Luigi Vesce

ORCID: 0000-0003-3322-8688
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About
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Research Areas
  • Perovskite Materials and Applications
  • TiO2 Photocatalysis and Solar Cells
  • Chalcogenide Semiconductor Thin Films
  • Quantum Dots Synthesis And Properties
  • solar cell performance optimization
  • Conducting polymers and applications
  • Advanced Photocatalysis Techniques
  • Transition Metal Oxide Nanomaterials
  • Thin-Film Transistor Technologies
  • Organic Electronics and Photovoltaics
  • Photovoltaic Systems and Sustainability
  • 2D Materials and Applications
  • Organic Light-Emitting Diodes Research
  • Advanced optical system design
  • ZnO doping and properties
  • Nonlinear Optical Materials Studies
  • Silicon and Solar Cell Technologies
  • Botanical Research and Applications
  • Color Science and Applications
  • Solar Thermal and Photovoltaic Systems
  • Electronic and Structural Properties of Oxides
  • Nanowire Synthesis and Applications
  • Light effects on plants
  • Laser Material Processing Techniques
  • Advancements in Solid Oxide Fuel Cells

University of Rome Tor Vergata
2014-2024

Interface engineering of organic-inorganic halide perovskite solar cells (PSCs) plays a pivotal role in achieving high power conversion efficiency (PCE). In fact, the photoactive layer needs to work synergistically with other functional components cell, such as charge transporting/active buffer layers and electrodes. this context, graphene related two-dimensional materials (GRMs) are promising candidates tune "on demand" interface properties PSCs. work, we fully exploit potential GRMs by...

10.1021/acsnano.8b05514 article EN ACS Nano 2018-09-21

Small area hybrid organometal halide perovskite based solar cells reached performances comparable to the multicrystalline silicon wafer cells. However, industrial applications require scaling-up of devices module-size. Here, we report first fully laser-processed large (14.5 cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> ) module with an aperture ratio 95% and a power conversion efficiency 9.3%. To obtain this result, carried out...

10.1109/jphotov.2017.2732223 article EN IEEE Journal of Photovoltaics 2017-08-07

The use of solution processes to fabricate perovskite solar cells (PSCs) represents a winning strategy reduce capital expenditure, increase the throughput, and allow for process flexibility needed adapt PVs new applications. However, typical fabrication PSC development date is performed in an inert atmosphere (nitrogen), usually glovebox, hampering industrial scale-up. In this work, we demonstrate, first time, double-cation (forsaking unstable methylammonium (MA) cation) processed ambient...

10.1021/acsami.0c18920 article EN ACS Applied Materials & Interfaces 2021-03-02

Abstract Perovskite solar cells (PSCs) represent one of the most promising emerging photovoltaic technologies due to their high power conversion efficiency. However, despite huge progress made not only in terms efficiency achieved, but also fundamental understanding relevant physics devices and issues which affect stability, there are still unresolved problems obstacles on path toward commercialization this technology. In roadmap, we aim provide a concise up date summary outstanding...

10.1088/2515-7639/acc893 article EN cc-by Journal of Physics Materials 2023-03-29

Bifacial solar cells (BFSCs) are designed to enhance electrical power generation per unit area compared traditional monofacial cells. They accomplish this by capturing sunlight from both the front and rear surfaces.

10.1039/d3tc03220e article EN cc-by Journal of Materials Chemistry C 2023-12-21

Abstract The efficiency gap between perovskite (PVSK) solar sub‐modules (size ≥200 cm 2 ) and lab scale cells ˂1 is up to 36%. Moreover, the few attempts present in literature used lab‐scale techniques a glove‐box environment, reducing its compatibility for further product industrialization. Here, we report PVSK sub‐module (total area 320 , aperture 201 93% geometrical fill factor [GFF]) fabricated ambient air by hybrid meniscus coating assisted green antisolvent quenching method. To...

10.1002/pip.3741 article EN cc-by Progress in Photovoltaics Research and Applications 2023-11-02

Abstract Perovskite solar cells promise to be part of the future portfolio photovoltaic technologies, but their instability is slow down commercialization. Major stability assessments have been recently achieved reliable accelerated ageing tests on beyond small-area are still poor. Here, we report an industrial encapsulation process based lamination highly viscoelastic semi-solid/highly viscous liquid adhesive atop perovskite and modules. Our encapsulant reduces thermomechanical stresses at...

10.1038/s41467-024-48877-y article EN cc-by Nature Communications 2024-05-29

The versatility of printing technologies and their intrinsic ability to outperform other techniques in large-area deposition gives scope revolutionize the photovoltaic (PV) manufacturing field. Printing methods are commonly used conventional silicon-based PVs cover part production process. Screen techniques, for example, applied deposit electrical contacts on silicon wafer. However, it is with advent third generation that printing/coating have been extensively almost all processes. Among...

10.1088/0268-1242/30/10/104003 article EN Semiconductor Science and Technology 2015-09-21

Organo-metal halide perovskite demonstrates a large potential for achieving highly efficient photovoltaic devices. The scaling-up process represents one of the major challenges to exploit this technology at industrial level. Here, solar modules from 5 × 10 cm2 substrate area is reported by blade coating both CH3NH3PbI3 and spiro-OMeTAD layers. sequential deposition approach used in which lead iodide (PbI2) conversion step are optimized using additives. PbI2 solution modified adding...

10.1021/acsami.9b05730 article EN ACS Applied Materials & Interfaces 2019-06-25

Semitransparent dye-sensitized solar cells (DSSCs) for greenhouse integration were manufactured by using especially designed organic dyes featuring different heterocyclic moieties integrated into a thiazolo[5,4-<italic>d</italic>]thiazole-molecular scaffold.

10.1039/d0se00124d article EN cc-by Sustainable Energy & Fuels 2020-01-01

Our world is facing an environmental crisis that driving scientists to research green and smart solutions in terms of the use renewable energy sources low polluting technologies. In this framework, photovoltaic (PV) technology one most worthy interest. Dye-sensitized solar cells (DSSCs) are innovative PV devices known for their encouraging features cost easy fabrication, good response diffuse light colour tunability. All these make DSSCs suitable being applied so-called agrovoltaic field,...

10.3390/en14196393 article EN cc-by Energies 2021-10-06

Although halide perovskite solar cell (PSC) technology reaches, in few years, efficiencies greater than 25%, the cost‐ceffective perspective is achievable only if scalable processes real manufacturing conditions (i.e., pilot line and/or plant factory) are designed and optimized for full device stack. Herein, a semiautomatic process based on blade‐coating technique demonstrated to fabricate modules ambient conditions. An efficient stable triple‐cation cesium methylammonium formamidinium...

10.1002/solr.202100073 article EN Solar RRL 2021-05-07

The development of next-generation optoelectronic devices relies on the necessity for self-powered, fast, and high-sensitivity photodetectors with a wide-spectral response. This Article investigates impact nickel doping growth ZnO nanorods (79–123 nm diameter) p-type silicon substrate, exploring alterations in photovoltaic characteristics compared to pure counterparts. results reveal enhanced performances ranging from 1% 5%, exhibiting superior behavior across tested parameters. Despite...

10.1021/acsanm.4c00725 article EN ACS Applied Nano Materials 2024-04-17

Perovskite and dye-sensitized solar cells are PV technologies which hold promise for application. Arguably, the biggest issue facing these is stability. The vast majority of studies have been limited to small area laboratory cells. Moisture, oxygen, UV light, thermal electrical stresses leading degradation causes. There remains a shortage stability investigations on large devices, in particular modules. At module level there exist challenges can be different from those at cell such as...

10.1088/1361-6463/50/3/033001 article EN Journal of Physics D Applied Physics 2016-12-08

Organic–inorganic lead halide perovskite has recently emerged as an efficient absorber material for solution process photovoltaic (PV) technology, with certified efficiency exceeding 25%. The development of low-temperature (LT) processing is a challenging topic decreasing the energy payback time solar cell (PSC) technology. In this context, LT planar n–i–p architecture meets all requirements in terms efficiency, scalability, and processability. However, long-term stability PSC under heat...

10.1021/acsami.0c05878 article EN ACS Applied Materials & Interfaces 2020-06-26

Among the technologies adopted in building‐integrated photovoltaics sector, dye‐sensitized solar cells appear very attractive because of unique features like tunable color and good transparency. However, prospect their low‐cost fabrication is realistic only if reliable scalable processes under real manufacturing conditions (i.e., pilot line and/or plant factory) are designed, developed, optimized for large‐area, efficient, stable devices. Herein, a highly reproducible process shown based on...

10.1002/solr.202200403 article EN Solar RRL 2022-05-19

By identifying the right combination of laser parameters, in particular integrated fluence Φ, we fabricated dye solar cells (DSCs) with UV laser-sintered TiO2 films exhibiting a power conversion efficiency η=5.2%, highest reported for devices. η is dramatically affected by Φ and clear trend reported. Significantly, DSCs raster scanning beam to sinter are made as efficient those oven-sintered ones. These results, confirmed on three batches cells, demonstrate remarkable potential (noncontact,...

10.1063/1.3222915 article EN Applied Physics Letters 2009-09-07

ABSTRACT We have designed and fabricated dye solar cell (DSC) modules with optimized geometries processes. Integrated interconnections were made following the “Z” architecture for series connections. Several prepared varying materials, multilayer combination of TiO 2 active layers, fabrication With best multilayers, titanium tetrachloride (TiCl 4 ) treatment, a back reflector/diffusor, layout cells via simulations, we DSC module conversion efficiency 6.9% on 43 cm aperture area 9.4% area....

10.1002/pip.2228 article EN Progress in Photovoltaics Research and Applications 2012-06-20
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