A5009044356- Synthesis and Properties of Aromatic Compounds
- Porphyrin and Phthalocyanine Chemistry
- Spectroscopy and Quantum Chemical Studies
- Analytical Chemistry and Sensors
- Molecular Junctions and Nanostructures
- Acoustic Wave Resonator Technologies
- Molecular spectroscopy and chirality
- Microencapsulation and Drying Processes
- Political and Social Issues
- Gas Sensing Nanomaterials and Sensors
- Multiculturalism, Politics, Migration, Gender
- Surface Chemistry and Catalysis
- Hepatitis B Virus Studies
- Graphene research and applications
- Advanced Thermodynamics and Statistical Mechanics
- Vaccine Coverage and Hesitancy
- Mechanical and Optical Resonators
- Date Palm Research Studies
- Electrochemical Analysis and Applications
- DNA and Nucleic Acid Chemistry
- Elevator Systems and Control
- Healthcare Systems and Practices
- Hepatitis C virus research
- Power System Reliability and Maintenance
- Heat Transfer and Boiling Studies
University of Monastir
2013-2021
London Rebuilding Society
2020
Hopital Universitaire Hedi Chaker
2017
Université de Lille
2012-2014
Centre Hospitalier Universitaire de Lille
2013-2014
Santé Publique France
2013
École Nationale Supérieure des Mines de Paris
1992
Purdue University West Lafayette
1992
The sorption isotherms give information about the interaction of biopolymers with water vapor. These are extremely important in modeling drying processes and prediction humidity changes during product storage. An analytical expression for vapor agricultural products was developed using statistical physics formalism. model further used to fit interpret desorption Tunisian olive leaves some food products. In this model, five parameters relation process intervene, such as number molecules per...
The adsorption of a metal ion to polycyclic aromatic molecule such as helicene is the object our study.
In this article, Tetraphenylporphyrin molecules were synthesized and used as biosensor for Magnesium ion. The metallization of porphyrin is a fundamental step which needs to be studied educated. fact, adsorption isotherms magnesium nitrate on coated onto Quartz crystal are achieved at four temperatures. Then, statistical physics treatment has been applied deduce new microscopic interpretations the experimental data. main contribution analytical deduct some physicochemical parameters related...
In this paper, water sorption isotherms into date kernels give interesting insights about the mechanism. The equilibrium adsorption data expressing change in moisture content of were collected at three different temperatures using static gravimetric technique. isotherm profiles demonstrated that process was performed via an infinite number layers. A modified form Brunauer, Emett and Teller (BET) model is obtained based on use real gas law statistical physics treatment so interaction between...
In this research paper, the equilibrium isotherms for adsorption of cobalt(ii)nitrate and cobalt(ii)chloride on tetrakis(4-tolylphenyl)porphyrin (H2TTPP) were obtained at four temperatures modeling analysis. The experimental data describing adsorbed quantity cobalt particles measured using quartz crystal microbalance (QCM) strategy. Then, statistical physics formalism was employed to interpret complexation mechanism by applying real gas law that contemplates interaction between adsorbate in...
New theoretical expressions for the modeling of adsorption isotherms Xenon on Graphite at 110 K have been established. The establishment these new is based statistical physics formalism and some working assumptions. This method allowed estimation physico-chemical parameters in model. intervening process deduced directly from experimental isotherm by numerical simulation. proposed models allow a good correlation to Type VI isotherms. We mainly introduce three affecting process, namely,...
In this article, the investigation of adsorption process six metal compounds (aluminum chloride, aluminum sulfate, iron indium chloride and sulfate) on promising macromolecule named porphyrin was performed to prove new insights about metals-porphyrin complexes. The experimental data complexation systems were controlled at four reaction temperatures using well-known microbalance apparatus (QCM). fact, outcomes physical modeling treatment indicated that aluminium should be analyzed via...
Abstract In recent papers, it is found that the silver-[6]Helicene complex can be used as a cancer drug but interaction silver-hexaHelicene has not yet proven. The idea of this paper to investigate complexation process [6]Helicene by silver metal (Ag + ) using three types adsorbates. Indeed, adsorption chloride, nitrate and sulfide into sensor films deposited on QCM electrode are measured at temperatures (293–333 K ). Films were resonators spin coating method in order obtain uniform...
A chemically coated piezoelectric sensor has been used for the determination in liquid phase of adsorption isotherm potassium. thin film aza[7]helicene was attached to surface a gold electrode quartz crystal microbalance using spin coating method.Statistical physics formalism applied elucidate mechanism potassium onto by aza[7]helicene. The simulation results showed that monolayer occurs with number per site about 1 and energy is less than 30 kJ.mol−1, characteristic physical adsorption.The...
Equilibrium adsorbed amounts of manganese on porphyrins were determined at 288 K and 308 using the quartz crystal microbalance strategy. The experimental measurements achieved in order to compare adsorption capacities tetratolylporphyrin tetraphenylporphyrin for ionophore investigation. aim this work is examine these isotherms ionic scale elucidate physical clarifications about microscopic interactions between ions two complexing (TTP TPP). Indeed, statistical physics formalism employed by...
The interaction between the silver ion and cyclic aromatic molecules, namely, helicenes, is subject of this paper. In fact, a complexation system based on quartz crystal microbalance (QCM) sensor with functional film helicenes has been designed developed at four temperatures. system, in which response reflects adsorption hexahelicene heptahelicene, was able to control complexed mass for each concentration. Experimental outcomes indicated that coated heptahelicene adequate material...
In this work, experimental isotherms of silver on hexahelicene and heptahelicene were collected at five adsorption temperatures using the quartz crystal microbalance strategy. Two analytical models statistical physics (MMPG MMRG) applied to explain complexation process two helicenes. Based physical significance models’ parameters, was found be typical an endothermic phenomenon by intermediate steric variables. Thus, fitted values adsorbed amounts saturation (QS1 QS2) highest in case...
A quartz crystal adsorbent functionalized with two promising porphyrins (the 5,10,15,20-tetrakis(4-tolylphenyl)porphyrin and the 5,10,15,20-tetraphenylporphyrin) was applied for investigation of adsorption phenomenon aluminum chloride, iron indium chloride. The aim is to prove new insights about appropriate materials metalloporphyrin fabrication. equilibrium isotherms were measured at five temperatures (from 290 330 K) through microbalance (QCM) method. discussion experimental observations...
A novel adsorption model for the description of isotherms cobalt nitrate on porphyrins H2TPP and H2TTPP is developed in present paper. Experimental data were measured at five temperatures using quartz crystal microbalance technique discussed to choose most reproductive adsorbent achievement vitamin B12 nucleus. Then, modeling treatment was established based grand canonical formalism statistical physics by taking into account lateral interaction between adsorbate particles. This leads a six...
The grand canonical ensemble in statistical physics has enabled us to develop a theoretical model that is an interesting application for adsorption gaseous phase. present approach turns out promising the characterization adsorbent material surface. Indeed, contains physicochemical parameters enable detailed investigation of process. Particularly, our allows study anchorage effect, receptor sites densities at surface, number adsorbed layers and this possible form isotherms. All these reached...
Abstract In this article, new insights about the metals-porphyrin complexes are proved by analyzing zinc, nickel and chromium adsorption process over well-known porphyrin macromolecule. The use of quartz crystal microbalance (QCM) apparatus allows control complexation systems’ experimental data operating at four temperatures. results physical models reveal that zinc processes to be examined using mono layer model. While, double model describes interaction between compound porphyrin....