A5029669152- Carbon dioxide utilization in catalysis
- CO2 Reduction Techniques and Catalysts
- Polyoxometalates: Synthesis and Applications
- Catalytic Processes in Materials Science
- Advanced battery technologies research
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
Weizmann Institute of Science
2018-2024
The electrochemical reduction of CO2 has been extensively investigated in recent years, with the expectation that a detailed mechanistic understanding could achieve goal finding stable catalyst high turnover frequencies and low potentials. In catalytic cycle carbon dioxide hydrogenase enzyme, it suggested reduced metal center reacts to form carboxylate intermediate is stabilized by hydrogen bonding using histidine moiety second coordination sphere. Using well-known fac-Re(I)bipyridine(CO)3Cl...
Electrocatalytic CO
Carbon monoxide dehydrogenase (CODH) enzymes are active for the reversible CO oxidation-CO2 reduction reaction and of interest in context CO2 abatement carbon-neutral solar fuels. Bioinspired by active-site composition CODHs, polyoxometalates triply substituted with first-row transition metals were modularly synthesized. The polyanions, short, {SiM3 W9 } {SiM'2 M''W9 }, M, M', M''=CuII , NiII FeIII shown to be electrocatalysts reduction. A catalytic Tafel plot showed that {SiCu3 was most...
Abstract Carbon monoxide dehydrogenase (CODH) enzymes are active for the reversible CO oxidation–CO 2 reduction reaction and of interest in context abatement carbon‐neutral solar fuels. Bioinspired by active‐site composition CODHs, polyoxometalates triply substituted with first‐row transition metals were modularly synthesized. The polyanions, short, {SiM 3 W 9 } {SiM′ M′′W }, M, M′, M′′=Cu II , Ni Fe III shown to be electrocatalysts reduction. A catalytic Tafel plot showed that {SiCu was...