A5103157738- Silicone and Siloxane Chemistry
- Fluorine in Organic Chemistry
- Chemical Synthesis and Reactions
- Synthesis and characterization of novel inorganic/organometallic compounds
- Synthetic Organic Chemistry Methods
- Chemical Reactions and Mechanisms
- Synthesis and Reactions of Organic Compounds
- Carbon dioxide utilization in catalysis
- Inorganic and Organometallic Chemistry
- Chemical Synthesis and Analysis
- Radioactive element chemistry and processing
- Boron Compounds in Chemistry
- Organic Chemistry Synthesis Methods
- Catalysis and Oxidation Reactions
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Inorganic Fluorides and Related Compounds
- Magnetism in coordination complexes
- Synthesis and properties of polymers
- Ferrocene Chemistry and Applications
- Organoboron and organosilicon chemistry
- Synthesis and Biological Evaluation
- Silicon Nanostructures and Photoluminescence
- Electron Spin Resonance Studies
- Organic Chemistry Cycloaddition Reactions
- Quinazolinone synthesis and applications
Moscow State University of Fine Chemical Technologies
2006-2017
Lomonosov Moscow State University
2009-2015
Moscow Architectural Institute
1994-2012
Abstract A new method of metallasilsesquioxane synthesis is described for the first time. According to this method, a partial nucleophilic cleavage polymeric copper phenylsilsesquioxane by use sym‐cis ‐tetraphenylcyclotetrasiloxanolate nonaethanolate ( 1 ) gave previously unknown binuclear cage‐like silsesquioxane [(PhSiO 1.5 10 (CuO) 2 (NaO 0.5 · 4EtOH] ). The unprecedented structure , so called “Cooling Tower” structure, was confirmed single‐crystal X‐ray diffraction analysis. Compound...
The reaction of pyrrole with hexamethyldisilazane/chloro(chloromethyl)dimethylsilane is shown to lead the formation only transsilylation product—previously unknown 1-[(chloromethyl)dimethylsilyl]-1H-pyrrole. This product was also obtained by counter synthesis through interaction 1-(trimethylsilyl)-1H-pyrrole chloro(chloromethyl)dimethylsilane. Unlike diazoles, in this case no rearrangement Cl–CH2–Si–N bond system into Cl–Si–CH2–N and isomerization silicon methylation are realized.
The cover picture shows a symbolic process of benzene/alcohol oxidation catalysis by the binuclear cage-like copper(II) silsesquioxane with an unprecedented structure (“Cooling Tower”). high catalytic activity this very unusual, frustum-like cage compound gave authors opportunity to ironically represent reaction as “chemical plant” process. Details are discussed in article A. N. Bilyachenko, M. Levitsky, G. B. Shul'pin et al. on p. 5240 ff. For more story behind research, see Cover Profile....