A5011209257- Radical Photochemical Reactions
- Electrochemical Analysis and Applications
- CO2 Reduction Techniques and Catalysts
- Catalytic C–H Functionalization Methods
- Radioactive element chemistry and processing
- Analytical chemistry methods development
- Crystallization and Solubility Studies
- Advanced Chemical Sensor Technologies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Mass Spectrometry Techniques and Applications
- Fluorine in Organic Chemistry
- Electrochemical sensors and biosensors
- Porphyrin and Phthalocyanine Chemistry
- Oxidative Organic Chemistry Reactions
- Photoreceptor and optogenetics research
- Polyoxometalates: Synthesis and Applications
- Magnetism in coordination complexes
- Sulfur-Based Synthesis Techniques
- Inorganic and Organometallic Chemistry
Princeton University
2019-2022
Charging through the looking glass Asymmetric catalysis is a commonly applied technique to prepare just one of two mirror-image products in chemical reaction. But what if you already have compound want, stuck mixture left- and right-handed enantiomers? Shin et al. now show that light-induced electron transfer can trigger favorable succession proton hydrogen-atom steps, both which are susceptible biasing by catalysts, preferentially convert cyclic urea enantiomers into (see Perspective...
While heteroatom-centered radicals are understood to be highly electrophilic, their ability serve as transient electron-withdrawing groups and facilitate polar reactions at distal sites has not been extensively developed. Here, we report a new strategy for the electronic activation of halophenols, wherein generation phenoxyl radical via formal homolysis aryl O–H bond enables direct nucleophilic aromatic substitution halide with carboxylate nucleophiles under mild conditions. Pulse radiolysis...
A new strategy for catalytic deracemization is presented, wherein amine derivatives undergo spontaneous optical enrichment upon exposure to visible light in the presence of three distinct molecular catalysts. Initiated by an excited-state iridium chromophore, this reaction proceeds <i>via </i>a sequence favorable electron, proton, and hydrogen atom transfer steps that serve break reform a stereogenic C–H bond. The enantioselectivity these reactions jointly determined two...
A new strategy for catalytic deracemization is presented, wherein amine derivatives undergo spontaneous optical enrichment upon exposure to visible light in the presence of three distinct molecular catalysts. Initiated by an excited-state iridium chromophore, this reaction proceeds via a sequence favorable electron, proton, and hydrogen atom transfer steps that serve break reform stereogenic C–H bond. The enantioselectivity these reactions jointly determined two independent stereoselective...
Department of Chemistry & Division Energy Systems Research, Ajou University, Suwon 443-749, KoreaReceived August 20, 2013, Accepted September 25, 2013Key Words : Coordination polymers, Polymer single crystals, CarbazoleCoordination polymers consisting metal cations andorganic linkers are widely used in fundamental supramole-cular approaches as well various other practical appli-cations.