- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Crystallography and molecular interactions
- Solid-state spectroscopy and crystallography
- Magnetism in coordination complexes
- Chemical Synthesis and Characterization
- Electrochemical Analysis and Applications
- Photochemistry and Electron Transfer Studies
- Perovskite Materials and Applications
- Analytical Chemistry and Sensors
- Crystal Structures and Properties
- Spectroscopy and Quantum Chemical Studies
- Inorganic Chemistry and Materials
- Radioactive element chemistry and processing
- Organic and Molecular Conductors Research
- Molecular Sensors and Ion Detection
- Metal-Organic Frameworks: Synthesis and Applications
- Crystal structures of chemical compounds
- Analytical Chemistry and Chromatography
- Inorganic and Organometallic Chemistry
- Luminescence Properties of Advanced Materials
- Organometallic Compounds Synthesis and Characterization
- Inorganic Fluorides and Related Compounds
- Lanthanide and Transition Metal Complexes
- Synthesis and characterization of novel inorganic/organometallic compounds
NS Kurnakova Institute of General and Inorganic Chemistry
2002-2024
National Research University Higher School of Economics
2018-2024
Russian Academy of Sciences
1999-2019
Institute of General and Inorganic Chemistry
2019
D. Mendeleyev University of Chemical Technology of Russia
2018
Moscow City University
2012-2015
Institute of Natural Science
2012
Moscow State Pedagogical University
2003-2011
Pedagogical University
2004-2010
A. N. Nesmeyanov Institute of Organoelement Compounds
2008
An unexpected mechanism of halogen bonding that cannot be rationalized within the accepted σ-hole model was found in co-crystal N-methylpyrazine iodide with molecular iodine via topological analysis electron density distribution derived from high-resolution X-ray diffraction data.
The crystal structure of a new hybrid iodobismuthate contains linear anionic chains. This black compound is semiconductor (<italic>E</italic><sub>g</sub>= 1.73 eV) and can be proposed as promising material for solar cells.
Outer-sphere charge transfer (OSCT) transitions are shown to correlate with previously published photoelectron emission threshold energies. From these data it is possible generate a set of parameters, I(D) and I(A), which define OSCT energies, where identified as the solution phase vertical ionization potential, I(A) electron affinity. An easy procedure for deriving wide variety cations anions presented. The application leads powerful extracting reorganization solvation energies value in...
The product of Br–I substitution in 1-D (C<sub>15</sub>H<sub>14</sub>N<sub>4</sub>)BiBr<sub>5</sub>·H<sub>2</sub>O can be proposed as a promising material for solid-state solar cells.
Producing new hybrid halobismuthates by the thermal decomposition of corresponding solvates.
The gradual change of the optical properties solid solutions by variation halogen composition is shown.
The experimental charge density in the crystal of disodium pentacyanonitrosoferrate (sodium nitroprusside) dihydrate was analyzed detail by means Bader's atoms molecules theory. It shown that nitroprusside anion is involved relatively strong self-interactions through nitroso group. obtained results agree well with spectroscopic data, indicating tendency corresponding moiety to formation anion−anion association both solutions and crystalline phase.
A series of new type hybrid bromobismuthates formed by various pyrazinium cations were isolated and studied. In the systems initially containing iodide anions monocations substituted pyrazines, complexes based on doubly charged pyrazines instead ones corresponding surprisingly formed. The variation affects not only crystal structures via tuning nuclearity but also hydrolytic stability compounds. thorough structural study transformations was performed for halobismuthates first time. results...
Tuning the optical properties of solid solutions by variation halogen composition.