical-based reducing agent in synthesisM. Ballestri, C. Chatgilialoglu, K. B. Clark, D. Griller, Giese, and KoppingCite this: J. Org. Chem. 1991, 56, 2, 678–683Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 January 1991https://pubs.acs.org/doi/10.1021/jo00002a035https://doi.org/10.1021/jo00002a035research-articleACS PublicationsRequest reuse...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTris(trimethylsilyl)silane. A new reducing agentC. Chatgilialoglu, D. Griller, and M. LesageCite this: J. Org. Chem. 1988, 53, 15, 3641–3642Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://pubs.acs.org/doi/10.1021/jo00250a051https://doi.org/10.1021/jo00250a051research-articleACS PublicationsRequest reuse permissionsArticle Views2174Altmetric-Citations197LEARN ABOUT THESE...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTris(trimethylsilyl)silane: an efficient hydrosilylating agent of alkenes and alkynesB. Kopping, C. Chatgilialoglu, M. Zehnder, B. GieseCite this: J. Org. Chem. 1992, 57, 14, 3994–4000Publication Date (Print):July 1, 1992Publication History Published online1 May 2002Published inissue 1 July 1992https://doi.org/10.1021/jo00040a048RIGHTS & PERMISSIONSArticle Views1928Altmetric-Citations166LEARN ABOUT THESE METRICSArticle Views are the...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReduction of silicon-hydrogen bond strengthsJ. M. Kanabus-Kaminska, J. A. Hawari, D. Griller, and C. ChatgilialogluCite this: Am. Chem. Soc. 1987, 109, 17, 5267–5268Publication Date (Print):August 1, 1987Publication History Published online1 May 2002Published inissue 1 August 1987https://pubs.acs.org/doi/10.1021/ja00251a035https://doi.org/10.1021/ja00251a035research-articleACS PublicationsRequest reuse permissionsArticle...
Abstract This Concept shows the flexibility and applicability of (Me 3 Si) SiH in several synthetic transformations, such as radical reductions, consecutive reactions hydrosilylation. The reactivity combines multidisciplinary aspects physical organic chemistry synthesis, extending to polymers materials science, functionalization flat silicon surfaces.
Metabolic homeostasis of fatty acids is complex and well-regulated in all organisms. The biosynthesis saturated (SFA) mammals provides substrates for β-oxidation ATP production. Monounsaturated (MUFA) are products desaturases that introduce a methylene group cis geometry SFA. Polyunsaturated (n-6 n-3 PUFA) elongation desaturation the essential linoleic acid α-linolenic acid, respectively. liver processes dietary exports them lipoproteins distribution storage peripheral tissues. three types...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnergies of Activation. The Paradigm Hydrogen Abstractions by RadicalsAndreas A. Zavitsas and Chryssostomos ChatgilialogluCite this: J. Am. Chem. Soc. 1995, 117, 43, 10645–10654Publication Date (Print):November 1, 1995Publication History Published online1 May 2002Published inissue 1 November 1995https://pubs.acs.org/doi/10.1021/ja00148a006https://doi.org/10.1021/ja00148a006research-articleACS PublicationsRequest reuse permissionsArticle...
The palladium-catalyzed dehalogenation reaction of alkyl or aryl halides with triethylsilane takes place, giving high yields under mild conditions. efficiency the reduction is similar for organic chlorides, bromides, iodides, and presence functionalities such as esters ethers does not interfere outcome reaction.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAbsolute rate constants for the addition of triethylsilyl radicals to various unsaturated compoundsC. Chatgilialoglu, K. U. Ingold, and J. C. ScaianoCite this: Am. Chem. Soc. 1983, 105, 10, 3292–3296Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Published inissue 1 1983https://pubs.acs.org/doi/10.1021/ja00348a055https://doi.org/10.1021/ja00348a055research-articleACS PublicationsRequest reuse permissionsArticle...
Previous studies show that polyunsaturated fatty acids (PUFAs) increase the insulin secretory capacity of pancreatic β-cells. We aimed at identifying PUFA-derived mediators and their cellular targets are involved in amplification release from β-cells preexposed to high glucose levels.The content phospholipids INS-1E was determined by lipidomics analysis. High-performance liquid chromatography used identify peroxidation products β-cell cultures. Static dynamic glucose-stimulated secretion...