A5076298842- Oxidative Organic Chemistry Reactions
- Metal-Organic Frameworks: Synthesis and Applications
- Porphyrin and Phthalocyanine Chemistry
- Metal-Catalyzed Oxygenation Mechanisms
- Electrocatalysts for Energy Conversion
- Chemical Synthesis and Reactions
- Catalytic Processes in Materials Science
- Covalent Organic Framework Applications
- Advanced Photocatalysis Techniques
- Analytical Chemistry and Chromatography
- CO2 Reduction Techniques and Catalysts
- Sulfur-Based Synthesis Techniques
- Surface Modification and Superhydrophobicity
- Enzyme Catalysis and Immobilization
- Carbohydrate Chemistry and Synthesis
- Synthesis and properties of polymers
- Asymmetric Synthesis and Catalysis
- Inorganic and Organometallic Chemistry
- Nanoparticle-Based Drug Delivery
- Multicomponent Synthesis of Heterocycles
- Catalysis and Oxidation Reactions
- Surfactants and Colloidal Systems
- Protein purification and stability
- Fuel Cells and Related Materials
- Drug Solubulity and Delivery Systems
Zhejiang University of Technology
2013-2024
Hangzhou Xixi hospital
2015-2020
Hangzhou Academy of Agricultural Sciences
2019
Sun Yat-sen University
2011-2014
Metal-organic frameworks (MOFs) are a class of advanced porous crystalline materials. However, numerous MOFs have poor chemical stability, significantly restricting their industrial application. The introduction trifluoromethyl groups around clusters results in shielding effect caused by hydrophobicity and bulkiness, thus preventing guest molecules from attacking the coordination bonds. To prove such effect, position is rationally adjusted, with at ortho positions carboxyl improving...
Developing efficient oxygen evolution catalysts (OECs) made from earth-abundant elements is extremely important since the reaction (OER) with sluggish kinetics hinders development of many energy-related electrochemical devices. Herein, an strategy developed to prepare conjugated microporous polymers (CMPs) abundant and uniform coordination sites by coupling N-rich organic monomer 2,4,6-tris(5-bromopyrimidin-2-yl)-1,3,5-triazine (TBPT) Co(II) porphyrin. The resulting CMP-Py(Co) further...
Photocatalysis is one of the most promising technologies to achieve efficient carbon dioxide reduction reaction (CO2RR) under mild conditions. Herein, metalloporphyrin-based metal–organic frameworks (MOFs) with different metal centers, denoted as PCN-222, were utilized visible-light photocatalysts for CO2 reduction. Due combination conjugated planar macrocyclic structures metalloporphyrins and stable porous MOFs, all PCN-222 materials exhibited excellent light-harvesting CO2-adsorbing...
Fast adsorption of <italic>p</italic>-nitrophenol was achieved through surface immobilization β-cyclodextrin onto hybrid silica and maintenance its hydrophobic cavity.
Photoreduction of CO2 with water into chemical feedstocks fuels provides a green way to help solve both the energy crisis and carbon emission issues. Metal–organic frameworks (MOFs) show great potential for photoreduction. However, poor stability sluggish charge transfer could limit their application. Herein, three water-stable MOFs functionalized electron-donating methyl groups and/or electron-withdrawing trifluoromethyl are obtained Compared UiO-67-o-CF3–CH3 UiO-67-o-(CF3)2,...
Intramolecular hydrogen bonds in ligands restrict the rotation of carboxyl groups and consequently enhance chemical stability MOFs.