David Ortiz de Zárate

ORCID: 0000-0003-4127-9338
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About
Contact & Profiles
Research Areas
  • Mesoporous Materials and Catalysis
  • Polyoxometalates: Synthesis and Applications
  • Analytical Chemistry and Sensors
  • Advanced biosensing and bioanalysis techniques
  • Catalytic Processes in Materials Science
  • Zeolite Catalysis and Synthesis
  • Online Learning and Analytics
  • Technology-Enhanced Education Studies
  • Aerogels and thermal insulation
  • E-Learning and Knowledge Management
  • Education and Critical Thinking Development
  • Educational Methods and Media Use
  • E-Learning and COVID-19
  • Knowledge Societies in the 21st Century
  • Electrochemical sensors and biosensors
  • Layered Double Hydroxides Synthesis and Applications
  • Transition Metal Oxide Nanomaterials
  • Problem and Project Based Learning
  • Silicon Nanostructures and Photoluminescence
  • Nanomaterials for catalytic reactions
  • Advanced Biosensing Techniques and Applications
  • TiO2 Photocatalysis and Solar Cells
  • Scientific Research and Technology
  • Educational Curriculum and Learning Methods
  • Nanoporous metals and alloys

Universitat Politècnica de València
2002-2024

Universitat de València
2002-2008

Institut Charles Gerhardt Montpellier
2008

Université de Montpellier
2008

Institut Européen des Membranes
2008

École Nationale Supérieure de Chimie de Montpellier
2008

Centre National de la Recherche Scientifique
2004-2008

Sorbonne Université
2004

Institut des Matériaux Jean Rouxel
2002

Nantes Université
2002

Porous pure and doped silicas with pore sizes at two length scales (meso/macroporous) have been prepared shaped both as powders monoliths through a one-pot surfactant assisted procedure by using simple template agent starting from atrane complexes inorganic precursors.

10.1039/b110883b article EN Chemical Communications 2002-02-05

Nanoparticulated bimodal porous silicas (NBSs) with pore systems structured at two length scales (meso- and large-meso-/macropores) have been prepared through a one-pot surfactant-assisted procedure by using simple template agent starting from silicon atrane complexes as hydrolytic inorganic precursors. The final bulk materials are constructed an aggregation of pseudospherical mesoporous primary nanoparticles process, over the course which interparticle (textural) large system is generated....

10.1021/ic800893a article EN Inorganic Chemistry 2008-08-14

We present here a new family of bimodal porous silicas with organically modified surfaces or frameworks constructed from mesoporous primary nanoparticles. These organosilicas, denoted HPNOs, have been synthesized through one-pot surfactant-assisted procedure by using simple commercial template agent in triethanolamine/water media.

10.1021/cm025650b article EN Chemistry of Materials 2002-10-12

Abstract Silica‐based nanoparticulated bimodal mesoporous materials with high Zr content (43 ≥ Si/Zr 4) have been synthesized by a one‐pot surfactant‐assisted procedure from hydroalcoholic medium using cationic surfactant (CTMABr = cetyltrimethylammonium bromide) as structure‐directing agent, and starting molecular atrane complexes of Si hydrolytic inorganic precursors. This preparative technique allows optimization the dispersion guest species in silica walls. The nature final surface area...

10.1002/ejic.200501140 article EN European Journal of Inorganic Chemistry 2006-04-21

Nanosized Ti-UVM-7 materials with a hierarchical system of pores at two different length scales have been prepared through one-pot procedure by using simple template agent; the catalytic activity and selectivity resulting in bulky olefin epoxidation organic peroxides are highest reported to date.

10.1039/b205856c article EN New Journal of Chemistry 2002-01-01

Nanomaterials with very specific features (purity, colloidal stability, composition, size, shape, location…) are commonly requested by cutting-edge technologic applications, and hence a sustainable process for the mass-production of tunable/engineered nanomaterials would be desirable. Despite this, tuning nano-scale when scaling-up production nanoparticles/nanomaterials has been considered main technological barrier development nanotechnology. Aimed at overcoming these challenging frontier,...

10.3390/nano10030466 article EN cc-by Nanomaterials 2020-03-05

Ordered mesoporous TiO2–NiTiO3 thin films, with nickel content x < 0.5, were prepared by dip-coating an acidic solution of hydrolysed transition metal chlorides in controlled humidity, followed a very careful annealing treatment. These latter treatments studied situ SAXS-WAXS experiments involving synchrotron radiation and TEM analysis. They revealed that the walls can be composed amorphous, single crystalline or multi nanoparticles depending on conditions applied during thermal

10.1039/b416184j article EN New Journal of Chemistry 2004-12-14

We report a new development of the so-called MSU route, first route to use nonionic surfactants and block-copolymers, for synthesis silica with bimodal porosity in micromesoporous range. Among different strategies that have been explored until now, "two-step" process led formation stable hybrid micelles before condensation. This mechanism provided large freedom adjustment reaction parameters consequently final material structure. here these are enough allow them be concentrated through...

10.1021/cm7024558 article EN Chemistry of Materials 2008-01-03

Education 4.0 arises to provide citizens with the technical/digital competencies and cognitive/interpersonal skills demanded by Industry 4.0. New technologies drive this change, though time-independent learning remains a challenge, because students might face lack of support, advice surveillance when teachers are unavailable. This study proposes complementing presential lessons online driven ChatGPT, applied as an educational tool able mentor K-12 science at home. First, ChatGPT’s...

10.20944/preprints202409.1323.v1 preprint EN 2024-09-17

Education 4.0 arises to provide citizens with the technical/digital competencies and cognitive/interpersonal skills demanded by Industry 4.0. New technologies drive this change, though time-independent learning remains a challenge, because students might face lack of support, advice surveillance when teachers are unavailable. This study proposes complementing presential lessons online driven ChatGPT, applied as an educational tool able mentor K-12 science at home. First, ChatGPT’s...

10.3390/knowledge4040031 article EN cc-by Knowledge 2024-12-05

This paper presents the concept of a novel adaptable sensing solution currently being developed under EU Commission founded PHOTONGATE project. will allow to quantify multiple analytes same or different nature (chemicals, metals, bacteria, etc.) in single test with levels sensitivity and selectivity at/or over those offered by current solutions. relies on two core technologies: bio-chemical technology (molecular gates) which confer specificity and, therefore, capability be analyte interest,...

10.20944/preprints202309.1514.v1 preprint EN 2023-09-22

This paper presents the concept of a novel adaptable sensing solution currently being developed under EU Commission-founded PHOTONGATE project. will allow for quantification multiple analytes same or different nature (chemicals, metals, bacteria, etc.) in single test with levels sensitivity and selectivity at/or over those offered by current solutions. relies on two core technologies: biochemical technology (molecular gates), which confer specificity and, therefore, capability to be analyte...

10.3390/s23208548 article EN cc-by Sensors 2023-10-18

UTILIZING ARTIFICIAL INTELLIGENCE AS A TOOL TO ENHANCE STUDENT PARTICIPATION IN THE CLASSROOM THROUGH EFFECTIVE EVALUATION OF RESEARCH WORKS' QUALITY

10.21125/iceri.2023.0688 article EN ICERI proceedings 2023-11-01

LEVERAGING ARTIFICIAL INTELLIGENCE AND PROBLEM-BASED LEARNING TO FOSTER CRITICAL ANALYSIS SCIENTIFIC COMMUNICATION IN GRADUATE STUDENTS

10.21125/iceri.2023.1540 article EN ICERI proceedings 2023-11-01

Many optical sensors exploit the interesting properties of porous materials, as they ensure a stronger interaction between light and analyte directly within structure. Most are mainly based on silicon anodized aluminum oxide, showing high sensitivities. However, top-down strategies usually employed to produce those materials might offer limited control over layer, which could affect homogeneity, reducing sensor reproducibility. In this work, we present bottom-up synthesis mesoporous TiO2...

10.3390/chemosensors9120329 article EN cc-by Chemosensors 2021-11-25

E. Pinilla-Cienfuegos L. Mercadé F.J. Díaz-Fernández M. Gómez J. Navarro-Arenas Sinusia Lozano D. Ortiz de Zárate V.J. Hernández A. Díaz-Rubio

10.21125/inted.2023.1045 article ES INTED proceedings 2023-03-01

Porous materials are currently the basis of many optical sensors because their ability to provide a higher interaction between light and analyte, directly within structure. In this study, mesoporous TiO2 layers were fabricated using bottom-up synthesis approach in order develop sensing structures. comparison with more typical top-down fabrication strategies where bulk constitutive material is etched obtain required porous medium, use potentially allows increasing interconnectivity pore...

10.3390/s22145398 article EN cc-by Sensors 2022-07-20
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