A5025991586- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
- Catalytic C–H Functionalization Methods
- Sulfur-Based Synthesis Techniques
- Metal complexes synthesis and properties
- Luminescence Properties of Advanced Materials
- Radical Photochemical Reactions
- Luminescence and Fluorescent Materials
- Radioactive element chemistry and processing
- Synthesis and Biological Evaluation
- Glass properties and applications
- Catalytic Cross-Coupling Reactions
- Synthesis and Catalytic Reactions
- Catalytic Alkyne Reactions
- Computational Drug Discovery Methods
- Covalent Organic Framework Applications
- Catalytic Processes in Materials Science
- Pharmacogenetics and Drug Metabolism
- Neuropeptides and Animal Physiology
- Advanced Photocatalysis Techniques
- Molecular Sensors and Ion Detection
- Fuel Cells and Related Materials
- Synthesis and Reactivity of Heterocycles
- Polyoxometalates: Synthesis and Applications
Anhui Jianzhu University
2022-2025
Nanyang Normal University
2015-2025
CAS Key Laboratory of Urban Pollutant Conversion
2022-2024
University of Science and Technology of China
2020-2024
Anyang Normal University
2016-2024
Harbin Engineering University
2010-2023
Hefei University
2020
Hefei National Center for Physical Sciences at Nanoscale
2020
Shuguang Hospital
2019
Shanghai University of Traditional Chinese Medicine
2019
The development of multimodal nanoprobes that combined properties near-infrared (NIR) fluorescence and magnetic resonance imaging (MRI) within a single probe is very important for medical diagnosis. NIR-emitting persistent luminescent nanoparticles (PLNPs) are ideal optical owing to no need in situ excitation, the absence background noise, deep tissue penetration. However, PLNP based have been reported so far. Here, we report novel nanoprobe on gadolinium complexes functionalized PLNPs...
Radical borylation using N-heterocyclic carbene (NHC)-BH3 complexes as boryl radical precursors has emerged an important synthetic tool for organoboron assembly. However, the majority of reported methods are limited to reaction modes involving carbo- and/or hydroboration specific alkenes and alkynes. Moreover, generation NHC-boryl radicals relies principally on hydrogen atom abstraction with aid initiators. A distinct method is reported, well pathways enabled by photoredox catalysis....
By simply modifying the expansion of ligand tether length, two Cd(ii) metal-organic frameworks have been constructed from linear tetranuclear and trinuclear cadmium clusters, respectively, which present an unprecedented 10-connected uninodal bct net.
Charge separation is very important for increasing the activity of semiconductor-based photocatalysts. Here we show that main active species BiOI are photo-induced holes, rather than ˙OH and O2˙−, under visible light irradiation. Based on this finding, cocatalyst MnOx was used to enhance transfer resulting in much higher photocatalytic activity, compared with photocatalyst without MnOx. MnOx–BiOI heterogeneous nanostructure photocatalysts have been prepared by photo-deposition Mn(NO3)2...
The construction of diversely substituted all-carbon quaternary centers has been a longstanding challenge in organic synthesis. Methods that add three alkyl substituents to simple C(sp3) atom rely heavily on lengthy multiple processes, which usually involve several preactivation steps. Here, we describe straightforward three-step sequence uses range readily accessible activated trichloromethyl groups as the carbon source, C–Cl bonds are selectively functionalized introduce chains. In each...
By modulating the quantity of complexed NH4+ in deposition solution, three distinct morphologies multiphase composite films composed iron vanadate and hydrogen bronze were grown on an indium tin oxide (ITO) conductive substrate using liquid-phase technique. Among them, N-doped FeVO4/Fe2V4O13/HxV2O5 triphase nanosheets exhibit enhanced discharge capacities at a high current density retain capacity 115.1 mAh m-2 after 300 cycles. Cyclic voltammetry tests galvanostatic charge-discharge revealed...
Abstract The crystal structure of the FMN‐binding domain human NADPH‐cytochrome P450 reductase (P450R‐FMN), a key component in cytochrome monooxygenase system, has been determined to 1.93 å resolution and shown be very similar both global fold solution (Barsukov I et al., 1997, J Biomol NMR 10 :63–75) corresponding 2.6 intact rat P450R (Wang M Proc Nat Acad Sci USA 94 :8411–8416). P450R‐FMN reported here confirms overall similarity its α‐β‐α architecture that bacterial flavodoxins, but...
Abstract Herein, we have developed a facile and economic HOTf‐catalyzed synthesis for the construction of quinolines from aldehydes, amines, alkynes/alkenes, which are readily available commercial vendors. The electronic properties substituents on alkynes/alkenes been investigated. It was found that molecules with both electron‐donating electron‐withdrawing were suitable substrates this transformation, expected products obtained in moderate to excellent yields. use single catalytic system...
A practical and effective palladium-catalyzed C-H activation/alkene insertion/annulation has been reported for the synthesis of furans cyclopropanes from cyclic 1,3-diketones or 1,3-indandione diverse alkenes, resulting in moderate to good yields. This protocol demonstrates excellent selectivity is well-compatible with a wide range alkene substrates, exhibiting exceptional regioselectivities, high efficiency, functional group tolerance.
An electrooxidative [3 + 2] annulation between phenols and electron-deficient alkenes for the synthesis of C3-functionalized 2-aryl-2,3-dihydrobenzofuran derivatives is described.
As an efficient and green synthesis method, the electrocatalysis hydrogen evolution coupling reaction has been widely used by chemists to realize combining of two nucleophiles. In this work, alternative method synthesize 6-phosphorylated phenanthridines developed synergistically utilizing Mn catalysis, with moderate relatively good yields achieved. Mild oxidant-free conditions make synthetic applicable in various settings.
A polydentate pyridyl ligand, 2,3,6,7,10,11-hexa(2-pyridyl)-dipyrazino[2,3-<italic>f</italic>:2′,3′-<italic>h</italic>] quinoxaline (HPDQ), was found to have excellent light-emitting selectivity La<sup>3+</sup> over many other lanthanide metal ions (Ce<sup>3+</sup>, Pr<sup>3+</sup>, Nd<sup>3+</sup>, Sm<sup>3+</sup>, Eu<sup>3+</sup>, Gd<sup>3+</sup>, Tb<sup>3+</sup>, Dy<sup>3+</sup>, Ho<sup>3+</sup>, Er<sup>3+</sup>, Tm<sup>3+</sup>, Yb<sup>3+</sup>, and Lu<sup>3+</sup>).
In this study, multifunctional Fe₃O₄@SiO₂@GdVO₄:Dy3+ nanocomposites were successfully synthesized via a two-step method. Their structure, luminescence and magnetic properties characterized by X-ray diffraction (XRD), scanning electronic microscope (SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectra vibrating sample magnetometer (VSM). The results indicated that the as-prepared composites displayed well-defined core-shell structure. show spherical morphology with...
Abstract Radical borylation using N ‐heterocyclic carbene (NHC)‐BH 3 complexes as boryl radical precursors has emerged an important synthetic tool for organoboron assembly. However, the majority of reported methods are limited to reaction modes involving carbo‐ and/or hydroboration specific alkenes and alkynes. Moreover, generation NHC‐boryl radicals relies principally on hydrogen atom abstraction with aid initiators. A distinct method is reported, well pathways enabled by photoredox...
Pyridine carboxylic acid ligand H 3 cppa was used to construct metal complexes by a hydrothermal reaction, and eight new were constructed. Luminescence behavior magnetic properties of investigated.