Zhi Qiao

ORCID: 0000-0003-4408-6793
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About
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Research Areas
  • Complex Systems and Time Series Analysis
  • Polymer composites and self-healing
  • Market Dynamics and Volatility
  • Conducting polymers and applications
  • Financial Risk and Volatility Modeling
  • Synthetic Organic Chemistry Methods
  • Mass Spectrometry Techniques and Applications
  • Advanced Sensor and Energy Harvesting Materials
  • Porphyrin and Phthalocyanine Chemistry
  • Spaceflight effects on biology
  • Aerospace Engineering and Energy Systems
  • N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
  • Microfluidic and Capillary Electrophoresis Applications
  • Analytical chemistry methods development
  • Surface Modification and Superhydrophobicity
  • Catalytic Cross-Coupling Reactions
  • Polyoxometalates: Synthesis and Applications
  • Luminescence and Fluorescent Materials
  • Perovskite Materials and Applications
  • Photochromic and Fluorescence Chemistry
  • Adventure Sports and Sensation Seeking
  • Oil Spill Detection and Mitigation
  • Organic Light-Emitting Diodes Research
  • Ion-surface interactions and analysis
  • High Temperature Alloys and Creep

Southwest University
2025

National University of Singapore
2014-2024

Anhui Institute of Optics and Fine Mechanics
2022-2024

Chinese Academy of Sciences
2018-2024

University of Science and Technology of China
2022-2024

Beijing National Laboratory for Molecular Sciences
2018-2023

Institute of Chemistry
2018-2023

Hefei Institutes of Physical Science
2023

Laser Research Institute
2022-2023

Technische Universität Dresden
2016-2022

Abstract Constructing responsive and adaptive materials by dynamic covalent bonds is an attractive strategy in material design. Here, we present a kind of polyureas which can be prepared from the highly efficient polyaddition reaction pyrazoles diisocyanates at ambient temperature absence catalyst. Owing to multiphase structural design, poly(pyrazole-ureas) (PPzUs) show excellent mechanical properties unique crystallization behavior. Besides, crosslinked PPzUs successfully recycled upon...

10.1038/s41467-019-12766-6 article EN cc-by Nature Communications 2019-10-18

Thermosetting polymers possess excellent environmental resistance and mechanical properties but cannot be reprocessed due to their covalently cross-linked structures. Recycling of thermosets via the implantation dynamic covalent bonds offers a promising solution. Here, we report direct catalyst-free ester metathesis N-acyloxyphthalimide (NAPI) at about 100 °C without requirement hydroxyl groups its utilization for fabrication adaptable networks (CANs). NAPI has interesting sigmoid kinetics...

10.1021/jacs.3c06262 article EN Journal of the American Chemical Society 2023-09-15

An understanding of the factors limiting open-circuit voltage (Voc) and related photon energy loss mechanisms is critical to increase power conversion efficiency (PCE) small-molecule organic solar cells (OSCs), especially those with near-infrared (NIR) absorbers. In this work, two NIR boron dipyrromethene (BODIPY) molecules are characterized for application in planar (PHJ) bulk (BHJ) heterojunction OSCs. When H atoms substituted by F on peripheral phenyl rings molecules, molecular...

10.1021/acs.jpclett.9b01222 article EN The Journal of Physical Chemistry Letters 2019-05-08

Measuring volatility in financial markets is a primary challenge the theory and practice of risk management essential when developing investment strategies. Although vast literature on topic describes many different models, two nonparametric measurements have emerged received wide use over past decade: realized absolute return volatility. The former strongly favored sector latter by econophysicists. We examine memory clustering features these methods find that both enable strong predictions....

10.1371/journal.pone.0102940 article EN cc-by PLoS ONE 2014-07-23

Recently, N-heterocyclic carbenes (NHCs) are explored as anchor groups to bind organic ligands colloidal gold (i.e. nanoparticles, Au NPs), yet these efforts confined non-conjugated so far-that is, focused solely on exploiting the stability aspect. Using NHCs link NPs and electronically active components, for example, conjugated polymers (CPs), will allow capitalizing both well inherent conductivity of NHC anchors. Here, we report three types Br-NHC-Au-X (X=Cl, Br) complexes, which, when...

10.1002/anie.202012216 article EN cc-by Angewandte Chemie International Edition 2020-11-02

Abstract Smart responsive materials that can alter their function in response to environmental changes are attractive for potential applications intelligent devices and products. Herein, a smart material exhibits reversible multiple properties upon variations humidity or temperature is created. The spontaneously transits between hydrated dehydrated states fluctuations the surrounding temperature. Consisting of mixture poly(propylene glycol) (PPG) with urea linkages (PPGurea) ionic liquid...

10.1002/admt.202400214 article EN cc-by Advanced Materials Technologies 2024-05-21

This paper presents a new monitoring method for multimode processes based on subspace decomposition. In the proposed method, influence of quality variables and information are considered in modeling, which is crucially important to ensure industrial production safety stabilization. Process data decomposed into global common local specific performed each simplify model structure. Two experiments: penicillin fermentation practical foods processes, have been used demonstrate excellent...

10.1021/ie504730x article EN Industrial & Engineering Chemistry Research 2015-04-09

One-dimensional (1D) fibers have been widely used in composites reinforcement for microwave attenuation due to their outstanding mechanical and electromagnetic properties, especially the axial direction. However, precise control of fiber alignment a polymer matrix remains challenge. In this work, we successfully demonstrated well-controlled silicon carbide nanowires (SiCNW) silicone by using direct ink writing (DIW)-based 3D printing. It is proven that printed multilayer material with could...

10.1021/acsami.2c06567 article EN ACS Applied Materials & Interfaces 2022-06-29

Abstract Two aryl‐fused BODIPY dyes BF‐BDP and NF‐BDP were synthesized with benzofuran naphtho[ b ]furan fusions on the α,β‐positions of skeleton, respectively, resulting in large linear conjugated structures. Both molecules planar characterized as intense deep‐red/NIR emitters emission bands tunable by solution concentration. Their red‐shifted to λ =730 760 nm vacuum‐deposited films.

10.1002/cptc.201800159 article EN ChemPhotoChem 2018-09-13

Matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) and the corresponding visualizing technique MALDI MS imaging (MSI) are potent widely used analytical methods in medical pathological research. In recent years, investigation of low-molecular-weight compounds (LMWCs) such as metabolites has moved increasingly into focus. techniques require a matrix system, small organic matrices (SOMs) commonly used. While SOMs offer multiple advantages, broad analyte scopes high...

10.1021/acsapm.1c00665 article EN ACS Applied Polymer Materials 2021-07-07

A precise air pollution forecast is the basis for targeted control and sustained improvements in quality. It desirable crucial to select most suitable model forecasting (APF). To achieve this goal, paper provides a comprehensive evaluation of performances different models simulating common pollutants (e.g., PM2.5, NO2, SO2, CO) Guangzhou (23.13° N, 113.26° E), China. simulate temporal variations above-mentioned pollutant concentrations September October 2020, we use numerical (i.e., Weather...

10.3390/atmos13101527 article EN cc-by Atmosphere 2022-09-20

10.1016/j.physa.2019.03.100 article EN Physica A Statistical Mechanics and its Applications 2019-03-27

Abstract Two novel aza‐BODIPY derivatives are synthesized, with the fluorine atoms in BF 2 moiety replaced by cyano groups. The introduction of groups changes phenyl substituents on 3,5 positions from parallel to antiparallel. HOMO/LUMO energy levels stabilized gradually upon increasing number groups, and photophysical properties show corresponding shifts. With high thermal stability, can be purified sublimation used prepare vacuum‐deposited thin films. This research extends family...

10.1002/cplu.201600479 article EN ChemPlusChem 2016-11-25

Abstract Polytriarylamines (PTAAs) are amorphous polymers that can be reversibly oxidized to generate stable radical cations. Despite exhibiting a low charge carrier mobility, PTAAs widely used as hole‐transporting layers in perovskite solar cells due their excellent stability under ambient conditions. The highest occupied molecular orbital (HOMO) energy levels of PTAA generally the range −5.1 −5.2 eV, and therefore slightly too high for an optimal alignment with perovskites. Most linear...

10.1002/pol.20220016 article EN cc-by-nc-nd Journal of Polymer Science 2022-05-11

<title>Abstract</title> Finding the optimal signal timing strategy poses a formidable challenge in traffic control problems. While multi-agent reinforcement learning holds promise for addressing this issue, majority of studies prioritize vehicle-centric approaches, neglecting crucial pedestrian factors, particularly unpredictable behavior pedestrians during street crossings. This research aims to bridge gap by investigating effectiveness novel Double Q-learning method based on collaboration...

10.21203/rs.3.rs-3981045/v1 preprint EN cc-by Research Square (Research Square) 2024-03-18

This study proposes a numerical model to simulate the thermal characteristics of stratospheric airships (SA). introduces simple yet accurate method for selection optical bands target detection based on multispectral features. The key this is spectral in which significant radiation difference exists between and its surrounding background. Using signal-to-noise ratio (SNR), probability, false alarm rate as evaluation metrics, analysis differences atmospheric background, it found that there are...

10.3390/rs16111884 article EN cc-by Remote Sensing 2024-05-24

With the development of fiber technologies, lasers are able to deliver very high power beams and energy pulses which can be used not only in scientific researches but industrial fields (laser marking, welding,…). The key laser is amplifier. In this paper, we present a two-level master-oscillator amplifier system at 1053 nm based on Yb-doped photonic crystal fibers. front-end facility for amplification nano-second meet high-level requirements. Thanks gain over 50 dB, pulse more than 0.89 mJ...

10.1117/12.2282342 article EN 2017-10-24

Residues oil from slick treatment on the water surface cause chronic damage to environment. These thin slicks were labeled with fluorescent. Adsorption characteristics of modified polypropylene (PP) non-woven fabric PP-GMA-OA/SS studied. The introduction hydrophilic groups oleophilic materials can accelerate adsorption and produces two strengthening effects. Hydrophilicity is used induce molecules carry approach fabrics. Hydrophobicity quickly capture oil. Through a method fluorescence image...

10.1080/01932691.2020.1740729 article EN Journal of Dispersion Science and Technology 2020-03-19
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