P. M. Rupasinghe

ORCID: 0000-0003-4656-332X
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About
Contact & Profiles
Research Areas
  • Spectroscopy and Laser Applications
  • Cold Atom Physics and Bose-Einstein Condensates
  • Quantum optics and atomic interactions
  • Atomic and Molecular Physics
  • Atomic and Subatomic Physics Research
  • Molecular Junctions and Nanostructures
  • Spectroscopy and Quantum Chemical Studies
  • Advanced Chemical Physics Studies
  • Molecular Spectroscopy and Structure
  • Various Chemistry Research Topics
  • Advanced Frequency and Time Standards
  • Analytical Chemistry and Sensors
  • Laser-induced spectroscopy and plasma
  • Laser Design and Applications
  • Atmospheric and Environmental Gas Dynamics
  • Inorganic Fluorides and Related Compounds
  • Surface Roughness and Optical Measurements
  • Photochemistry and Electron Transfer Studies
  • Photoacoustic and Ultrasonic Imaging
  • Non-Destructive Testing Techniques
  • Laser-Matter Interactions and Applications
  • Atmospheric Ozone and Climate
  • Gas Sensing Nanomaterials and Sensors
  • Electron and X-Ray Spectroscopy Techniques
  • Optical and Acousto-Optic Technologies

State University of New York at Oswego
2021-2023

Williams College
2016-2019

California Institute of Technology
2014

Pomona College
2011

University of Oklahoma
2008-2011

Frequency-stabilized cavity ring-down spectroscopy was used to study CO2 lineshapes in the (20013) ← (00001) band centered near 2.06 μm. Two rovibrational transitions were chosen for this measure non-Voigt collisional effects air-broadened lines over pressure range of 7 kPa–28 kPa. Lineshape analysis both revealed evidence simultaneous Dicke (collisional) narrowing and speed-dependent that would introduce biases exceeding 2% retrieved air-broadening parameters if not incorporated modeling...

10.1063/1.4900502 article EN The Journal of Chemical Physics 2014-11-03

Pure rotational spectra of the ground electronic-vibrational ${X}_{1}$ state ${}^{204}$Pb${}^{19}$F, ${}^{206}$Pb${}^{19}$F, ${}^{207}$Pb${}^{19}$F, and ${}^{208}$Pb${}^{19}$F are measured with a resonator pulsed supersonic jet Fourier-transform microwave spectrometer. Also reported is new measurement Stark effect on optical $A\ensuremath{\leftarrow}{X}_{1}$ transitions. These combined published high-resolution infrared ${X}_{2}\ensuremath{\leftrightarrow}{X}_{1}$ transitions in order to...

10.1103/physreva.84.022508 article EN Physical Review A 2011-08-17

Here we report precision microwave spectroscopy of pure rotational transitions the $^{207}\mathrm{Pb}$$^{19}\mathrm{F}$ isotopologue. We use these data to make predictions sensitivity molecule $P$-odd, $T$-even and $T$-odd effects.

10.1103/physreva.83.040501 article EN publisher-specific-oa Physical Review A 2011-04-21

A highly efficient pseudo continuous resonance enhanced multiphoton ionisation detection scheme is presented that combines the sensitivity of (REMPI) with high resolution. This employed to obtain A(v′ = 1) ← X 1(v 0) spectra 208Pb19F a resolution 90 MHz. The observed 19F hyperfine splittings are analysed in terms effective parameters describe interaction between fluorine nuclear spin and unpaired electron 1 states molecule.

10.1080/00268970903567304 article EN Molecular Physics 2010-03-12

We derive an effective Hamiltonian to account for the geometric phase that occurs in adiabatic separation of center-of-mass and internal motion a molecule moving external fields. then apply this determination coherence time molecules confined region space by anisotropic electric field. show is expected scale as load temperature squared milli-K temperatures are likely be required trapped experiment compete with more conventional Ramsey beam resonance experiment.

10.1103/physreva.78.033427 article EN Physical Review A 2008-09-24

We present saturation absorption spectroscopy of transitions in Te2 near 444.4 nm. These spectra were taken using a blue diode laser locked to Fabry–Perot (FP) cavity that is turn Zeeman-stabilized helium–neon laser. Tuning the frequency accomplished by N2 pressure tuning FP cavity. The result proportional dispersion index refraction between helium neon and wavelengths. assess stability scanning over single line repeatedly 48 h period. This work motivated our desire produce versatile...

10.1364/josab.28.002934 article EN Journal of the Optical Society of America B 2011-11-17

We report measurements of the scalar and tensor static polarizabilities $^{115}\mathrm{In}\phantom{\rule{4pt}{0ex}}7{p}_{1/2}$ $7{p}_{3/2}$ excited states using two-step diode laser spectroscopy in an atomic beam. These are one to two orders magnitude larger than for lower-lying indium due close proximity $7p$ $6d$ states. For polarizabilities, we find values (in units) $1.811(4)\ifmmode\times\else\texttimes\fi{}{10}^{5}\phantom{\rule{4pt}{0ex}}{a}_{0}^{3}$...

10.1103/physreva.97.022507 article EN publisher-specific-oa Physical review. A/Physical review, A 2018-02-15

We completed a measurement of the Stark shift within $^{115}\mathrm{In}\phantom{\rule{4pt}{0ex}}6{s}_{1/2}\ensuremath{\rightarrow}6{p}_{1/2}$ excited-state transition using two-step laser spectroscopy in an indium atomic beam. By combining this with recent experimental results we determine scalar polarizability ${\ensuremath{\alpha}}_{0}$ $6{p}_{1/2}$ state to be $7683\ifmmode\pm\else\textpm\fi{}43{a}_{0}^{3}$ (in units), result which agrees very well theoretical calculations. In experiment,...

10.1103/physreva.94.022515 article EN publisher-specific-oa Physical review. A/Physical review, A 2016-08-31

The Saturated Absorption Spectroscopy (SAS) was performed to measure the hyperfine energy splittings of rubidium 5P$_{1/2}$ excited state using a homemade external-cavity diode laser (ECDL) operating at 795 nm. Any nonlinearities associated with ECDL scans were removed by low-expansion confocal Fabry-Perot cavity and hence created linearized frequency axis for spectra collected in fully automated fashion. We report our measurements magnetic dipole coupling constants 120.79(29) 407.75(50)...

10.1088/1402-4896/acc4f3 article EN Physica Scripta 2023-03-16

We have completed a measurement of the $(6s^26p^2)\, ^3\!P_0 \rightarrow \, ^3\!P_2$ 939 nm electric quadrupole ($E2$) transition amplitude in atomic lead. Using Faraday rotation spectroscopy technique and sensitive polarimeter, we measured this very weak $E2$ for first time, determined its to be $\langle ^3\!P_2 || Q \rangle$ = 8.91(9) a.u.. also present an ab initio theoretical calculation matrix element, which agrees with experiment at 0.5\% level. heat quartz vapor cell containing...

10.1103/physreva.100.052506 article EN Physical review. A/Physical review, A 2019-11-18

The electric-field-dependent $g$ factor and the electron electric dipole moment (eEDM)-induced Stark splittings for lowest rotational levels of $^{207,208}$PbF are calculated. Observed calculated Zeeman shifts $^{207}$PbF found to be in very good agreement. It is shown that hyperfine sublevels provide a promising system eEDM search related experiments.

10.1103/physreva.104.012811 article EN Physical review. A/Physical review, A 2021-07-22

There have been many advances in recent years remote sensing and ground-based measurement technologies utilizing optical detection to identify quantify species the atmosphere.Many of these instruments record high signal-to-noise spectra requiring sophisticated spectral modeling beyond Voigt profile.In order properly higher effects, high-resolution laboratory data measuring samples known composition under carefully controlled conditions are required.The oxygen A-band is used a number...

10.15278/isms.2016.wb05 article EN 2016-06-22

The 53rd Annual Meeting of the APS Division Atomic, Molecular and Optical Physics will take place from May 30 – June 3, 2022 in Orlando, Fl, USA. <a href="https://morressier.zoom.us/j/89880865272?pwd=SWxTRGhra1ZOSDBrSkhVZDBzVDR6UT09/">Virtual Presenter Help Desk</a>

10.26226/m.6275705c66d5dcf63a3115ca preprint EN 2022-05-12

The Saturated Absorption Spectroscopy (SAS) was performed to measure the hyperfine energy splittings of rubidium 5P$_{1/2}$ excited state using a homemade external-cavity diode laser (ECDL) operating at 795 nm. Any nonlinearities associated with ECDL scans were removed by low-expansion confocal Fabry-Perot cavity and hence created linearized frequency axis for spectra collected in fully automated fashion. We report our measurements magnetic dipole coupling constants 120.79(29) 407.75(50)...

10.48550/arxiv.2208.04244 preprint EN cc-by arXiv (Cornell University) 2022-01-01

10.15278/isms.2015.rf01 article EN Proceedings of the 74th International Symposium on Molecular Spectroscopy 2015-06-25

10.15278/isms.2014.ti15 article EN cc-by Proceedings of the 74th International Symposium on Molecular Spectroscopy 2014-06-17
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