A5036757967- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Synthesis and characterization of novel inorganic/organometallic compounds
- Crystallography and molecular interactions
- Organometallic Complex Synthesis and Catalysis
- Catalytic Cross-Coupling Reactions
- Synthetic Organic Chemistry Methods
- Organophosphorus compounds synthesis
- Cyclopropane Reaction Mechanisms
- Advanced Chemical Physics Studies
- Molecular Junctions and Nanostructures
- Fluorine in Organic Chemistry
- Synthesis of heterocyclic compounds
- Organoboron and organosilicon chemistry
- Synthesis and Reactions of Organic Compounds
- Inorganic Fluorides and Related Compounds
- Inorganic Chemistry and Materials
- Organic Chemistry Cycloaddition Reactions
- Catalytic C–H Functionalization Methods
- Metal complexes synthesis and properties
- Ferrocene Chemistry and Applications
- Lanthanide and Transition Metal Complexes
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Chemical Synthesis and Characterization
Georgia Institute of Technology
1998-2023
University of Alabama
2011-2020
Tuscaloosa City Schools
2017
DuPont (United States)
1992-2015
Experimental Station
1990-2015
Wilmington University
1991-2015
Johannes Gutenberg University Mainz
2015
University of Bonn
2013
Technische Universität Braunschweig
1999-2000
University of Illinois Urbana-Champaign
1980-1998
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA stable crystalline carbeneAnthony J. Arduengo III, Richard L. Harlow, and Michael KlineCite this: Am. Chem. Soc. 1991, 113, 1, 361–363Publication Date (Print):January 1991Publication History Published online1 May 2002Published inissue 1 January 1991https://pubs.acs.org/doi/10.1021/ja00001a054https://doi.org/10.1021/ja00001a054research-articleACS PublicationsRequest reuse permissionsArticle Views30534Altmetric-Citations3599LEARN ABOUT THESE...
ADVERTISEMENT RETURN TO ISSUEArticleNEXTLooking for Stable Carbenes: The Difficulty in Starting AnewAnthony J. ArduengoView Author Information Institut für Anorganische und Analytische Chemie, der Technischen Universität Carolo-Wilhelmina, D-38106 Braunschweig, Germany Cite this: Acc. Chem. Res. 1999, 32, 11, 913–921Publication Date (Web):August 21, 1999Publication History Received10 May 1999Published online21 August inissue 1 November...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic stabilization of nucleophilic carbenesAnthony J. Arduengo III, H. V. Rasika Dias, Richard L. Harlow, and Michael KlineCite this: Am. Chem. Soc. 1992, 114, 14, 5530–5534Publication Date (Print):July 1, 1992Publication History Published online1 May 2002Published inissue 1 July 1992https://doi.org/10.1021/ja00040a007RIGHTS & PERMISSIONSArticle Views14278Altmetric-Citations942LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA stable diaminocarbeneAnthony J. Arduengo III., Jens R. Goerlich, and William MarshallCite this: Am. Chem. Soc. 1995, 117, 44, 11027–11028Publication Date (Print):November 1, 1995Publication History Published online1 May 2002Published inissue 1 November 1995https://doi.org/10.1021/ja00149a034RIGHTS & PERMISSIONSArticle Views4035Altmetric-Citations381LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHomoleptic carbene-silver(I) and carbene-copper(I) complexesAnthony J. Arduengo III, H. V. Rasika Dias, Joseph C. Calabrese, Fredric DavidsonCite this: Organometallics 1993, 12, 9, 3405–3409Publication Date (Print):September 1, 1993Publication History Published online1 May 2002Published inissue 1 September 1993https://doi.org/10.1021/om00033a009Request reuse permissionsArticle Views3122Altmetric-Citations362LEARN ABOUT THESE METRICSArticle Views...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn electrically neutral .sigma.-sulfuranyl radical from the homolysis of a perester with neighboring sulfenyl sulfur: 9-S-3 speciesC. W. Perkins, J. C. Martin, A. Arduengo, Lau, Alegria, and K. KochiCite this: Am. Chem. Soc. 1980, 102, 26, 7753–7759Publication Date (Print):December 1, 1980Publication History Published online1 May 2002Published inissue 1 December...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoelectron Spectroscopy of a Carbene/Silylene/Germylene SeriesAnthony J. Arduengo III, Hans Bock, Han Chen, Michael Denk, David A. Dixon, Jennifer C. Green, Wolfgang Herrmann, Nancy L. Jones, Matthias Wagner, and Robert WestCite this: Am. Chem. Soc. 1994, 116, 15, 6641–6649Publication Date (Print):July 1, 1994Publication History Published online1 May 2002Published inissue 1 July...
The air-stable crystalline carbene 1,3-dimesityl-4,5-dichloroimidazol-2-ylidene (2) is produced from the chlorination of 1,3-dimesityimidazol-2-ylidene (1) by 2 equiv carbon tetrachloride. physical and spectroscopic properties are reported. features which contribute to exceptional stability discussed. Further reaction with tetrachloride leads reduction CCl4 dichlorocarbene. formation mixed "dimers" (olefins) in situ generated dichlorocarbene various imidazol(in)-2-ylidenes also tellurones...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLow-Coordinate Carbene Complexes of Nickel(0) and Platinum(0)Anthony J. Arduengo III, Siegfried F. Gamper, Joseph C. Calabrese, Fredric DavidsonCite this: Am. Chem. Soc. 1994, 116, 10, 4391–4394Publication Date (Print):May 1, 1994Publication History Published online1 May 2002Published inissue 1 1994https://pubs.acs.org/doi/10.1021/ja00089a029https://doi.org/10.1021/ja00089a029research-articleACS PublicationsRequest reuse permissionsArticle...
Abstract The synthesis, characterization and X‐ray crystallographic structure determination are described for a stable thiazol‐2‐ylidene 2 . This is the first example of stable, crystalline carbene in which singlet center bears sulfur substituent. closest analog important thiamin (vitamin B 1 ) carbene. Although sufficiently to isolate at room temperature absence moisture oxygen, it will dimerize form normal carbene–carbene dimer { } With isolation both }, this system its corresponding have...
The syntheses, characterizations, and X-ray crystallographic structure determinations are described for adducts of stable nucleophilic carbenes with pnictinidenes. between 1,3-dimesitylimidazol-2-ylidene phenylphosphinidene, phenylarsinidene, (trifluoromethyl)phosphinidene, (pentafluorophenyl)arsinidene reported. These carbene-pnictinidene formed by the direct reaction a carbene corresponding pnictinidene cyclic oligomers. synthesis adduct 1,3-dimesitylimidazolin-2-ylidene...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic structure of a stable nucleophilic carbeneDavid A. Dixon and Anthony J. Arduengo IIICite this: Phys. Chem. 1991, 95, 11, 4180–4182Publication Date (Print):May 1, 1991Publication History Published online1 May 2002Published inissue 1 1991https://pubs.acs.org/doi/10.1021/j100164a003https://doi.org/10.1021/j100164a003research-articleACS PublicationsRequest reuse permissionsArticle Views1445Altmetric-Citations197LEARN ABOUT THESE...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA stable carbene-alane adductAnthony J. Arduengo III, H. V. Rasika Dias, Joseph C. Calabrese, and Fredric DavidsonCite this: Am. Chem. Soc. 1992, 114, 24, 9724–9725Publication Date (Print):November 1, 1992Publication History Published online1 May 2002Published inissue 1 November 1992https://pubs.acs.org/doi/10.1021/ja00050a098https://doi.org/10.1021/ja00050a098research-articleACS PublicationsRequest reuse permissionsArticle...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron Distribution in a Stable CarbeneAnthony J. Arduengo III, H. V. Rasika Dias, David A. Dixon, Richard L. Harlow, W. T. Klooster, and F. KoetzleCite this: Am. Chem. Soc. 1994, 116, 15, 6812–6822Publication Date (Print):July 1, 1994Publication History Published online1 May 2002Published inissue 1 July 1994https://pubs.acs.org/doi/10.1021/ja00094a040https://doi.org/10.1021/ja00094a040research-articleACS PublicationsRequest reuse...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Bis(carbene)-Proton Complex: Structure of a C-H-C Hydrogen BondAnthony J. III Arduengo, Siegfried F. Gamper, Matthias Tamm, Joseph C. Calabrese, Frederic Davidson, and Hugh A. CraigCite this: Am. Chem. Soc. 1995, 117, 1, 572–573Publication Date (Print):January 1995Publication History Published online1 May 2002Published inissue 1 January 1995https://pubs.acs.org/doi/10.1021/ja00106a082https://doi.org/10.1021/ja00106a082research-articleACS...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of a reverse ylide from nucleophilic carbeneAnthony J. Arduengo III, Michael Kline, Joseph C. Calabrese, and Fredric DavidsonCite this: Am. Chem. Soc. 1991, 113, 25, 9704–9705Publication Date (Print):December 1, 1991Publication History Published online1 May 2002Published inissue 1 December 1991https://pubs.acs.org/doi/10.1021/ja00025a063https://doi.org/10.1021/ja00025a063research-articleACS PublicationsRequest reuse permissionsArticle...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe synthesis, structure, and chemistry of 10-Pn-3 systems: tricoordinate hypervalent pnicogen compoundsAnthony J. Arduengo III, Constantine A. Stewart, Fredric Davidson, David Dixon, James Y. Becker, Scott Anthony Culley, Mark B. MizenCite this: Am. Chem. Soc. 1987, 109, 3, 627–647Publication Date (Print):February 1, 1987Publication History Published online1 May 2002Published inissue 1 February...
The reactions and adducts of 1,3,4,5-tetramethylimidazol-2-ylidene with bis(pentamethylcyclopentadienyl)magnesium, -calcium, -strontium, -barium, or -zinc are described. A consistent tend in the spectroscopic properties structures alkaline earth metallocenes is observed. adduct between bis(pentamethylcyclopentadienyl)zinc shows a structure which zinc only σ-bonded to three ligating groups. Among adducts, interaction former carbene center shortest metal−carbon distances each but difference...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemical Shielding Tensor of a CarbeneAnthony J. Arduengo III, David A. Dixon, Kristin K. Kumashiro, Chengteh Lee, William P. Power, and Kurt W. ZilmCite this: Am. Chem. Soc. 1994, 116, 14, 6361–6367Publication Date (Print):July 1, 1994Publication History Published online1 May 2002Published inissue 1 July 1994https://pubs.acs.org/doi/10.1021/ja00093a041https://doi.org/10.1021/ja00093a041research-articleACS PublicationsRequest reuse...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA carbene germanium diiodide adduct: model of the non-least-motion pathway for dimerization singlet carbenesAnthony J. Arduengo III, H. V. Rasika Dias, Joseph C. Calabrese, and Fredric DavidsonCite this: Inorg. Chem. 1993, 32, 9, 1541–1542Publication Date (Print):April 1, 1993Publication History Published online1 May 2002Published inissue 1 April 1993https://pubs.acs.org/doi/10.1021/ic00061a004https://doi.org/10.1021/ic00061a004research-articleACS...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA new inversion process at Group VA (Group 15) elements. Edge through a planar T-shaped structureDavid A. Dixon, Anthony J. Arduengo, and Tadamichi. FukunagaCite this: Am. Chem. Soc. 1986, 108, 9, 2461–2462Publication Date (Print):April 1, 1986Publication History Published online1 May 2002Published inissue 1 April 1986https://pubs.acs.org/doi/10.1021/ja00269a063https://doi.org/10.1021/ja00269a063research-articleACS PublicationsRequest reuse...