A5060821863- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Industrial Gas Emission Control
- Inorganic Fluorides and Related Compounds
- Carbon Dioxide Capture Technologies
- Membrane Separation and Gas Transport
- Sulfur Compounds in Biology
Universidad Nacional Autónoma de México
2018-2022
Instituto de Investigaciones en Ciencia y Tecnología de Materiales
2018
Mg-CUK-1 exhibited high chemical stability towards H<sub>2</sub>S and H<sub>2</sub>O. Monte Carlo Simulations correlated with uptake.
Mg-CUK-1 showed a 1.8-fold increase in CO<sub>2</sub> capture (from 4.6 wt% to 8.5 wt%) the presence of 18% RH.
The environmentally benign metal-organic framework (MOF) CUK-1 based on 2,4-pyridine dicarboxylate has been prepared for the first time using Mn(II) as inorganic node and water only solvent. Mn-CUK-1 shows reversible efficient capture of H2O, SO2, H2S. Compared to previously studied Co(II) Mg(II) versions same MOF, also exhibited unique temperature-induced structural flexibility due organic linker torsion, detailed by variable-temperature single-crystal X-ray diffraction studies. Owing this...