- Organic Light-Emitting Diodes Research
- Cardiac Arrhythmias and Treatments
- Luminescence and Fluorescent Materials
- Cardiovascular Conditions and Treatments
- Lanthanide and Transition Metal Complexes
- Veterinary Practice and Education Studies
- Human-Animal Interaction Studies
- Poisoning and overdose treatments
- Cardiac electrophysiology and arrhythmias
- Organic Electronics and Photovoltaics
- Blood Coagulation and Thrombosis Mechanisms
- Organometallic Complex Synthesis and Catalysis
- Atrial Fibrillation Management and Outcomes
- Platelet Disorders and Treatments
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Prenatal Substance Exposure Effects
- Cardiac Arrest and Resuscitation
- Pesticide Exposure and Toxicity
- Cardiac Imaging and Diagnostics
- Cardiovascular Function and Risk Factors
- Veterinary Oncology Research
- Molecular Junctions and Nanostructures
- Trauma and Emergency Care Studies
- Pleural and Pulmonary Diseases
University of Wisconsin–Madison
2022-2025
University of Pennsylvania
2025
Lakeland College
2022-2023
Rhode Island Hospital
2018-2020
Kidney Health Australia
2020
Carolina Veterinary Specialists
2019
NHS Lothian
2019
Brigham and Women's Hospital
2018
Queen Mary University of London
2018
University of British Columbia
2009-2016
This study highlights the potential benefits of using terdentate over bidentate ligands in construction organometallic complexes as organic light-emitting diode (OLED) emitters offering better color purity, and explores detail molecular origins differences between two. A pair closely related platinum(II) has been selected, incorporating a cyclometallating ligand, respectively, namely, Pt(4,6-dFppy)(acac) (1) {4,6-dFppy = 2-(4,6-difluorophenyl)pyridine metalated at C(2) phenyl ring}...
BACKGROUND : Studies were conducted to measure the state of United States' national blood resource in 1992 and changes therein from 1989. STUDY DESIGN AND METHODS With data supplied by American Red Cross Association Blood Banks, as well a stratified random‐sample survey 3350 non‐American Banks hospitals, statistical methods applied estimate activities 1992. RESULTS The total US supply was 13,794,000 units, decrease 3.1 percent Some 11,307,000 red cell units transfused 3,772,000 patients, an...
The intense luminescence of the new complex Ir(ppy)(2)(pybz) (1) within cytoplasm live cells can be discriminated from fluorescence an organic stain, solely on basis emission timescale {pybzH = 2-pyridyl-benzimidazole}. protonated form 1 displays red-shifted emission, and may implicated in a superior uptake compared to Ir(ppy)(3).
By using a tridentate N^C^N-coordinating ligand, the luminescence of cyclometallated Pt(II) complex can be shifted into blue region, without problematic drop-off in quantum yield observed for bidentate analogues. The combination blue-shifted monomer and excimer allows white-emitting OLEDs with high colour rendering index to produced.
The Pt(II) complex N^C2^N-1,3-di(2-pyridyl)benzene platinum chloride (PtL1Cl) is known to display efficient triplet luminescence in the green region of spectrum, and form an unusually emissive excimer that emits around 690 nm. In this contribution, introduction trifluoromethyl groups into either 4- or 5-position pyridyl rings ligand shown lead a red-shift band, moving it near infra-red (NIR) region. new ligands, synthesised by Suzuki Stille cross-coupling methods, are...
A simple way of tuning the emission color and electroluminescence efficiency from vacuum-deposited emitters phosphorescent organic light emitting diodes (LEDs) is demonstrated. For each a single-emissive layer consisting blend two materials, one Pt(N∧C∧N) complex series [where (N∧C∧N)=di(2-pyridinyl)benzene-based tridentate ligands] as either low-concentration bluish green (molecular) phosphorescence emitter or high-concentration red (excimer) emitter,...
A new family of platinum(II) complexes the form PtLnSR have been prepared, where Ln represents a cyclometalating, N∧C∧N-bound tridentate ligand and SR is monodentate thiolate ligand. The fall into two groups, those PtL1SR HL1 = 1,3-bis(2-pyridyl)benzene, PtL2SR, HL2 methyl 3,5-bis(2-pyridyl)benzoate. Each group consists five complexes, R CH3, C6H5, p-C6H4-CH3, p-C6H4-OMe, p-C6H4-NO2. These compounds, which are bright red, orange, or yellow solids, formed readily upon treatment PtLnCl with...
Journal Article Client Satisfaction and Outcome Comparisons of Online Face-to-Face Counselling Methods Get access Lawrence Murphy, Murphy is co-founder Worldwide Therapy a director, clinician trainer with the company. He holds an MA from University British Columbia. Paul Parnass counsellor Inc. runs his own private online practice. MSW Toronto. Daniel Mitchell Rebecca Hallett associate professor in department Environmental Biology at Guelph. Paula Cayley CEO Interlock, division PPC...
Detailed photophysical studies of the emitting triplet state highly phosphorescent compound Pt(dpyb)Cl based on high-resolution optical spectroscopy at cryogenic temperatures are presented {dpyb = N∧C2∧N-coordinated 1,3-di(pyridylbenzene)}. The results reveal a total zero-field splitting T1 10 cm−1 and relatively short individual decay times for two higher lying substates II III, while time lowest substate I is distinctly longer. Further evidence assignment gained by emission measurements...
Abstract OBJECTIVE The investigators sought to reanalyze previously published vertebral heart size (VHS) reference intervals in Yorkshire Terriers (YTs), Pomeranians (POMs), Pugs, and Boston (BTs). METHODS electronic medical records of IDEXX Telemedicine Consultants were searched for YTs, POMs, BTs undergoing radiography between January 1, 2023, March 31, 2023. Dogs included if they had 2- or 3-view thoracic radiographs performed no evidence cardiopulmonary systemic disease. This was an...
Abstract OBJECTIVE To determine the prevalence of vitamin E deficiency in horses at admission and time discharge. The hypothesis was that concentrations would decrease during hospitalization. METHODS A prospective cohort study performed client-owned admitted as patients or companions through emergency service a tertiary referral center. Exclusion criteria included supplementation. Whole blood collected into an additive-free tube for all discharge if horse hospitalized minimum 5 days. Serum...
Abstract Objective To evaluate vertebral heart size (VHS) and left atrial (VLAS) reference intervals in Shetland Sheepdogs (SSs), Cairn Terriers (CTs), Italian Greyhounds (IGs), English Springer Spaniels (ESSs). Methods The electronic medical records of IDEXX Telemedicine Consultants were searched for SSs, CTs, IGs, ESSs undergoing radiography from January 1, 2023, through December 31, 2023. Dogs included if they had 2- or 3-view thoracic radiographs performed no evidence cardiopulmonary...
Three dipicolinic acid amine-derived compounds functionalized with a carboxylate (H3dpaa), phosphonate (H4dppa), and bisphosphonate (H7dpbpa), as well their nonfunctionalized analogue (H2dpa), were successfully synthesized characterized. The 1:1 lanthanum(III) complexes of H2dpa, H3dpaa, H4dppa, the 1:2 complex gallium(III) H3dpaa characterized, including via X-ray crystallography for [La4(dppa)4(H2O)2] [Ga(dpaa)(H2O)]. H4dppa evaluated thermodynamic stability potentiometric either UV–vis...
Abstract Background Slow recruitment and poor retention jeopardize the reliability statistical power of clinical trials, delaying access to effective interventions increasing costs, as commonly observed in nephrology trials. Involving patients trial design, is infrequent but potentially transformational. Methods We conducted three workshops involving 105 patients/caregivers 43 health professionals discussing patient trials chronic kidney disease. Results identified four themes. ‘Navigating...
Objectives To investigate the effect of client complaints on small animal veterinary internists’ welfare, job satisfaction and medical practices. Materials Methods Cross‐sectional anonymous survey study. Between February 1 March 31, 2017, a web‐based questionnaire was made available through American College Veterinary Internal Medicine sub‐specialty Small Animal E‐mail List Serve. Results A total 92 completed surveys were for review. Fifty‐nine (64∙1%) respondents received complaint during...
Serum chemistry panels and complete mineral heavy metal screens were performed on blood samples from eight adult northern goshawks (Accipiter gentilis) breeding in Pennsylvania. to determine the health status of each bird. Biochemical values measured included serum glucose, sodium, potassium, chloride, magnesium, uric acid, creatine kinase, aspartate transaminase. Glucose, transaminase elevated when compared with published for other species raptors. Complete better document content goshawks....